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Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.

There is a great deal of interest in new technologies to assist in reducing the CO2 output of passenger vehicles, as part of the drive to meet the limits agreed by the EU and the European Automobile Manufacturer's Association ACEA, itself a result of the Kyoto Protocol. For the internal combustion engine, the most promising of these include gasoline direct injection, downsizing and fully variable valve trains. While new types of spray-guided gasoline direct injection (GDI) combustion systems are finally set to yield the level of fuel consumption improvement which was originally promised for the so-called ‘first generation’ wall- and air-guided types of GDI, injectors for spray-guided combustion systems are not yet in production to help justify the added complication and cost of the NOx trap necessary with a stratified combustion concept.