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Low speed pre-ignition (LSPI) is a limiting phenomenon for several of the technologies being pursued as part of the low carbon agenda. To achieve maximum power density and efficiency engines are being downsized and turbocharged, while Direct- injection technologies are becoming ever more prominent. All changes that increase the propensity of LSPI. The low speed-high load operation envelope is limited due to LSPI. Hydrogen engines are also being explored, however, with such a low minimum enthalpy of ignition, LSPI is a major limitation to thermal efficiency. Several techniques are utilized in this study to investigate physical and physio-chemical aspects of lubricant initiated LSPI. Where possible attempts have been to validate methodologies or directional alignment with published data. The basis of the methodologies used is a validated 1D predictive combustion model of a single cylinder GTDI engine, that was used to provide simulation boundary conditions.

A significant amount of harmful emissions pass unreacted through catalytic after-treatment devices for IC engines before the light-off temperature is reached, despite the high conversion efficiency of these systems in fully warm conditions. Further tightening of fleet targets and worldwide emission regulations will make a faster catalyst light-off to meet legislated standards hence reduce the impact of road transport on air quality even more critical. This work investigates the effect of adding hydrogen (H2) at levels up to 2500 ppm into the exhaust gases produced by combustion of various oxygenated C2-, C4- and renewable fuel molecules blended at 20 % wt/wt with gasoline on the light-off performance of a commercially available three-way catalyst (TWC) (0.61 L, Pd/Rh/Pt - 19/5/1, 15g). The study was conducted on a modified naturally aspirated, 1.4 L, four-cylinder, direct-injected, spark-ignition engine.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

Development of new fuels and engine combustion strategies for future ultra-low emission engines requires a greater level of insight into the process of emissions formation than is afforded by the approach of engine exhaust measurement. The paper describes the development of an in-cylinder gas sampling system consisting of a fast-acting, percussion-based, poppet-type sampling valve, and a heated dilution tunnel; and the deployment of the system in a single cylinder engine. A control system was also developed for the sampling valve to allow gas samples to be extracted from the engine cylinder during combustion, at any desired crank angle in the engine cycle, while the valve motion was continuously monitored using a proximity sensor. The gas sampling system was utilised on a direct injection diesel engine co-combusting a range of hydrogen-diesel fuel and methane-diesel fuel mixtures.

The design of a Diesel injector is a key factor in achieving higher engine efficiency. The injector's fuel atomisation characteristics are also critical for minimising toxic emissions such as unburnt Hydrocarbons (HC). However, when developing injection systems, the small dimensions of the nozzle render optical experimental investigations very challenging under realistic engine conditions. Therefore, Computational Fluid Dynamics (CFD) can be used instead. For the present work, transient, Volume Of Fluid (VOF), multiphase simulations of the flow inside and immediately downstream of a real-size multi-hole nozzle were performed, during and after the injection event with a small air chamber coupled to the injector downstream of the nozzle exit. A Reynolds Averaged Navier-Stokes (RANS) approach was used to account for turbulence. Grid dependency studies were performed with 200k-1.5M cells.

Flash-boiling of sprays may occur when a superheated liquid is discharged into an ambient environment with lower pressure than its saturation pressure. Such conditions normally exist in direct-injection spark-ignition engines operating at low in-cylinder pressures and/or high fuel temperatures. The addition of novel high volatile additives/fuels may also promote flash-boiling. Fuel flashing plays a significant role in mixture formation by promoting faster breakup and higher fuel evaporation rates compared to non-flashing conditions. Therefore, fundamental understanding of the characteristics of flashing sprays is necessary for the development of more efficient mixture formation. The present computational work focuses on modelling flash-boiling of n-Pentane and iso-Octane sprays using a Lagrangian particle tracking technique.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

One of the latest advancements in injector technology is laser drilling of the nozzle holes. In this context, the spray formation and atomisation characteristics of gasoline, ethanol and 1-butanol were investigated for a 7-hole spark eroded (SE) injector and its ‘direct replacement’ Laser-drilled (LD) injector using optical techniques. In the first step of the optical investigation, high-speed spray imaging was performed in a quiescent injection chamber with global illumination using diffused Laser light. The images were statistically analyzed to obtain spray penetration, spray tip velocity and spray ‘cone’ angles. Furthermore, droplet sizing was undertaken using Phase Doppler Anemometry (PDA). A single spray plume was isolated for this analysis and measurements were obtained across the plume at a fixed distance from the nozzle exit.

Improvements in the efficiency of internal combustion engines and the development of renewable liquid fuels have both been deployed to reduce exhaust emissions of CO2. An additional approach is to scrub CO2 from the combustion gases, and one potential means by which this might be achieved is the reaction of combustions gases with sodium borohydride to form sodium carbonate. This paper presents experimental studies carried out on a modern direct injection diesel engine supplied with a solution of dissolved sodium borohydride so as to investigate the effects of sodium borohydride on combustion and emissions. Sodium borohydride was dissolved in the ether diglyme at concentrations of 0.1 and 2 % (wt/wt), and tested alongside pure diglyme and a reference fossil diesel. The sodium borohydride solutions and pure diglyme were supplied to the fuel injector under an inert atmosphere and tested at a constant injection timing and constant engine indicated mean effective pressure (IMEP).

This paper presents a study of the combustion mechanism of hydrous and anhydrous ethanol in comparison to iso-octane and gasoline fuels in a single-cylinder spark-ignition research engine operated at 1000 rpm with 0.5 bar intake plenum pressure. The engine was equipped with optical access and tests were conducted with both Port Fuel Injection (PFI) and Direct Injection (DI) mixture preparation methods; all tests were conducted at stoichiometric conditions. The results showed that all alcohol fuels, both hydrous and anhydrous, burned faster than iso-octane and gasoline for both PFI and DI operation. The rate of combustion and peak cylinder pressure decreased with water content in ethanol for both modes of mixture preparation. Flame growth data were obtained by high-speed chemiluminescence imaging. These showed similar trends to the mass fraction burned curves obtained by in-cylinder heat release analysis for PFI operation; however, the trend with DI was not as consistent as with PFI.

International obligations to reduce carbon dioxide emissions and requirements to strengthen security of fuel supply, indicate a need to diversify towards the use of cleaner and more sustainable fuels. Hydrogen has been recommended as an encouraging gaseous fuel for future road transportation since with reasonable modifications it can be burned in conventional internal combustion engines without producing carbon-based tailpipe emissions. Direct injection of hydrogen into the combustion chamber can be more preferable than port fuel injection since it offers advantages of higher volumetric efficiency and can eliminate abnormal combustion phenomena such as backfiring. The current work applied a fully implicit computational methodology along with the Reynolds-Averaged Navier-Stokes (RANS) approach to study the mixture formation and combustion in a direct-injection spark-ignition engine with hydrogen fuelling.

Particulate emissions are of growing concern due to health impacts. Many urban areas around the world currently have particulate matter levels exceeding the World Health Organisation safe limits. Gasoline engines, especially when equipped with direct injection systems, contribute to this pollution. In recognition of this fact European limits on particulate mass and number are being introduced. A number of ways to meet these new stringent limits have been under investigation. The focus of this paper is on particulate emissions reduction through improvements in fuel delivery. This investigation is part of the author's ongoing particulate research and development that includes optical engine spray and combustion visualisation, CFD method development, engine and vehicle testing with the aim to move particulate emission development upstream in the development process.

Unlike RANS method, LES method needs more time and much more grids to accurately simulate the spray process. In KIVA, spray process was modeled by Lagrangain-drop and Eulerian-fluid method. The coarse grid can cause errors in predicting the droplet-gas relative velocity, so for reducing grid dependency due to the relative velocity effects, an improved spray model based on a gas-jet theory is used in this work and in order to validate the model seven different size grids were used. In this work, the local dense grid was used to reduce the computation cost and obtain accurate results that also were compared with entire dense grid. Another method to improve computation efficiency is the MUSCL (Monotone Upstream-centered Schemes for Conservation Laws) differencing scheme that was implemented into KIVA3V-LES code to calculate the momentum convective term and reduce numerical errors.

Hydrogen has been largely proposed as a possible fuel for internal combustion engines. The main advantage of burning hydrogen is the absence of carbon-based tailpipe emissions. Hydrogen's wide flammability also offers the advantage of very lean combustion and higher engine efficiency than conventional carbon-based fuels. In order to avoid abnormal combustion modes like pre-ignition and backfiring, as well as air displacement from hydrogen's large injected volume per cycle, direct injection of hydrogen after intake valve closure is the preferred mixture preparation method for hydrogen engines. The current work focused on computational studies of hydrogen injection and mixture formation for direct-injection spark-ignition engines. Hydrogen conditions at the injector's nozzle exit are typically sonic.

Current developments in fuels and emissions regulations are resulting in an increasingly severe operating environment for diesel fuel injection systems. The formation of deposits within the holes or on the outside of the injector nozzle can affect the overall system performance. The rate of deposit formation is affected by a number of parameters, including operating conditions and fuel composition. For the work reported here an accelerated test procedure was developed to evaluate the relative importance of some of these parameters in a high pressure common rail fuel injection system. The resulting methodology produced measurable deposits in a custom-made injector nozzle on a single-cylinder engine. The results indicate that fuels containing 30%v/v and 100% Fatty Acid Methyl Ester (FAME) that does not meet EN 14214 produced more deposit than an EN590 petroleum diesel fuel.

Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.

Hydrogen has been largely proposed as a possible alternative fuel for internal combustion engines. Its wide flammability range allows higher engine efficiency with leaner operation than conventional fuels, for both reduced toxic emissions and no CO2 gases. Independently, Homogenous Charge Compression Ignition (HCCI) also allows higher thermal efficiency and lower fuel consumption with reduced NOX emissions when compared to Spark-Ignition (SI) engine operation. For HCCI combustion, a mixture of air and fuel is supplied to the cylinder and autoignition occurs from compression; engine is operated throttle-less and load is controlled by the quality of the mixture, avoiding the large fluid-dynamic losses in the intake manifold of SI engines. HCCI can be induced and controlled by varying the mixture temperature, either by Exhaust Gas Recirculation (EGR) or intake air pre-heating.

This experimental work was concerned with the combination of internal EGR with an early inlet valve closure strategy for improved part-load fuel economy. The experiments were performed in a new spark-ignited thermodynamic single cylinder research engine, equipped with a mechanical fully variable valvetrain on both the inlet and exhaust. During unthrottled operation at constant engine speed and load, increasing the mass of trapped residual allowed increased valve duration and lift to be used. In turn, this enabled further small improvements in gas exchange efficiency, thermal efficiency and hence indicated fuel consumption. Such effects were quantified under both port and homogeneous central direct fuel injection conditions. Shrouding of the inlet ports as a potential method to increase in-cylinder gas velocities has also been considered.

Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

Recent pressures on vehicle manufacturers to reduce their average fleet levels of CO2 emissions have resulted in an increased drive to improve fuel economy and enable use of fuels developed from renewable sources that can achieve a net reduction in the CO2 output of each vehicle. The most popular choice for spark-ignition engines has been the blending of ethanol with gasoline, where the ethanol is derived either from agricultural or cellulosic sources such as sugar cane, corn or decomposed plant matter. However, other fuels, such as butanol, have also arisen as potential candidates due to their similarities to gasoline, e.g. higher energy density than ethanol. To extract the maximum benefits from these new fuels through optimized engine design and calibration, an understanding of the behaviour of these fuels in modern engines is necessary.