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Low speed pre-ignition (LSPI) is a limiting phenomenon for several of the technologies being pursued as part of the low carbon agenda. To achieve maximum power density and efficiency engines are being downsized and turbocharged, while Direct- injection technologies are becoming ever more prominent. All changes that increase the propensity of LSPI. The low speed-high load operation envelope is limited due to LSPI. Hydrogen engines are also being explored, however, with such a low minimum enthalpy of ignition, LSPI is a major limitation to thermal efficiency. Several techniques are utilized in this study to investigate physical and physio-chemical aspects of lubricant initiated LSPI. Where possible attempts have been to validate methodologies or directional alignment with published data. The basis of the methodologies used is a validated 1D predictive combustion model of a single cylinder GTDI engine, that was used to provide simulation boundary conditions.

A significant amount of harmful emissions pass unreacted through catalytic after-treatment devices for IC engines before the light-off temperature is reached, despite the high conversion efficiency of these systems in fully warm conditions. Further tightening of fleet targets and worldwide emission regulations will make a faster catalyst light-off to meet legislated standards hence reduce the impact of road transport on air quality even more critical. This work investigates the effect of adding hydrogen (H2) at levels up to 2500 ppm into the exhaust gases produced by combustion of various oxygenated C2-, C4- and renewable fuel molecules blended at 20 % wt/wt with gasoline on the light-off performance of a commercially available three-way catalyst (TWC) (0.61 L, Pd/Rh/Pt - 19/5/1, 15g). The study was conducted on a modified naturally aspirated, 1.4 L, four-cylinder, direct-injected, spark-ignition engine.

The demand for more efficient and clean engines have prompted the research and development of new engine technologies. Automotive engines expected to run with leaner mixtures and higher compression ratios. Lean burn is effective to increase fuel economy whilst reducing emissions but unreliable ignition of the lean mixtures by the conventional spark plug is one of the problems which causes concerns to the engine designers. Laser ignition is a promising technology and holds many benefits over the spark ignition because it can extend the ignitability of lean mixtures with flexibility of the ignition location and absence of electrode degradation for improved engine performance with lean burn. In this study, high-speed photography is used to investigate the flame kernel growth and propagation in an optical direct injection engine using laser ignition by an Nd:YAG laser.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

Development of new fuels and engine combustion strategies for future ultra-low emission engines requires a greater level of insight into the process of emissions formation than is afforded by the approach of engine exhaust measurement. The paper describes the development of an in-cylinder gas sampling system consisting of a fast-acting, percussion-based, poppet-type sampling valve, and a heated dilution tunnel; and the deployment of the system in a single cylinder engine. A control system was also developed for the sampling valve to allow gas samples to be extracted from the engine cylinder during combustion, at any desired crank angle in the engine cycle, while the valve motion was continuously monitored using a proximity sensor. The gas sampling system was utilised on a direct injection diesel engine co-combusting a range of hydrogen-diesel fuel and methane-diesel fuel mixtures.

With increasingly stringent requirements and regulations related to particulate matter(PM) emissions, manufacturers are paying more and more attention to emissions from gasoline direct injection(GDI) engines. The present paper proposes an improved two-step soot model. The model is applied in the Kiva-Chemkin program to simulate the processes of spray impinging, fuel mixture preparation, combustion and soot formation in a typical turbocharged downsized GDI engine. The simulation results show that soot formation in the GDI engine is attributed to non-uniform distribution of the air-fuel mixture and pool fire of wall film in the cylinder. Under homogeneous mode, increasing the injection advance angle can optimize fuel atomization and improve air-fuel mixing, thus reducing soot formation. However, an excessive injection advance angle may cause spray to impinge on the cylinder wall and this will sharply increase the soot emission.

Particle Number (PN) have already been a big issue for developing high efficiency internal combustion engines (ICEs). In this study, controlled spark-assisted stratified compression ignition (SSCI) with moderate end-gas auto-ignition was used for reducing PN in a high compression ratio gasoline direct injection (GDI) engine. Under wide open throttle (WOT) and Maximum Brake Torque timing (MBT) condition, high external cooled exhaust gas recirculation (EGR) was filled in the cylinder, while two-stage direct injection was used to form desired stoichiometric but stratified mixture. SSCI combustion mode exhibits two-stage heat release, where the first stage is associated with flame propagation induced by spark ignition and the second stage is the result of moderate end-gas auto-ignition without pressure oscillation at the middle or late stage of the combustion process.

An experimental study of particulate matter and volatile organic compounds (VOCs) emissions was conducted on a direct injection gasoline (DIG) engine and a port fuel injection (PFI) engine which both were produced by Chinese original equipment manufacturers (OEMs) to investigate the impact of fuel properties from Chinese market on particulate and VOCs emissions from modern gasoline vehicles. The study in this paper is just the first step of the work which is to investigate the impact of gasoline fuel properties and light duty vehicle technologies on the primary and secondary emissions, which are the sources of particulate matter 2.5 (PM2.5) in the atmosphere in China. It is expected through the whole work to provide some suggestions and guidelines on how to improve air quality and mediate severe haze pollution in China through fuel quality control and vehicle technology advances.

A 1-Dimensional (1-D) model of fluid dynamic and chemistry kinetics following hot spot auto-ignition has been developed to simulate the process from auto-ignition to pressure wave propagation. The role of wall effect on the physical-chemical interaction process is numerically studied. A pressure wave is generated after hot spot auto-ignition and gradually damped as it propagates. The reflection of the wall forms a reflected pressure wave with twice the amplitude of the incident wave near the wall. The superposition of the reflected and forward pressure waves reinforces the intensity of the initial pressure wave. Wall effect is determined by the distance between the hot spot center and the cylinder wall. Hot spot auto-ignition near the wall easily initiates detonation under high-temperature and high-pressure conditions because pressure wave reflection couples with chemical reactions and propagates in the mixture with high reactivity.

The design of a Diesel injector is a key factor in achieving higher engine efficiency. The injector's fuel atomisation characteristics are also critical for minimising toxic emissions such as unburnt Hydrocarbons (HC). However, when developing injection systems, the small dimensions of the nozzle render optical experimental investigations very challenging under realistic engine conditions. Therefore, Computational Fluid Dynamics (CFD) can be used instead. For the present work, transient, Volume Of Fluid (VOF), multiphase simulations of the flow inside and immediately downstream of a real-size multi-hole nozzle were performed, during and after the injection event with a small air chamber coupled to the injector downstream of the nozzle exit. A Reynolds Averaged Navier-Stokes (RANS) approach was used to account for turbulence. Grid dependency studies were performed with 200k-1.5M cells.

Flash-boiling of sprays may occur when a superheated liquid is discharged into an ambient environment with lower pressure than its saturation pressure. Such conditions normally exist in direct-injection spark-ignition engines operating at low in-cylinder pressures and/or high fuel temperatures. The addition of novel high volatile additives/fuels may also promote flash-boiling. Fuel flashing plays a significant role in mixture formation by promoting faster breakup and higher fuel evaporation rates compared to non-flashing conditions. Therefore, fundamental understanding of the characteristics of flashing sprays is necessary for the development of more efficient mixture formation. The present computational work focuses on modelling flash-boiling of n-Pentane and iso-Octane sprays using a Lagrangian particle tracking technique.

This paper addresses the need for fundamental understanding of the mechanisms of fuel spray formation and mixture preparation in direct injection spark ignition (DISI) engines. Fuel injection systems for DISI engines undergo rapid developments in their design and performance, therefore, their spray breakup mechanisms in the physical conditions encountered in DISI engines over a range of operating conditions and injection strategies require continuous attention. In this context, there are sparse data in the literature on spray formation differences between conventionally drilled injectors by spark erosion and latest Laser-drilled injector nozzles. A comparison was first carried out between the holes of spark-eroded and Laser-drilled injectors of same nominal type by analysing their in-nozzle geometry and surface roughness under an electron microscope.

2-Butanone (C4H8O) is a promising alternative fuel candidate as a pure as well as a blend component for substitution in standard gasoline fuels. It can be produced by the dehydrogenation of 2-butanol. To describe 2-butanone's basic combustion behaviour, it is important to investigate key physical properties such as the laminar burning velocity. The laminar burning velocity serves on the one hand side as a parameter to validate detailed chemical kinetic models. On the other hand, especially for engine simulations, various combustion models have been introduced, which rely on the laminar burning velocity as the physical quantity describing the progress of chemical reactions, diffusion, and heat conduction. Hence, well validated models for the prediction of laminar burning velocities are needed. New experimental laminar burning velocity data, acquired in a high pressure spherical combustion vessel, are presented for 1 atm and 5 bar at temperatures of 373 K and 423 K.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Occurrence of sporadic super-knock is the main obstacle to the development of advanced gasoline engines. One of the possible inducements of super-knock, agglomerated soot particle induced pre-ignition, was studied for high boosted gasoline direct injection (GDI) engines. The correlation between soot emissions and super-knock frequency was investigated in a four-cylinder gasoline direct injection production engine. The test results indicate that higher in-cylinder soot emission correlate with more pre-ignition and super-knock cycles in a GDI production engine. To study the soot/carbon particles trigger super-knock, a single-cylinder research engine for super-knock study was developed. The carbon particles with different temperatures and sizes were introduced into the combustion chamber to trigger pre-ignition and super-knock.

The design and optimization of a modern spray-guided gasoline direct injection engine require a thorough understanding of the fuel spray characteristics and atomization process. The fuel spray Computational Fluid Dynamics (CFD) modeling technology can be an effective means to study and predict spray characteristics, and as a consequence, to drastically reduce experimental work during the engine development process. For this reason, an accurate numerical simulation of the spray evolution process is imperative. Different models based on aerodynamically-induced breakup mechanism have been implemented to simulate spray atomization process in earlier studies, and the effect of turbulence from the injector nozzle is recently being concerned increasingly by engine researchers. In this study, a turbulence-induced primary breakup model coupled with aerodynamic instability is developed.

Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

Improvements in the efficiency of internal combustion engines and the development of renewable liquid fuels have both been deployed to reduce exhaust emissions of CO2. An additional approach is to scrub CO2 from the combustion gases, and one potential means by which this might be achieved is the reaction of combustions gases with sodium borohydride to form sodium carbonate. This paper presents experimental studies carried out on a modern direct injection diesel engine supplied with a solution of dissolved sodium borohydride so as to investigate the effects of sodium borohydride on combustion and emissions. Sodium borohydride was dissolved in the ether diglyme at concentrations of 0.1 and 2 % (wt/wt), and tested alongside pure diglyme and a reference fossil diesel. The sodium borohydride solutions and pure diglyme were supplied to the fuel injector under an inert atmosphere and tested at a constant injection timing and constant engine indicated mean effective pressure (IMEP).

This paper presents a study of the combustion mechanism of hydrous and anhydrous ethanol in comparison to iso-octane and gasoline fuels in a single-cylinder spark-ignition research engine operated at 1000 rpm with 0.5 bar intake plenum pressure. The engine was equipped with optical access and tests were conducted with both Port Fuel Injection (PFI) and Direct Injection (DI) mixture preparation methods; all tests were conducted at stoichiometric conditions. The results showed that all alcohol fuels, both hydrous and anhydrous, burned faster than iso-octane and gasoline for both PFI and DI operation. The rate of combustion and peak cylinder pressure decreased with water content in ethanol for both modes of mixture preparation. Flame growth data were obtained by high-speed chemiluminescence imaging. These showed similar trends to the mass fraction burned curves obtained by in-cylinder heat release analysis for PFI operation; however, the trend with DI was not as consistent as with PFI.

A study of Multiple Premixed Compression Ignition (MPCI) with heavy naphtha is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the net indicated mean effective pressure (IMEP) from 0.5MPa to 0.9MPa. Commercial diesel is also tested with the single injection for reference. The combustion and emissions characteristics of the heavy naphtha are investigated by sweeping the first (−200 ∼ −20 deg ATDC) and the second injection timing (−5 ∼ 15 deg ATDC) with an injection split ratio of 50/50. The results show that compared with diesel combustion, the naphtha MPCI can reduce NOx, soot emissions and particle number simultaneously while maintaining or achieving even higher indicated thermal efficiency. A low pressure rise rate can be achieved due to the two-stage combustion character of the MPCI mode but with the penalty of high HC and CO emissions, especially at 0.5MPa IMEP.