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Ammonia shows promise as an alternative fuel for internal combustion engines (ICEs) in reducing CO2 emissions due to its carbon-free nature and well-established infrastructure. However, certain drawbacks, such as the high ignition energy, the narrow flammability range, and the extremely low laminar flame speed, limit its widespread application. The dual fuel (DF) mode is an appealing approach to enhance ammonia combustion. The combustion characteristics of ammonia-diesel dual fuel mode and ammonia-PODE3 dual fuel mode were experimentally studied using a full-view optical engine and the high-speed photography method. The ammonia energy ratio (ERa) was varied from 40% to 60%, and the main injection energy ratio (ERInj1) and the main injection time (SOI1) were also varied in ammonia-PODE3 mode.

Internal combustion engines, as the dominant power source in the transportation sector and the primary contributor to carbon emissions, face both significant challenges and opportunities in the context of achieving carbon neutral goal. Biofuels, such as biodiesel produced from biomass, and zero-carbon fuel ammonia, can serve as alternative fuels for achieving cleaner combustion in internal combustion engines. The dual-fuel combustion of ammonia-biodiesel not only effectively reduces carbon emissions but also exhibits promising combustion performance, offering a favorable avenue for future applications. However, challenges arise in the form of unburned ammonia (NH3) and N2O emissions. This study, based on a ammonia-biodiesel duel-fuel engine modified from a heavy-duty diesel engine, delves into the impact of adjustments in the two-stage injection strategy on the combustion and emission characteristics.

The strategy for emission reduction in the P2.5 hybrid system involves the optimization of engine torque, engine speed, catalyst heat duration, and motor torque regulation in a coordinated manner. In addition to employing traditional engine control methods used in HEV models, unique approaches can be utilized to effectively manage emissions. The primary principle is to ensure that the engine operates predominantly under steady-state conditions or limits its load to regulate emissions levels. The main contributions of this paper are as follows: The first is the optimization of catalyst heating stage. During the catalyst heating stage, the system divides it into one or two stages. In the first stage, the vehicle is driven by the motor while keeping the engine idle. This approach stabilizes catalyst heating and prevents fluctuations in air-fuel ratio caused by speed and load changes that could potentially worsen emissions performance.

Both ammonia and hydrogen, as zero-carbon fuels for internal combustion engines, are received growing attention. However, ammonia faces a challenge of low flame propagation velocity. Through injecting hydrogen into active pre-chamber, its jet flame ignition can accelerate the flame propagation velocity of ammonia. The influence of different pre-chamber structures on engine combustion characteristics is significant. In this paper, numerical studies were conducted to assess the impact of various pre-chamber structures and hydrogen injection strategy on the combustion characteristics of ammonia/hydrogen engines while maintaining the equivalent ratio of 1.0. The results indicate that the jet angle significantly affects the position of jet flame and the followed main combustion. The in-cylinder combustion pressure peaks at jet angle of 150°. Meanwhile, the combustion duration of 150° is shortened by 74.3% compared with that of 60°.

In the context of carbon neutrality, ammonia is considered a zero-carbon fuel with potential applications in the transportation sector. However, its high ignition energy, low flame speed, and high natural temperature, indicative of low reactivity, make it challenging to be applied as a sole fuel in engines. In such a scenario, the use of another zero-carbon and highly reactive fuel, hydrogen, becomes necessary to enhance the combustion of ammonia. Furthermore, jet ignition, a method known for improving engine combustion performance, may also hold potential for enhancing the combustion performance of ammonia engines. To explore the applicability of jet ignition in engines, this study conducted experimental research on a single-cylinder engine. Two ignition methods were employed: passive jet ignition of premixed ammonia-hydrogen at a compression ratio of 11.5, and active jet ignition of pure ammonia using hydrogen jet flame at a compression ratio of 17.3.

Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.

Ammonia (NH3), a zero-carbon fuel, has great potential for internal combustion engine development. However, its high ignition energy, low laminar burning velocity, narrow range of flammability limits, and high latent heat of vaporization are not conducive for engine application. This paper numerically investigates the feasibility of utilizing ammonia in a heavy-duty diesel engine, specifically through low-pressure direct injection (LP-DI) of hydrogen to ignite ammonia combustion. Due to the lack of a well-corresponding mechanism for the operating conditions of ammonia-hydrogen engines, this study serves only as a trend-oriented prediction. The paper compares the engine's combustion and emission performance by optimizing four critical parameters: excess air ratio, hydrogen energy ratio, ignition timing, and hydrogen injection timing. The results reveal that excessively high hydrogen energy ratios lead to an advanced combustion phase, reducing indicated thermal efficiency.

Turbulent jet ignition (TJI) combustion using pre-chamber ignition can accelerate the combustion speed in the cylinder and has garnered growing interest in recent years. However, it is complicated for the optimization of the pre-chamber structure and combustion system. This study investigated the effects of the pre-chamber structure and the intake ports on the combustion characteristics of a gasoline engine through CFD simulation. Spark ignition (SI) combustion simulation was also conducted for comparison. The results showed that the design of the pre-chamber that causes the jet flame colliding with walls severely worsen the combustion, increasing the knocking intendency, and decrease the thermal efficiency. Compared with SI combustion mode, the TJI combustion mode has the higher heat transfer loss and lower unburned loss. The well-optimized pre-chamber can accelerate the flame propagation with knock suppression.

Ammonia is employed as the carbon-free fuel in the future engine, which is consistent with the requirements of the current national dual-carbon policy. However, the great amount of NOx and unburned NH3/H2 in the exhaust emissions is produced from combustion of ammonia and is one kind of the most strictly controlled pollutants in the emission regulation. This paper aims to investigate the NOx and unburned NH3/H2 generative process and emission characteristics by CFD simulation during the engine combustion. The results show that the unburned ammonia and hydrogen emissions increase with an increase of equivalence ratio and hydrogen blending ratio. In contrast, the emission concentrations of NOx, NO, and NO2 decrease with the increasing of equivalence ratio, but increase with hydrogen blending ratio rising. The emission concentration of N2O is highly sensitive to the O/H group and temperature, and it is precisely opposite to that of NO and NO2.

Liquid ammonia is an ideal zero carbon fuel to reduce carbon emission of internal combustion engines. The high-pressure injection of liquid ammonia is a key technology to fast distribute fuels and prepare better combustion performances. The physical properties of liquid ammonia are different to traditional fossil fuels including diesel and gasoline, which can change the spray and droplet characteristics significantly. However, the spray droplet characteristics of liquid ammonia injection is lack of investigations. In this paper, Phase Doppler Particle Analyzer (PDPA) are used to measure the droplet diameter and velocity of high-pressure liquid ammonia sprays up to 75 MPa and compare to diesel sprays. Effects of flash boiling of liquid ammonia droplet characteristics are also analyzed.

Low speed pre-ignition (LSPI) is a limiting phenomenon for several of the technologies being pursued as part of the low carbon agenda. To achieve maximum power density and efficiency engines are being downsized and turbocharged, while Direct- injection technologies are becoming ever more prominent. All changes that increase the propensity of LSPI. The low speed-high load operation envelope is limited due to LSPI. Hydrogen engines are also being explored, however, with such a low minimum enthalpy of ignition, LSPI is a major limitation to thermal efficiency. Several techniques are utilized in this study to investigate physical and physio-chemical aspects of lubricant initiated LSPI. Where possible attempts have been to validate methodologies or directional alignment with published data. The basis of the methodologies used is a validated 1D predictive combustion model of a single cylinder GTDI engine, that was used to provide simulation boundary conditions.

Lean combustion is an approach to achieving higher thermal efficiency for spark ignition engines. However, it faces low burning velocity and unstable combustion problems near the lean flammability limits region. The current work is attempting to investigate the combustion characteristics of iso-octane flame with 0% and 30% H2 up to near lean limits (λ = 1.7) at 100-300 kPa and 393-453 K. The flame appeared spherically by 37 mJ spark energy at λ = 0.8-1.2, whereas the ultra-lean mixtures, λ ≥ 1.3, ignited at 3000 mJ under wrinkles and buoyancy effects. The impact of initial pressure and temperature on the lean mixture was stronger than the stoichiometric mixture regarding flame radius and diffusional-thermal instability. The buoyancy appeared at the highest burning velocity of 27.41 cm/s.

In order to improve the ignition capacity and burning rate for spark-ignited engines, pre-chamber jet ignition is a promising technique to achieve fast premixed combustion and low pollutant emissions. However, few studies focus on the interaction between multiple reacting (i.e. flamelet) or reacted (i.e. radical) jets, its effect on ignition, exotherm and flow behaviors also remain to be revealed. This paper investigated two types of jet interaction under different pre-chamber structures, including the jet-crossing and unequal nozzle designs. Optical experiments under different conditions were conducted in a constant volume combustion chamber with CH4 as fuel, using simultaneous high speed schlieren and OH* chemiluminescence method. Meanwhile, computational fluid dynamics (CFD) simulations with CH4 and NH3/CH4 blend fuels were carried out using Converge software to provide further insights of turbulent flow and ignition process.

Octane number (ON) and octane sensitivity (S), the fuel anti-knock indices, are critical for the design of advanced jet ignition engines. In this study, ten fuels with different research octane number (RON) and varying S were formulated based on ethanol reference fuels (ERFs) to investigate the effect of S on combustion of jet ignition engine. To fully understand S effects, the combustion characteristics under EGR dilution and lean burn were further investigated. The results indicated that increasing S resulted in higher reactivity with shorter ignition delay and combustion duration. The increase of reactivity led to heavier knocking intensity. The competition between the flame speed and the reactivity of the mixture determined the auto-ignition fraction of mixture and the knocking onset crank angle as S varied. Medium S (S=3) was helpful to improve the combustion speed, reduce the auto-ignition fraction of mixture and retard the knocking onset crank angle.

A feasible method was developed to reconstruct the three-dimensional flame surface of SI combustion based on 2D images. A double-window constant volume vessel was designed to simultaneously obtain the side and bottom images of the flame. The flame front was reconstructed based on 2D images with a slicing model, in which the flame characteristics were derived by slicing flame contour modeling and flame-piston collision area analysis. The flame irregularity and anisotropy were also analyzed. Two different principles were used to build the slicing model, the ellipse hypothesis modeling and deep learning modeling, in which the ellipse hypothesis modeling was applied to reconstruct the flame in the optical SI engine. And the reconstruction results were analyzed and discussed. The reconstruction results show that part of the wrinkled and folded structure of the flame front in SI engines can be revealed based on the bottom view image.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

A significant amount of harmful emissions pass unreacted through catalytic after-treatment devices for IC engines before the light-off temperature is reached, despite the high conversion efficiency of these systems in fully warm conditions. Further tightening of fleet targets and worldwide emission regulations will make a faster catalyst light-off to meet legislated standards hence reduce the impact of road transport on air quality even more critical. This work investigates the effect of adding hydrogen (H2) at levels up to 2500 ppm into the exhaust gases produced by combustion of various oxygenated C2-, C4- and renewable fuel molecules blended at 20 % wt/wt with gasoline on the light-off performance of a commercially available three-way catalyst (TWC) (0.61 L, Pd/Rh/Pt - 19/5/1, 15g). The study was conducted on a modified naturally aspirated, 1.4 L, four-cylinder, direct-injected, spark-ignition engine.

This paper presents an investigation of drivability issue of engine start-stop. Hybrid vehicles provide excellent benefits regarding fuel efficiency and emission. However, vibration results from constant engine start and stop events generate drivability issues, thus compromising driving comfort. This paper has designed a high speed torque sensor to capture instantaneous torque at the engine shaft. Its consequences help to find out the most suitable index of vibration severity. This paper is organized in four sections. The first section introduces the powertrain to be studied. The second section introduces development of a specially designed torque sensor. The torque sensor is installed between the engine and ISG (Integrated Starter Generator), alongside with an encoder. The torque sensor is utilized to collect the instantaneous shaft torque on occasion of engine start. In the third section, this paper has performed two experiments.

The ignition of lubricating oil droplet has been proved to be the main factor for pre-ignition and the following super-knock in turbocharged gasoline direct injection engine. In this paper, the ignition process of lubricating oil droplet in combustible ambient gaseous mixture was investigated in a rapid compression machine (RCM). The pre-ignition induction by oil droplet of the ambient gaseous mixture was analyzed under different initial droplet volume and effective temperature conditions. The oil droplet was suspended on a tungsten fiber in the combustion chamber and the ignition process was recorded by a high-speed camera through the quartz window mounted at the end of the combustion chamber. The pressure traces were also obtained by a sensor in order to get the ignition delay and analyze the combustion process in detail.

Compression ratio and specific heat ratio are two dominant factors influencing engine thermal efficiency. Therefore, ultra-lean burn may be one method to deal with increasingly stringent fuel consumption and emission regulations in the approaching future. To achieve high efficiency and clean combustion, innovative combustion modes have been applied on research engines including homogeneous charge compression ignition (HCCI), spark-assisted compression ignition (SACI), and gasoline direct-injection compression ignition (GDCI), etc. Compared to HCCI, SACI can extend the load range and more easily control combustion phase while it is constrained by the limit of flame propagation. For SACI with ultra-lean burn in engines, equivalence ratio (φ), rich-fuel mixture around spark plug, and supercharging are three essentials for combustion stability.