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The growing demand for transportation fuels and the global emphasis on reducing greenhouse gas (GHG) emissions have led to increased interest in analyzing transport GHG emissions from the life-cycle perspective. Methanol, a potentially carbon-neutral fuel synthesized from CO2 and H2, has emerged as a promising candidate. This paper conducts a comprehensive life-cycle analysis (LCA) of the GHG emissions associated with the methanol production process, utilizing data inventory from China in 2019. To simulate the synthesis and distillation process of methanol, Aspen Plus is employed, using parameters obtained from actual plants. GHG emissions are then calculated using the GREET model, incorporating updated industry statistics and research findings. The CO2 necessary for methanol production is captured from factory flue gas.

Ethanol fuel blends with gasoline for spark ignition (SI) internal combustion engines are widely used on account of their advantages in terms of fuel economy and emissions reduction potential. The focus of this paper is to study the effects of these blends on combustion characteristics such as in-cylinder pressure profiles, gas-phase emissions (e.g., unburned hydrocarbons, NOx) and particulates (e.g., particulate matter and particle number) using both measurement campaigns and digital engineering workflows. Nineteen load-speed operating points in a 1L 3-cylinder GDI SI engine were measured and modelled. The measurements for in-cylinder pressure and emissions were repeated at each operating point for three types of fuel: gasoline (E0, 0% by volume of ethanol blend), E10 (10 % by volume of ethanol blend) and E20 (20% by volume of ethanol blend).

The large eddy simulation (LES) with Volume of Fluid (VOF) interface tracking method in Ansys-FLUENT has been used to study the effects of nozzle hole geometrical parameters on gasoline direct injection (GDI) fuel injectors, namely the effect of inner hole length/diameter (L/D) ratio and counter-bore diameters on near field spray characteristics. Using iso-octane as a model fuel at the fuel injection pressure of 200 bar, the results showed that the L/D ratio variation of the inner hole has a more significant influence on the spray characteristics than the counter-bore diameter variation. Reducing the L/D ratio effectively increases the mass flow rate, velocity, spray angle and reduces the droplet size and breakup length. The increased spray angle results in wall impingements inside the counter-bore cavity, particularly for L/D=1 which can potentially lead to increased deposit accumulation inside fuel injectors.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from Initial Boiling Point (IBP) of gasoline to Final Boiling Point (FBP) of diesel. Polyoxymethylene Dimethyl Ethers (PODEn) have high oxygen content and cetane number, are promising green additive to diesel fuel. In this paper, WDF was prepared by blending diesel and gasoline at ratio of 1:1, by volume; the mass distribution of oligomers in the PODE3-4 product was 88.9% of PODE3 and 8.46% of PODE4. Diesel fuel (Diesel), WDF (G50D50) and WDF (80%)-PODE3-4 (20%) (G40D40P20) were tested in a light-duty single-cylinder diesel engine, combustion characteristic, fuel consumption and exhaust emissions were measured. The results showed that: at idling condition, G40D40P20 has better combustion stability, higher heat release rate, higher thermal efficiency compared with G50D50.

There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

Due to the emission benefits of the oxygen in the fuel molecule, the interest for the use of ethanol as fuel blend components in compression ignition engines has been increased. However the use of fuel blends with high percentage of ethanol can lead to poor fuel blend quality (e.g. fuel miscibility, cetane number, viscosity and lubricity). An approach which can be used to improve these properties is the addition of biodiesel forming ternary blends (ethanol-biodiesel-diesel). The addition of castor oil-derived biodiesel (COME) containing a high proportion of methyl ricinoleate (C18:1 OH) is an attractive approach in order to i) reduce the use of first generation biodiesel derived from edible sources, ii) balance the reduction in viscosity and lubricity of ethanol-diesel blends due to the high viscosity and excellent lubricity of methyl ricinoleate.

The near-field diesel spray process in diesel engines is the intermediate one that connects the in-nozzle flow with far field spray process and high-speed imaging techniques with high-quality temporal and spatial resolution are required in order to record this short process (< 300 μs). In this study, a high-speed charge-coupled-device (CCD) camera with the speed of up to 1,000,000 fps was used to study the near-field spray process for a diesel injector with different nozzle diameters. The tests were carried out in a constant volume vessel over a range of injection pressure and ambient pressure in non-evaporating conditions. The observed zone of the spray was where penetration length is less than 18 mm. The development of spray penetration length against time after start of injection (ASOI) was used to evaluate the spray process. The significant difference on spray penetration length development is found when the nozzle diameter varied.

Unregulated emissions have become an important factor restricting the development of methanol and ethanol alternative alcohols fuels. Using two light-duty vehicles fuelled with pure gasoline, gasoline blend of 10% and 20% volume fraction of ethanol fuels, gasoline blend of 15% and 30% volume fraction of methanol fuels, New European Driving Cycle (NEDC) emission tests were carried on a chassis dynamometer according to ECE R83-05. High performance liquid chromatography (HPLC), Gas chromatography - Mass spectrometry (GC-MS), Fourier transform infrared spectrometer (FTIR) were used to measure methanol, formaldehyde, acetaldehyde, acetone, benzene, toluene, xylene, ethylene, propylene, 1,3-butadiene and isobutene emissions in the exhaust during the NEDC.

For spark ignition (SI) engines, the optimum spark timing is crucial for maximum efficiency. However, as the spark timing is advanced, so the propensity to knock increases, thus compromising efficiency. One method to suppress knock is to use high octane fuel additives. However, the blend ratio of these additives cannot be varied on demand. Therefore, with the advent of aggressive downsizing, new knock mitigation techniques are required. Fortuitously, there are two well-known lower alcohols which exhibit attractive knock mitigation properties: ethanol and methanol. Both not only have high octane ratings, but also result in greater charge-cooling than with gasoline. In the current work, the authors have exploited these attractive properties with the dual-injection, or the dual-fuel concept (gasoline in PFI and fuel additive in DI) using pure ethanol and methanol.

Ethanol has long been regarded as the optimal gasoline-alternative biofuel for spark-ignition (SI) engines. It is used widely in Latin and North America and is increasingly accepted as an attractive option across Europe. Nevertheless, its low energy density requires a high rate of manufacture; in areas which are deficient of arable land, such rates might prove problematic. Therefore, fuels with higher calorific values, such as butanol or 2,5-dimethylfuran (DMF) deserve consideration; a similar yield to ethanol, in theory, would require much less land. This report addresses the suitability of DMF, to meet the needs as a biofuel substitute for gasoline in SI engines, using ethanol as the biofuel benchmark. Specific attention is given to the sensitivity of DMF to various engine control parameters: combustion phasing (ignition timing), injection timing, relative air-fuel ratio and valve timing (intake and exhaust).

It is well known that direct injection (DI) is a technology enabler for stratified combustion in spark-ignition (SI) engines. At full load or wide-open throttle (WOT), partial charge stratification can suppress knock, enabling greater spark advance and increased torque. Such split-injection or double-pulse injection strategies are employed when using gasoline in DI (GDI). However, as the use of biofuels is set to increase, is this mode still beneficial? In the current study, the authors attempt to answer this question using two gasoline-alternative biofuels: firstly, ethanol; the widely used gasoline-alternative biofuel and secondly, 2,5-dimethylfuran (DMF); the new biofuel candidate. These results have been benchmarked against gasoline in a single-cylinder, spray-guided DISI research engine at WOT (λ = 1 and 1500 rpm). Firstly, single-pulse start of injection (SOI) timing sweeps were conducted with each fuel to find the highest volumetric efficiency and IMEP.

The lubricating properties of two sustainable alternative diesels blended with ultra low sulphur diesel (ULSD) were investigated. The candidate fuels were a biodiesel consisting of fatty acid methyl esters derived from rapeseed (RME) and gas-to-liquid (GTL). Lubricity tests were conducted on a high frequency reciprocating rig (HFRR). The mating specimen surfaces were analysed using optical microscopy and profilometery for wear scar diameters and profiles respectively. Microscopic surface topography and deposit composition was evaluated using a scanning electronic microscope (SEM) with an energy dispersive spectrometer (EDS). Like all modern zero sulphur diesel fuel (ZSD), GTL fuels need a lubricity agent to meet modern lubricity specifications. It has been proven that GTL responds well to typical lubricity additives in the marketplace.

In this paper, the microscopic spray characteristics of diesel, Rapeseed Methyl Ester (RME) and Gas-to-Liquid (GTL) fuel, were studied at different injection pressures and measuring positions using Phase Doppler Anemometry (PDA) technique and the velocity development and size distributions of the fuel droplets were analysed in order to understand spray atomisation process. The injection pressures ranged from 80MPa to 150MPa, and the measuring position varied from 20mm to 70mm downstream the nozzle. It was found that the data rate is quite low in the near nozzle region and at high injection pressure. Sauter Mean Diameter (SMD) of all fuels obviously decreases when the injection pressure increases from 80MPa to 120MPa; but the injection pressure has little promotion on the axial velocity of droplets.

Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

Limits on the total future potential of biodiesel fuel due to the availability of raw materials mean that ambitious 20% fuel replacement targets will need to be met by the use of both first and next generation biodiesel fuels. The use of higher percentage biodiesel blends requires engine recalibration, as it affects engine performance, combustion patterns and emissions. Previous work has shown that the combustion of 50:50 blends of biodiesel fuels (first generation RME and next generation synthetic fuel) can give diesel fuel-like performance (i.e. in-cylinder pressure, fuel injection and heat release patterns). This means engine recalibration can be avoided, plus a reduction in all the regulated emissions. Using a 30% biodiesel blend (with different first and next generation proportions) mixed with Diesel may be a more realistic future fuel.

The effects of variable intake-valve-timing on the gas exchange process and performance of a 4-valve direct-injection HCCI engine were computationally investigated using a 1D gas dynamics engine cycle simulation code. A non-typical strategy to actuate the pair of intake valves was examined; whereby each valve was assumed to be actuated independently at different timing. Using such an intake valves strategy, the obtained results showed a considerable improvement of the engine parameters such as load and charging efficiency as compared with the typical identical intake valve pair timings case. Additional benefits of minimizing pumping losses and improving the fuel economy were demonstrated with the use of the non-simultaneous actuation of the intake valve pair having the opening timing of the early intake valve coupled with a symmetric degree of crank angle for the timing of exhaust valve closing.

This paper presents a computational investigation of the in-cylinder charge characteristics within a motored 4-valve direct injection HCCI engine cylinder with applied negative valve overlapping. Non-typical intake valve strategy was investigated; whereby the pair of intake valves was assumed to follow the same low-lift short-duration valve-lift profile but actuated at different timings. The phase of intake-valve-opening relative to that of exhaust-valve-closing was optimized in terms of pumping losses. The flow fields generated with such an intake valve strategy were compared to those produced in the same engine cylinder but with typical early and late intake-valve-timing. The computational results of such an approach showed modifications in the in-cylinder swirl and tumble motions during the intake and compression strokes.

The aims of this study are to investigate the responses of a Hybrid III dummy and a human body model in rollover crashes of an SUV, and to assess the effect of seat belts on occupant kinematics in rollover events. A SAEJ2114 rollover test of a 1994 Ford Explorer for two front row dummies with an inflatable tubular structure (ITS) is reconstructed and validated in MADYMO. By removing the ITS, the simulations of the Hybrid III dummy occupants with and without seat belts are obtained. By replacing the dummy models with human body models, with and without seat belts, two other combinations are also modelled. The kinematics and injury risks of two kinds of occupant models are compared and evaluated. Significant differences exist in the motions, and injury levels of the dummies and human body models with and without seat belts. Seat belts can significantly mitigate against occupant ejection.

In recent years in the United Kingdom, dual-fuelled vehicles incorporating Liquid Petroleum Gas (LPG) have become more prevalent, as there are the perceived benefits of reduced fuelling costs, whilst also reducing the harmful emissions that effect air quality and climate change. In 2001, over 75,000 vehicles were registered as being powered by LPG and it is estimated that nearly 250,000 conversions were made to UK cars by the end of 2004. It is considered that the world population of such vehicles is in the order of 5 million vehicles, 2 million of which are being driven within EU countries.1 This paper will therefore examine the incidence of car fires in the area covered by Hereford and Worcester Fire and Rescue Service (HWFRS) in the UK. The data was used to establish the travel time for fire pumps to such incidents, the amount of time those units were detained at the scene and the possible cause of the fires themselves.

With the high auto ignition temperature of natural gas, various approaches such as high compression ratios and/or intake charge heating are required for auto ignition. Another approach utilizes the trapping of internal residual gas (as used before in gasoline controlled auto ignition engines), to lower the thermal requirements for the auto ignition process in natural gas. In the present work, the achievable engine load range is controlled by the degree of internal trapping of exhaust gas supplemented by intake charge heating. Special valve strategies were used to control the internal retention of exhaust gas. Significant differences in the degree of valve overlap were necessary when compared to gasoline operation at the same speeds and loads, resulting in lower amounts of residual gas observed. The dilution effect of residual gas trapping is hence reduced, resulting in higher NOx emissions for the stoichiometric air/fuel ratio operation as compared to gasoline.