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A fast response sensor for measuring carbon dioxide concentration has been developed for laboratory research and tested on a spark ignition engine. The sensor uses the well known infra-red absorption technique with a miniaturized detection system and short capillary sampling tubes, giving a time constant of approximately 5 milliseconds; this is sufficiently fast to observe changes in CO2 levels on a cycle-by-cycle basis under normal operating conditions. The sensor is easily located in the exhaust system and operates continuously. The sensor was tested on a standard production four cylinder spark-ignition engine to observe changes in CO2 concentration in exhaust gas under steady state and transient operating conditions. The processed sensor signal was compared to a standard air-to-fuel ratio (AFR) sensor in the exhaust stream and the results are presented here. The high frequency response CO2 measurements give new insights into both engine and catalyst transient operation.

The gas velocity through an automotive catalyst has been determined by measuring the time of flight of a pulse of propane injected at the inlet plane of the catalyst. The arrival time at the exit plane was detected by a fast flame ionization detector. By synchronizing and delaying the injection of propane with respect to the engine crankshaft position, the fluctuations of the exhaust gas velocity during the engine cycle were investigated. A number of tests at different engine load and speed points were carried out. The results show a complex velocity/time characteristic, including flow reversals. The technique is shown to be a viable option for flow measurement in this harsh environment.