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Biodiesel is a widely used biofuel in diesel engines, which is of particular interest as a renewable fuel because it possesses the similar properties as the diesel fuel. The pure soybean biodiesel was tested in an optical constant volume combustion chamber using natural flame luminosity and forward illumination light extinction (FILE) methods to explore the combustion process and soot distribution at various ambient temperatures (800 K and 1000 K) and oxygen concentrations (21%, 16%, 10.5%). Results indicated that, with a lower ambient temperature, the autoignition delay became longer for all three oxygen concentrations and more ambient air was entrained by spray jet and more fuel was burnt by premixed combustion. With less ambient oxygen concentration, the heat release rate showed not only a longer ignition delay but also longer combustion duration.

The influence of different combustion chamber configuration, intake temperature, and coolant temperature on HCCI combustion processes were investigated in a single-cylinder optical engine. Two-dimensional images of the chemiluminescence were captured using an intensified CCD camera in order to understand the spatial distribution of the combustion. N-heptane was used as the test fuel. Three combustion chamber geometries with different squish lip, salient, orthogonal, reentrant shape, referred as V-type, H-type, and A-type respectively, were used in this study. Intake temperature was set to 65°C and 95°C, while coolant temperature was set to 85°C. The experimental data consisting of the in-cylinder pressure, heat release rate, chemiluminescence images all indicated that the different combustion chamber geometries result in different turbulence intensity in the combustion chamber, and thus affect the auto-ignition timing, chemiluminescence intensity, and combustion processes.