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The 2023 FISITA White Paper (for which the author was a contributor) on managing in-service emissions and transportation options, to reduce CO2 (CO2-e or carbon footprint) from the existing vehicle fleet, proposed 6 levers which could be activated to complement the rapid transition to vehicles using only renewable energy sources. Another management opportunity reported here is optimizing the vehicle’s life in-service to minimize the life-cycle CO2 impact of a range of present and upcoming vehicles. This study of the US vehicle fleet has quite different travel and composition characteristics to European (EU27) vehicles. In addition, the embodied CO2 is based on ANL’s GREET data rather than EU27 SimaPro methodology. It is demonstrated that in-service, whole-of-life mileage has a significant influence on the optimum life cycle CO2 for BEVs and H2 fuelled FCEVs, as well as ICEs and PHEVs.

Compressed natural gas (CNG) is an attractive, alternative fuel for spark-ignited (SI), internal combustion (IC) engines due to its high octane rating, and low energy-specific CO2 emissions compared with gasoline. Directly-injected (DI) CNG in SI engines has the potential to dramatically decrease vehicles’ carbon emissions; however, optimization of DI CNG fueling systems requires a thorough understanding of the behavior of CNG jets in an engine environment. This paper therefore presents an experimental and modeling study of DI gaseous jets, using methane as a surrogate for CNG. Experiments are conducted in a non-reacting, constant volume chamber (CVC) using prototype injector hardware at conditions relevant to modern DI engines. The schlieren imaging technique is employed to investigate how the extent of methane jets is impacted by changing thermodynamic conditions in the fuel rail and chamber.

Fuel supercriticality has recently received significant attention due to the elevated pressures and temperatures that directly-injected (DI) fuel sprays encounter in modern internal combustion (IC) engines. This paper presents a theoretical examination of conventional and alternative DI fuels at conditions relevant to the operation of compression ignition (CI) engines. The focus is to identify the conditions under which the injected liquid fuel can bypass the atomization process and directly transition to a diffusional mixing regime with the chamber gas. Evaluating the microscopic length-scales of the phase boundary associated with the injection of liquid nitrogen into its own vapor, it is found that the conventional threshold based on the interfacial Knudsen number (i.e. Kn = 0.1) does not adequately quantify the direct transition between sub- and supercriticality. Instead, a threshold that is an order of magnitude smaller is more appropriate for this purpose.

The focus of internal combustion (IC) engine research is the improvement of fuel economy and the reduction of the tailpipe emissions of CO2 and other regulated pollutants. Promising solutions to this challenge include the use of both direct-injection (DI) and alternative fuels such as liquefied petroleum gas (LPG). This study uses Mie-scattering and schlieren imaging to resolve the liquid and vapor phases of propane and iso-octane, which serve as surrogates for LPG and gasoline respectively. These fuels are imaged in a constant volume chamber at conditions that are relevant to both naturally aspirated and boosted, gasoline direct injection (GDI) engines. It is observed that propane and iso-octane have different spray behaviors across these conditions. Iso-octane is subject to conventional spray breakup and evaporation in nearly all cases, while propane is heavily flash-boiling throughout the GDI operating map.

This paper presents a numerical study of trace knocking combustion of ethanol/gasoline blends in a modern, single cylinder SI engine. Results are compared to experimental data from a prior, published work [1]. The engine is modeled using GT-Power and a two-zone combustion model containing detailed kinetic models. The two zone model uses a gasoline surrogate model [2] combined with a sub-model for nitric oxide (NO) [3] to simulate end-gas autoignition. Upstream, pre-vaporized fuel injection (UFI) and direct injection (DI) are modeled and compared to characterize ethanol's low autoignition reactivity and high charge cooling effects. Three ethanol/gasoline blends are studied: E0, E20, and E50. The modeled and experimental results demonstrate some systematic differences in the spark timing for trace knock across all three fuels, but the relative trends with engine load and ethanol content are consistent. Possible reasons causing the differences are discussed.

This paper studies autoignition characteristics and HCCI engine combustion of ketone fuels, which are important constituents of recently discovered fungi-derived biofuels. Two ketone compounds, 2,4-dimethyl-3-pentanone (DMPN) and cyclopentanone (CPN), are systematically investigated in the Sandia HCCI engine, and the results are compared with conventional gasoline and neat ethanol. It is found that CPN has the lowest autoignition reactivity of all the biofuels and gasoline blends tested in this HCCI engine. The combustion timing of CPN is also the most sensitive to intake-temperature (Tin) variations, and it is almost insensitive to intake-pressure (Pin) variations. These characteristics and the overall HCCI performance of CPN are similar to those of ethanol. In contrast, DMPN shows multi-faceted autoignition characteristics. On the one hand, DMPN has strong temperature-sensitivity, even at boosted Pin, which is similar to the low-reactivity ethanol and CPN.

This paper presents an experimental, numerical and theoretical study of the performance of the same spark ignition engine running on four different gaseous fuels: hydrogen, two synthesis gases and natural gas. Measurements of the brake thermal efficiency, the combustion variability, the engine out emissions and the indicated, pumping and friction mean effective pressures are first presented, with particular interest placed on the lean burn performance. Combustion analysis is then undertaken, with the crank angle resolved in-cylinder turbulence and the flame propagation plotted on the so-called ‘Bradley diagram’ for turbulent premixed combustion. The loci of the combustion events on the Bradley diagram are then used to explain the observed, relative performance of the engine running on these four fuels.

This paper presents a study of the performance of a 6-cylinder, spark-ignited, port-fuel-injected, production engine modified for hydrogen fueling. The engine modifications include turbo-charging, multiple fuel injectors per port and charge-dilution control techniques. Pumping losses are reduced through ultra-lean burn and throttle-less operation alongside high charge dilution ratio control achieved by twin independent variable cam timing without external EGR. Lean-burn combustion, engine-out emissions and brake thermal efficiency results are examined in detail. In particular, low NO emissions and brake thermal efficiencies near 38% are observed experimentally at the same operating conditions. The former is explained in terms of the usual thermal NOx pathway. Usage of throttle position, injection timings and cam timings for avoiding preignition and knock over the entire engine map are also discussed.

This paper presents a study of the performance of a lean burn, natural gas-fuelled, naturally aspirated, spark ignition engine for an E class vehicle. Engine performance and exhaust emissions (NO, CO, and UHC) data are first discussed. An energy balance of the engine operating at different loads and air-fuel ratios is then presented, and used to explain why engine efficiency varies with air-fuel ratio. Finally, the hot start drive cycle CO2e (CO2 equivalent) emissions are estimated for a vehicle with this engine. This shows a potential for significant reduction in vehicle greenhouse gas emissions compared to an equivalent gasoline-fuelled vehicle.

The goal of hydrogen engine research is to achieve highest possible efficiency with low NOx emissions. This is necessary for the hydrogen car to remain competitive with the ever-improving efficiency of conventional fuel's use, to take advantage of the increased availability of hydrogen distribution for fuel cells and to achieve better range than battery electric vehicles. This paper examines the special problems of hydrogen engine combustion and ways to improve efficiency. Central to this are the effects of compression ratio (CR) and lambda (excess air ratio) and ignition system. The results demonstrate highest indicated thermal efficiency at ultra lean condition of lambda ≻ 2 and with central ignition. This need for this lean mixture is partly explained by the higher heat transfer losses.

Direct Injection (DI) is believed to be one of the key strategies for maximizing the thermal efficiency of Spark Ignition (SI) engines and meet the ever-tightening emissions regulations. This paper explores the use of Liquefied Petroleum Gas (LPG) liquid phase fuel in a 1.5 liter SI four cylinder gasoline engine with double over head camshafts, four valves per cylinder, and centrally located DI injector. The DI injector is a high pressure, fast actuating injector enabling precise multiple injections of the finely atomized fuel sprays. With DI technology, the injection timing can be set to avoid fuel bypassing the engine during valve overlap into the exhaust system prior to combustion. The fuel vaporization associated with DI reduces combustion chamber and charge temperatures, thereby reducing the tendency for knocking. Fuel atomization quality supports an efficient combustion process.

In this paper the experimental performance of the lean limits is examined for two different types of engines the first a dedicated LPG high compression ratio 2-valve per cylinder engine (Ford of Australia MY 2001 AU Falcon) and the second a gasoline moderate compression 4-valve per cylinder variant of the same engine (Ford of Australia MY 2006 BF Falcon). The in-cylinder composition at the lean limit over a range of steady state operating conditions is estimated using a quasi-dimensional model. This makes it possible to take into account the effects of both residual fraction and fresh charge diluents (EGR and excess air) that allow the exploration of a modeled lean limit performance [1, 2]. The results are compared to the predictions from a model for combustion variability applied to the quasi-dimensional model operating in optimization mode.

This paper reports comparative results for liquid phase versus gaseous phase port injection in a single cylinder engine. It follows previous research in a multi-cylinder engine where liquid phase was found to have advantages over gas phase at most operating conditions. Significant variations in cylinder to cylinder mixture distribution were found for both phases and leading to uncertainty in the findings. The uncertainty was avoided in this paper as in the engine used, a high speed Waukesha ASTM CFR, identical manifold conditions could be assured and MBT spark found for each fuel supply system over a wide range of mixtures. These were extended to lean burn conditions where gaseous fuelling in the multi-cylinder engine had been reported to be at least an equal performer to liquid phase. The experimental data confirm the power and efficiency advantages of liquid phase injection over gas phase injection and carburetion in multi-cylinder engine tests.

It is shown that LPG has the potential to be a main stream fuel because of its low particulate emissions and low greenhouse emission potential. The experimental study reported is directed at minimising the cost of LPG optimised engines through the use of gas phase, throttle body injection in an engine with 11.7 compression ratio up from 9.65 of the base gasoline engine. The advantages of throttle body injection, guided by CFD studies, are extension of the lean limit to lambda 1.6, where NOx is low enough to meet Euro4 emission standards without a reducing catalyst, as deduced from bench test results. Comparison is also made between throttle body and both liquid and gas phase multipoint port injection. Differences in the method of mixing significantly affect engine performance. Notable improvements in emissions and thermal efficiencies were achieved when compared with gasoline, eg.

This paper presents a parametric, experimental study of the performance of gas and liquid propane injection in a spark ignition, multi-point port injected (MPI) engine. An inline, six cylinder engine is used over a wide range of speeds and torques, and the air/fuel ratio, compression ratio and injection timing are all varied. The engine was mapped at the standard compression ratio of 9.65:1 with the original, gasoline MPI system, propane gas MPI, and single point, throttle body, propane gas injection. Gas and liquid propane MPI are then tested at a compression ratio of 11.7:1. Contour plots of thermodynamic efficiency and the specific emissions of HC, NOx, CO2 and CO over the torque/speed range are presented and compared. The results show significant differences in performance between gas and liquid propane MPI injection, as well as the MPI and throttle body gas injection.

The effects on bi-fuel car exhaust emissions, fuel consumption and acceleration performance of a range of LPG fuels has been determined. The LPGs tested included those representing natural gas condensate and oil refineries' products to include a spectrum of C3:C4 and paraffiinic:olefinic mixtures. The overall conclusions are that exhaust emissions from the gaseous fuels for the three-way catalyst equipped cars tested were lower than for gasoline. For all the LPGs, CO2 equivalent emissions are reduced by 7% to 10% or more compared with gasoline. The cars' acceleration performance indicates that there was no sacrifice in acceleration times to various speeds, with any gaseous fuel in these OEM developed cars.

HAJI, or Hydrogen Assisted Jet Ignition, is an ignition system which uses a hot gaseous jet to initiate and stabilise combustion. HAJI allows a dramatic reduction of cyclic variability, and an extension of the lean limit of the engine to lambda 5. Improvements in cyclic variability lead to increased power output, reduced noise, wear on components and emissions. The ability to operate ultra lean gives 25% improvements in efficiency and extremely low emissions, particularly of NOx. Combustion analysis based on the fractal dimensions of the propagating flame fronts, obtained from optical flame data, support the hypothesis of enhancement of flame speeds through the presence of active chemical species. However, the relative contributions of turbulence and active species to the mechanisms of combustion enhancement realised with HAJI are not well defined. HAJI ignition has also been simulated with a comprehensive three dimensional combustion code, KIVA3.

The hydrogen assisted jet ignition system (HAJI) replaces the spark plug of an Otto cycle engine and consists of a very small pre-chamber into which a hydrogen injector and spark plug are installed. The HAJI system allows stable combustion of very lean main-chamber hydrocarbon mixtures, leading to improved thermal efficiency and very much reduced NOx emissions. The current investigation focuses on the application of HAJI to a modern pent-roof, four valve per cylinder automotive engine. The development of a new hydrogen injection system and HAJI pre-chamber based on proprietary gasoline and diesel injectors is described. Results from injector and engine performance testing are presented in detail.

The HAJI (Hydrogen Assisted Jet Ignition) system for S.I. engines utilises direct injection of small amounts of hydrogen to enhance the combustion of a variety of automotive fuels. Although not the primary purpose of HAJI, the hardware, once in place, also lends itself to the possibility of hydrogen-only running during a cold start. Cold-start simulations have been performed using a single cylinder engine. Results are presented, comparing hydrogen-only tests with standard HAJI operation and normal spark-ignition operation. HAJI and spark ignition tests were carried out with gasoline as the main-chamber fuel. Emission levels and combustion stability characteristics were recorded as the engine warmed up. The differences between the various fueling/ignition scenarios are presented and the implications for possible automotive applications are discussed in light of current and proposed emissions legislation.

HAJI (Hydrogen Assisted Jet Ignition) is an advanced combustion initiation system for otherwise standard S.I engines. It utilises the fluid mechanics of a turbulent, chemically active jet, combined with the reliability of spark igniting rich hydrogen mixtures. The result is an extremely robust ignition system, capable of developing power from an engine charged with air-fuel mixtures as lean as λ = 5. Experiments have been performed using a single cylinder engine operating on gasoline in the speed range of 600-1800 r/min. Data are presented in the form of maps which describe fuel efficiency, combustion stability and emissions with respect to load, speed, air-fuel ratio and throttle. The results are incorporated into a model of a known engine and vehicle and this is used to estimate performance over the Federal drive-cycle.