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The emission of excessive quantities of NOx when the automobile air conditioner is turned on has received a fair amount of attention in recent years. Since NOx is a smog precursor, it is important to understand the reasons for this jump in emissions especially on hot sunny days when air conditioner usage is at a maximum. A simple thermodynamic model is used to demonstrate how the torque from a typical air conditioner compressor is mainly related to the ambient temperature. The compressor's on-off cycling patterns are also characterized. Since the compressor significantly loads the engine, it affects fuel economy and emissions. The key independent variable that we employ to represent engine load is fuel rate. The correlations between engine-out NOx emissions and fuel rate are shown for a number of light duty vehicles and trucks. From these, a physical model for engine-out NOx emissions (with and without air conditioning) is presented.