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Blends of propane-diesel fuel can be used in direct injection diesel engines to improve the air-fuel mixing and the premixed combustion phase, and to reduce pollutant emissions. The potential benefits of usinf propane in diesel engines are both environmental and economic; furthermore, its use does not require changes to the compression ratio of conventional diesel engines. The present paper describes an experimental investigation of the injection process for different liquid preformed blends of propane-diesel fuel in an optically accessible Common Rail diesel engine. Slight modifications of the injection system were required in order to operate with a blend of propane-diesel fuel. Pure diesel fuel and two propane-diesel mixtures at different mass ratios were tested (20% and 40% in mass of propane named P20 and P40). First, injection in air at ambient temperature and atmospheric pressure were performed to verify the functionality of the modified Common Rail injection system.