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The work examined the practicality of converting a modern production 6 cylinder 7.7 litre heavy-duty diesel engine for flex dual-fuel operation with ammonia as the main fuel. A small amount of diesel fuel (pilot) was used as an ignition source. Ammonia was injected into the intake ports during the intake stroke, while the original direct fuel injection equipment was retained and used for pilot diesel injection. A bespoke engine control unit was used to control the injection of both fuels and all other engine parameters. The aim was to provide a cost-effective retrofitting technology for existing heavy-duty engines, to enable eco-friendly operation with minimal carbon emissions. The tests were carried out at a baseline speed of 600 rpm for the load range of the engine (10-90%), with minimum pilot diesel quantity and as high as 90% substitution ratio of ammonia for diesel fuel.

Ammonia (NH3) is emerging as a potential fuel for longer range decarbonised heavy transport, predominantly due to favourable characteristics as an effective hydrogen carrier. This is despite generally unfavourable combustion and toxicity attributes, restricting end use to applications where robust health and safety protocols can always be upheld. In the currently reported work, a spark ignited thermodynamic single cylinder research engine was upgraded to include gaseous ammonia and hydrogen port injection fueling, with the aim of understanding maximum viable ammonia substitution ratios across the speed-load operating map. The work was conducted under stoichiometric conditions with the spark timing re-optimised for maximum brake torque at all stable logged sites. The experiments included industry standard measurements of combustion, performance and engine-out emissions.

The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

Engine research has increasingly focused on emission of sub 23 nm particulates in recent years. Likewise, current legislative efforts are being made for particulate number (PN) emission limits to include this previously omitted size range. In Europe, PN measurement equipment and procedures for regulatory purposes are defined by the particle measurement programme (PMP). Latest regulation drafts for sub 23 nm measurements specify counting efficiencies with a 65% cut-off size at 10 nm (d65) and a minimum of 90% above 15 nm (d90). Even though alternative instruments, such as differential mobility spectrometers (DMS), are widely used in laboratory environments, the interpretation of their sub 23 nm measurements has not yet been widely discussed. For this study, particulate emissions of a 1.0L gasoline direct injection (GDI) engine have been measured with a DMS system for low to medium speeds with two load steps.

Over the last decade, there has been an impetus in the automobile industry to develop new diesel injector systems, driven by a desire to reduce fuel consumption and proscribed by the requirement to fulfil legislation emissions. The modern common-rail diesel injector system has been developed by the industry to fulfil these aspirations, designed with ever-higher tolerances and pressures, which have led to concomitant increases in fuel temperatures after compression with reports of fuel temperatures of ~150°C at 1500-2500 bar. This engineering solution in combination with the introduction of Ultra Low Sulphur diesel fuel (ULSD) has been found to be highly sensitive to deposit formation both external injector deposits (EDID) and internal (IDID). The deposits have caused concerns for customers with poor spray patterns misfiring injector malfunction and failure, producing increased fuel consumption and emissions.

Through improving the 48V hybrid vehicle archetype, governmental emission targets could be more easily met without incurring the high costs associated with increasing levels of electrification. The braking energy recovery function of hybrid vehicles is recognised as an effective solution to reduce emissions and fuel consumption in the short to medium term. The aim of this study was to evaluate methods to maximise the braking energy recovery capability of the 48V hybrid electric vehicle over pre-selected drive cycles using appropriately sized electrified components. The strategy adopted was based upon optimising the battery chemistry type via specific power capability, so that overall brake power is equal to the maximum battery charging power in a typical medium-sized passenger car under typical driving. This will maximise the regenerative braking energy whilst providing a larger torque assistance for a lower battery capacity.

Characterization of soot nanoparticle morphology can be used to develop understanding of nanoparticle interaction with engine lubricant oil and its additives. It can be used to help direct modelling of soot-induced thickening, and in a more general sense for combatting reductions in engine efficiency that occur with soot-laden oils. Traditional 2D transmission electron microscopy (TEM) characterization possesses several important shortcomings related to accuracy that have prompted development of an alternative 3D characterization technique utilizing electron tomography, known as 3D-TEM. This work details progress made towards facilitating semi-automated image acquisition and processing for location of structures of interest on the TEM grid. Samples were taken from a four cylinder 1.4 L gasoline turbocharged direct injection (GTDI) engine operated in typically extra-urban driving conditions for 20,284 km, with automatic cylinder deactivation enabled.

Formation of soot is a known phenomenon for diesel engines, however, only recently emerged for gasoline engines with the introduction of direct injection systems. Soot-in-oil samples from a three-cylinder turbocharged gasoline direct injection (GDI) engine have been analysed. The samples were collected from the oil sump after periods of use in predominantly urban driving conditions with start-stop mode activated. Thermogravimetric analysis (TGA) was performed to measure the soot content in the drained oils. Soot deposition rates were similar to previously reported rates for diesel engines, i.e. 1 wt% per 15,000 km, thus indicating a similar importance. Morphology was assessed by transmission electron microscopy (TEM). Images showed fractal agglomerates comprising multiple primary particles with characteristic core-shell nanostructure. Furthermore, large amorphous structures were observed. Primary particle sizes ranged from 12 to 55 nm, with a mean diameter of 30 nm and mode at 31 nm.

Morphology plays an important role in determining behaviour and impact of soot nanoparticles, including effect on human health, atmospheric optical properties, contribution to engine wear, and role in marine ecology. However, its nanoscopic size has limited the ability to directly measure useful morphological parameters such as surface area and effective volume. Recently, 3D morphology characterization of soot nanoparticles via electron tomography has been the subject of several introductory studies. So-called ‘3D-TEM’ has been posited as an improvement over traditional 2D-TEM characterization due to the elimination of the error-inducing information gap that exists between 3-dimensional soot structures and 2-dimensional TEM projections. Little follow-up work has been performed due to difficulties with developing methodologies into robust high-throughput techniques.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

This work was concerned with study of the in-cylinder flow field and flame development in a spark ignition research engine equipped with Bowditch piston optical access. High-speed natural light (chemiluminescence) imaging and simultaneous in-cylinder pressure data measurement and analysis were used to understand the fundamentals of flame propagation for a variety of ethanol fuels blended with either gasoline or iso-octane. PIV was undertaken on the same engine in a motoring operation at a horizontal imaging plane close to TDC (10 mm below the fire face) throughout the compression stroke (30°,40°,90° and 180°bTDC) for a low load engine operating condition at 1500rpm/0.5 bar inlet plenum pressure. Up to 1500 cycles were considered to determine the ensemble average flow-field and turbulent kinetic energy. Finally, comparisons were made between the flame and flow experiments to understand the apparent interactions.

A physics based, lumped thermal capacity model of a 1litre, 3 cylinder, turbocharged, directly injected spark ignition engine has been developed to investigate the effects of cylinder deactivation on the thermal behaviour and fuel economy of small capacity, 3 cylinder engines. When one is deactivated, the output of the two firing cylinders is increased by 50%. The largest temperature differences resulting from this are between exhaust ports and between the upper parts of liners of the deactivated cylinder and the adjacent firing cylinder. These differences increase with load. The deactivated cylinder liner cools to near-coolant temperature. Temperatures in the lower engine structure show little response to deactivation. Temperature response times following deactivation or reactivation events are similar. Motoring work for the deactivated cylinder is a minor loss; the net benefit of deactivation diminishes with increasing load.

The oil distribution system of an automotive light duty engine typically has an oil pump mechanically driven through the front-endancillaries-drive or directly off the crankshaft. Delivery pressure is regulated by a relief valve to provide an oil gallery pressure of typically 3 to 4 bar absolute at fully-warm engine running conditions. Electrification of the oil pump drive is one way to decouple pump delivery from engine speed, but this does not alter the flow distribution between parts of the engine requiring lubrication. Here, the behaviour and benefits of a system with an electrically driven, fixed displacement pump and a distributor providing control over flow to crankshaft main bearings and big end bearings is examined. The aim has been to demonstrate that by controlling flow to these bearings, without changing flow to other parts of the engine, significant reductions in engine friction can be achieved.

Modeling the combustion process of a diesel-biodiesel fuel spray in a 3-dimensional (3D) computational fluid dynamics (CFD) domain remains challenging and time-consuming despite the recent advancement in computing technologies. Accurate representation of the in-cylinder processes is essential for CFD studies to provide invaluable insights into these events, which are typically limited when using conventional experimental measurement techniques. This is especially true for emerging new fuels such as biodiesels since fundamental understanding of these fuels under combusting environment is still largely unknown. The reported work here is dedicated to evaluating the Adaptive Local Mesh Refinement (ALMR) approach in OpenFOAM® for improved simulation of reacting biodiesel fuel spray. An in-house model for thermo-physical and transport properties is integrated to the code, along with a chemical mechanism comprising 113 species and 399 reactions.

Cold idle operation of a modern design light duty diesel engine and the effect of multiple pilot injections on stability were investigated. The investigation was initially carried out experimentally at 1000rpm and at −20°C. Benefits of mixture preparation were initially explored by a heat release analysis. Kiva 3v was then used to model the effect of multiple pilots on in-cylinder mixture distribution. A 60° sector of mesh was used taking advantage of rotational symmetry. The combustion system and injector arrangements mimic the HPCR diesel engine used in the experimental investigation. The CFD analysis covers evolutions from intake valve closing to start of combustion. The number of injections was varied from 1 to 4, but the total fuel injected was kept constant at 17mm3/stroke. Start of main injection timing was fixed at 7.5°BTDC.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

The nature of internal diesel injector deposits (IDID) continues to be of importance to the industry, with field problems such as injector sticking, loss of power, increased emissions and fuel consumption being found. The deposits have their origins in the changes in emission regulations that have seen increasingly severe conditions experienced by fuels because of high temperatures and high pressures of modern common rail systems and the introduction of low sulphur fuels. Furthermore, the effect of these deposits is amplified by the tight engineering tolerances of the moving parts of such systems. The nature and thus understanding of such deposits is necessary to both minimising their formation and the development of effective diesel deposit control additives (DCA).

The thermal efficiency of an internal combustion engine at steady state temperatures is typically in the region of 25-35%[1]. In a cold start situation, this reduces to be between 10% and 20% [2]. A significant contributor to the reduced efficiency is poor performance by the engine lubricant. Sub optimal viscosity resulting from cold temperatures leads to poor lubrication and a subsequent increase in friction and fuel consumption. Typically, the engine lubricant takes approximately twenty minutes [3] to reach steady state temperatures. Therefore, if the lubricant can reach its steady state operating temperature sooner, the engine's thermal efficiency will be improved. It is hypothesised that, by decoupling the lubricant from the thermal mass of the surrounding engine architecture, it is possible to reduce the thermal energy loss from the lubricant to the surrounding metal structure in the initial stages of warm-up.

The influence of size and concentration of carbon nanoparticle on the viscosity of an SAE 5W-30 lubricant oil has been investigated experimentally. Data were collected for oil samples drawn from sump of light duty automotive diesel engines. The average size of soot particles in the used oil samples was in the range of 180-320nm with concentrations ranging from 0 to 2 percentage by weight (wt. %.). A Brookfield DV-II Pro rotary viscometer was used to measure dynamic viscosity at low shear rates and temperatures of 40°C and 90°C. Nanoparticle concentration and particle size distribution were evaluated using Thermo-Gravimetric Analysis (TGA) and Dynamic Light Scattering (DLS) respectively. The viscosity of suspensions of graphite powder in lubricant oil was also investigated for concentrations ranging from 0 to 2 wt. %. The results show that dynamic viscosity increases with increasing soot content and decreasing temperature.

Experimental studies have been undertaken on a single-cylinder HPCR diesel engine with a compression ratio of 15.5:1 to explore the effect of fuel injection strategy on cycle by cycle stability. The influence of the number, separation and quantity of pilot injections on the coefficient of variation of IMEP has been investigated at -20°C, 1000 rev/min, post-start idling conditions. Injection strategy and glow plug temperature trade-off has also been investigated at a range of soak temperatures. Up to four pilot injections have been used. For timing of the main injection near to the optimum, CoVIMEP values of 10% or better can be achieved. Closer spacing of injections improved stability and extended the range of timings to meet target stability. The best combinations of pilot number and pilot quantity varied with total fuel delivered.