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This paper has two parts. The first compares the measured burned gas temperature using Coherent Anti-Stokes Raman Scattering (CARS) with the predictions of a multiple zone computer simulation of combustion. The second part describes a system that is capable of determining the heat flux into the combustion chamber by means of measuring the chamber surface temperature. It is shown that the multi-zone computer simulation can accurately predict the burned gas temperature once the fuel burn rate has been analyzed and the model tuned correctly. The effect of different fuels (methane and iso-octane) on the burned gas temperature is reported. A high burn rate or more advanced ignition timing gave a lower burned gas temperature towards the end of the engine cycle. The surface heat flux was deduced from measurements of the surface temperature by using a finite difference method.