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Battery packs of electric vehicles are typically composed of lithium-ion batteries with aluminum and copper acting as cell terminals. These terminals are joined together in series by means of connector tabs to produce sufficient power and energy output. Such critical electrical and structural cell terminal connections involve several challenges when joining thin, highly reflective and dissimilar materials with widely differing thermo-mechanical properties. This may involve potential deformation during the joining process and the formation of brittle intermetallic compounds that reduce conductivity and deteriorate mechanical properties. Among various joining techniques, laser welding has demonstrated significant advantages, including the capability to produce joints with low electrical contact resistance and high mechanical strength, along with high precision required for delicate materials like aluminum and copper.

The development of a comprehensive battery simulator is essential for future improvements in the durability, performance and service life of lithium-ion batteries. Although simulations can never replace actual experimental data, they can still be used to provide valuable insights into the performance of the battery, especially under different operating conditions. In addition, a single-cell model can be easily extended to the pack level and can be used in the optimization of a battery pack. The first step in building a simulator is to create a model that can effectively capture both the voltage response and thermal behavior of the battery. Since these effects are coupled together, creating a robust simulator requires modeling both components. This paper will develop a battery simulator, where the entire battery model will be composed of four smaller submodels: a heat generation model, a thermal model, a battery parameter model and a voltage response model.

In this paper, a degradation testing of a lithium-ion battery used for an electric vehicle (EV) is performed and the capacity fade is measured over 400 cycles. For this, a 200 Ah LiFePO4 battery cell is tested under ambient temperature conditions with charge-discharge cycles at rate of 1C (constant current). Additionally, individual cell characterization is conducted using a C/25 (0.8A) charge-discharge cycle and hybrid pulse power characterization (HPPC). Later, the Thevenin battery model was constructed in MATLAB along with an empirical degradation model and validated in terms of voltage for all cycles. It is also found that the presented model closely estimated the profiles observed in the experimental data. Data collected from the experimental results showed that a capacity fade occurred over the 400 cycles and the discharge capacity at the end of 400th cycle is found to be 137.73 Ah. The error between model/experiments is found to be less than 3.5% for all cycles.

The automobile industry has been undergoing a transition from fossil fuels to a low emission platform due to stricter environmental policies and energy security considerations. Electric vehicles, powered by lithium-ion batteries, have started to attain a noticeable market share recently due to their stable performance and maturity as a technology. However, electric vehicles continue to suffer from two disadvantages that have limited widespread adoption: charging time and energy density. To mitigate these challenges, vehicle Original Equipment Manufacturers (OEMs) have developed different vehicle architectures to extend the vehicle range. This work seeks to compare various powertrains, including: combined power battery electric vehicles (BEV) (zinc-air and lithium-ion battery), zero emission fuel cell vehicles (FCV)), conventional gasoline powered vehicles (baseline internal combustion vehicle), and ICE engine extended range hybrid electric vehicle.

Lithium-ion batteries, which are nowadays common in laptops, cell phones, toys, and other portable electronic devices, are also viewed as a most promising advanced technology for electric and hybrid electric vehicles (EVs and HEVs), but battery manufacturers and automakers must understand the performance of these batteries when they are scaled up to the large sizes needed for the propulsion of the vehicle. In addition, accurate thermo-physical property input is crucial to thermal modeling. Therefore, a designer must study the thermal characteristics of batteries for improvement in the design of a thermal management system and also for thermal modeling. This work presents a purely experimental thermal characterization in terms of measurement of the temperature gradient and temperature response of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration.

The performance, life cycle cost, and safety of electric and hybrid electric vehicles (EVs and HEVs) depend strongly on their energy storage system. Advanced batteries such as lithium-ion (Li-ion) polymer batteries are quite viable options for storing energy in EVs and HEVs. In addition, thermal management is essential for achieving the desired performance and life cycle from a particular battery. Therefore, to design a thermal management system, a designer must study the thermal characteristics of batteries. The thermal characteristics that are needed include the surface temperature distribution, heat flux, and the heat generation from batteries under various charge/discharge profiles. Therefore, in the first part of the research, surface temperature distribution from a lithium-ion pouch cell (20Ah capacity) is studied under different discharge rates of 1C, 2C, 3C, and 4C.

Lithium-ion batteries (LIBs) are one of the best candidates as energy storage systems for automobile applications due to their high power and energy densities. However, durability in comparison to other battery chemistries continues to be a key factor in prevention of wide scale adoption by the automotive industry. In order to design more-durable, longer-life, batteries, reliable and predictive battery models are required. In this paper, an effective model for simulating full-size LIBs is employed that can predict the operating voltage of the cell and the distribution of variables such as electrochemical current generation and battery state of charge (SOC). This predictive ability is used to examine the effect of parameters such as current collector thickness and tab location for the purpose of reducing non-uniform voltage and current distribution in the cell. It is identified that reducing the non-uniformities can reduce the ageing effects and increase the battery durability.

A major challenge in the development of the next generation electric and hybrid electric vehicle (EV and HEV) technology is the control and management of heat generation and operating temperatures. Vehicle performance, reliability and ultimately consumer market adoption are integrally dependent on successful battery thermal management designs. In addition to this, crucial to thermal modeling is accurate thermo-physical property input. Therefore, to design a thermal management system and for thermal modeling, a designer must study the thermal characteristics of batteries. This work presents a purely experimental thermal characterization of thermo-physical properties of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration. In this research, the thermal resistance and corresponding thermal conductivity of prismatic battery materials is evaluated.

In electrified vehicle applications, the heat generated of lithium-ion (Li-ion) cells may significantly affect the vehicle range and state of health (SOH) of the pack. Therefore, a major design task is creation of a battery thermal management system with suitable control and cooling strategies. To this end, the thermal behavior of Li-ion cells at various temperatures and operating conditions should be quantified. In this paper, two different commercial pouch cells for plug-in hybrid electric vehicles (PHEVs) are studied through comprehensive thermal performance tests. This study employs a fractional factorial design of experiments to reduce the number of tests required to characterize the behavior of fresh cells while minimizing the effects of ageing. At each test point, the effects of ambient temperature and charge/discharge rate on several types of cell efficiencies and surface heat generation are evaluated.

In this paper, initial results of Li-ion battery performance characterization through field tests are presented. A fully electrified Ford Escape that is equipped by three Li-ion battery packs (LiFeMnPO4) including an overall 20 modules in series is employed. The vehicle is in daily operation and data of driving including the powertrain and drive cycles as well as the charging data are being transferred through CAN bus to a data logger installed in the vehicle. A model of the vehicle is developed in the Powertrain System Analysis Toolkit (PSAT) software based on the available technical specification of the vehicle components. In this model, a simple resistive element in series with a voltage source represents the battery. Battery open circuit voltage (OCV) and internal resistance in charge and discharge mode are estimated as a function of the state of charge (SOC) from the collected test data.

Despite significant progress toward application of Li-ion batteries in electric vehicles, there are still major concerns about the range of electric vehicles and battery life. Depending on the climate of the region where the vehicle is in use, auxiliary loads could also play a significant role on the battery performance and durability. In this paper, the effect of air conditioning (AC) load on the electric range and Li-ion battery life is evaluated. For this purpose, a thermodynamic model for the vehicle cabin is developed and integrated to a battery model. The thermodynamic model takes the ambient conditions, solar load, and the vehicle drive cycle as inputs and calculates the instantaneous cabin temperature and humidity. The battery model, which represents a Li-on battery pack installed on a fully electrified Ford Escape 2009, consists of a voltage source in series with a lump resistance, a thermal sub-model, and a degradation sub-model to predict the battery capacity fade.

Due to rising fuel prices and environmental concerns, Electric Vehicles (EVs) and Hybrid Electric Vehicles (HEVs) have been gaining market share as fuel-efficient, environmentally friendly alternatives. Lithium-ion batteries are commonly used in EV and HEV applications because of their high power and energy densities. During controls development of HEVs and EVs, hardware-in-the-loop simulations involving real-time battery models are commonly used to simulate a battery response in place of a real battery. One physics-based model which solves in real-time is the reduced-order battery model developed by Dao et al. [1], which is based on the isothermal model by Newman [2] incorporating concentrated solution theory and porous electrode theory [3]. The battery models must be accurate for effective control; however, if the battery parameters are unknown or change due to degradation, a method for estimating the battery parameters to update the model is required.

The analysis of nickel metal hydride (Ni-MH) battery performance is very important for automotive researchers and manufacturers. The performance of a battery can be described as a direct consequence of various chemical and physical phenomena taking place inside the container. In this paper, a physics-based model of a Ni-MH battery will be presented. To analyze its performance, the efficiency of the battery is chosen as the performance measure, which is defined as the ratio of the energy output from the battery and the energy input to the battery while charging. Parametric sensitivity analysis will be used to generate sensitivity information for the state variables of the model. The generated information will be used to showcase how sensitivity information can be used to identify unique model behavior and how it can be used to optimize the capacity of the battery. The results will be validated using a finite difference formulation.

Within the last decade, the automotive industry has made major progress toward the electrification of drive trains and application of electrochemical power sources. Among available storage solutions, Li-ion batteries are considered as the most attractive and are set to be used in the next generation of hybrid and electric vehicles. This is due to their superiority in energy density, power density, and low self-discharge and high cycle life compared to other chemistries. However, there are some limitations associated with Li-ion battery; among them is the operating temperature range. Any deviation from a narrow temperature range may result in low overall performance and potential degradation of the cells. In this paper, impact of ambient temperature on the A123 Li-ion batteries performance is investigated. A123 cells have been tested under constant charge-discharge cycles, hybrid pulse power characterization (HPPC) tests and also standard drive cycle tests.

A series plug-in hybrid electric powertrain with all-wheel drive is designed using real-world drive cycles as part of the EcoCAR 2 competition. A stock 2013 Chevrolet Malibu Eco is being re-engineered to reduce fuel consumption and emissions while improving consumer acceptability. Waterloo utilizes a 18.9 kWh A123 energy storage system (ESS), which powers two 105 kW TM4 traction motors. A 2.4 L LE9 General Motors coupled to a 105 kW TM4 motor provides range extending performance. Each step of the design process is discussed, including a novel approach to powertrain selection and controls requirement selection that uses real-world drive cycles. The mechanical integration and unique ESS design is also discussed.

Due to the high power and energy density and also relative safety, lithium ion batteries are receiving increasing acceptability in industrial applications especially in transportation systems with electric traction such as electric vehicles and hybrid electric vehicles. In this regard, to ensure performance reliability, accurate modeling of calendar life of such batteries is a necessity. In fact, potential failure of Li-ion battery packs remains a barrier to commercialization. Battery pack life is a critical feature to warranty and maintenance planning for hybrid vehicles, and will require adaptive control systems to account for the loss in vehicle range, and loss in battery charge and discharge efficiency. Failure not only results in large replacement costs, but also potential safety concerns such as overheating or short circuiting which may lead to fires.

The effects of propylene (C₃H₆) and dodecane (n-C₁₂H₂₆) exposure on the NH₃-based selective catalytic reduction (SCR) performance of two Cu-exchanged zeolite catalysts were investigated. The first sample was a model Cu/beta zeolite sample and the second a state-of-the-art Cu/zeolite sample, with the zeolite material characterized by relatively small pores. Overall, the state-of-the-art sample performed better than the model sample, in terms of hydrocarbon inhibition (which was reduced) and N₂O formation (less formed). The state-of-the-art sample was completely unaffected by dodecane at temperatures lower than 300°C, and only slightly inhibited (less than 5% conversion loss), for standard SCR, by C₃H₆. There was no evidence of coke formation on this catalyst with C₃H₆ exposure. The model sample was more significantly affected by hydrocarbon exposure. With C₃H₆, inhibition is associated with its partial oxidation intermediates adsorbed on the catalyst surface.

The recent increase in oil prices and environmental concerns have attracted various research efforts on hybrid electric vehicles (HEVs) which provide promising alternatives to conventional engine-powered vehicles with better fuel economy and fewer emissions. To speed up the design and prototyping processes of new HEVs, a method that automatically generates mathematics equations governing the vehicle system response in an optimized symbolic form is desirable. To achieve this goal, we employed MapleSimTM, a new physical modeling tool developed by Maplesoft Inc., to develop the multi-domain model of a series-HEV, utilizing the symbolic computing algorithms of Maple software package to generate an optimized set of governing equations. The HEV model consists of a mean-value internal combustion engine (ICE), a chemistry-based Ni-MH battery pack, and a multibody vehicle model. Simulations are then used to demonstrate the performance of the developed HEV system.

The performance of a commercial Cu-zeolite SCR catalyst after differing degrees of hydrothermal aging (aged for 72 hours at 500, 700 and 800°C with 10% moisture balanced with air) was studied by spatially resolving different key reactions using gas-phase FTIR measurements. Gases were sampled along a channel at different positions and analyzed using FTIR, which overcomes the interference of water and nitrogen on ammonia concentration detection encountered in standard mass spectrometer-based spatial resolution measurements. The NO:NO₂ concentration ratio was changed so that the standard (NO:NO₂ = 1:0), fast (NO:NO₂ = 1:1) and NO₂ (NO:NO₂ = 0:1) SCR reactions could be investigated as a function of the catalyst's hydrothermal aging extent. In addition, the effects of hydrothermal aging on the activity of NH₃ and NO oxidation were also investigated. Hydrothermal aging had little effect on NO oxidation activity.

The response to increasingly stringent light duty diesel emission regulation is a nearly unanimous increase in heavy Exhaust Gas Recirculation (EGR) application to reduce feedgas NOx emissions. Little attention has been paid to the fact that heavy EGR usage is likely to push the engine operating conditions towards less efficient or even unstable regions of conventional centrifugal compressor operating maps. Moreover, the low oxygen content at part load operation also poses transient response challenges. Therefore, improving turbocharger efficiency at part load and extending the stable operating range is becoming critical for viable future low emission diesel engines. In this study of a turbocharger compression system, encompassing the airflow geometry from compressor impeller inlet to volute exit, a dual volute compressor concept was introduced, and Computational Fluid Dynamics (CFD) was used to investigate its effects on the overall expected performance level and range.