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Low-temperature combustion (LTC) strategies have been an active area of research due to their ability to achieve high thermal efficiency while avoiding the formation of NOx and particulate matter. One of the largest challenges with LTC is the relative lack of authority over the heat release rate profile, which, depending on the particular injection strategy, either limits the maximum attainable load, or creates a tradeoff between noise and efficiency at high load conditions. We have shown previously that control over heat release can be dramatically improved through a combination of reactivity stratification in the premixed charge and a diffusion-limited injection that occurs after the conclusion of the low-temperature heat release, in a strategy called direct dual fuel stratification (DDFS).

While Low Temperature Combustion (LTC) strategies such as Reactivity Controlled Compression Ignition (RCCI) exhibit high thermal efficiency and produce low NOx and soot emissions, low load operation is still a significant challenge due to high unburnt hydrocarbon (UHC) and carbon monoxide (CO) emissions, which occur as a result of poor combustion efficiencies at these operating points. Furthermore, the exhaust gas temperatures are insufficient to light-off the Diesel Oxidation Catalyst (DOC), thereby resulting in poor UHC and CO conversion efficiencies by the aftertreatment system. To achieve exhaust gas temperature values sufficient for DOC light-off, combustion can be appropriately phased by changing the ratio of gasoline to diesel in the cylinder, or by burning additional fuel injected during the expansion stroke through post-injection.

3-D Computational Fluid Dynamics (CFD) simulations have been performed to study particulate formation in a Spark-Ignition (SI) engine under premixed conditions. A semi-detailed soot model and a chemical kinetic model, including poly-aromatic hydrocarbon (PAH) formation, were coupled with a spark ignition model and the G equation flame propagation model for SI engine simulations and for predictions of soot mass and particulate number density. The simulation results for in-cylinder pressure and particle size distribution (PSDs) are compared to available experimental studies of equivalence ratio effects during premixed operation. Good predictions are observed with regard to cylinder pressure, combustion phasing and engine load. Qualitative agreements of in-cylinder particle distributions were also obtained and the results are helpful to understand particulate formation processes.

Diesel fuels are complex mixtures of thousands of hydrocarbons. Since modeling their combustion characteristics with the inclusion of all hydrocarbon species is not feasible, a hybrid surrogate model approach is used in the present work to represent the physical and chemical properties of three different diesel fuels by using up to 13 and 4 separate hydrocarbon species, respectively. The surrogates are arrived at by matching their distillation profiles and important properties with the real fuel, while the chemistry surrogates are arrived at by using a Group Chemistry Representation (GCR) method wherein the hydrocarbon species in the physical property surrogates are grouped based on their chemical classes, and the chemistry of each class is represented by using up to two hydrocarbon species.

This research investigates how the handling of mixing and heat transfer in a multi-zone kinetic solver affects the prediction of carbon monoxide and hydrocarbon emissions for simulations of HCCI engine combustion. A detailed kinetics multi-zone model is now more closely coordinated with the KIVA3V computational fluid dynamics code for simulation of the compression and expansion processes. The fluid mechanics is solved with high spatial and temporal resolution (40,000 cells). The chemistry is simulated with high temporal resolution, but low spatial resolution (20 computational zones). This paper presents comparison of simulation results using this enhanced multi-zone model to experimental data from an isooctane HCCI engine.

A computer program which rapidly calculates the equilibrium mole fractions and the partial derivatives of the mole fractions with respect to temperature, pressure and equivalence ratio for the products of combustion of any hydrocarbon fuel and air is described. A subroutine is also given which calculates the gas constant, enthalpy, internal energy and the partial derivatives of these with respect to temperature, pressure and equivalence ratio. Some examples of the uses of the programs are also given.

This paper describes a method for studying reactions of hydrocarbons in S.I. engine exhaust gases. The reaction of ethane is described using an Arrhenius model (experimentally E = 86,500 cal/mole) for the rate of ethane diappearance and empirical correlations for distributions of the products carbon monoxide, ethylene, formaldehyde, methane, acetylene, and propane as a function of the fraction of ethane reacted. The results show that the nature of partial oxidation products from a nonreactive hydrocarbon may be less desirable from an air pollution viewpoint than the initial hydrocarbon.

The purpose of the tests conducted on a single-cylinder laboratory engine was to determine the mechanism of combustion that affect exhaust emissions and the relationship of those mechanisms to engine design and operating variables. For the engine used in this study, the exhaust emissions were found to have the following dependence on various engine variables. Hydrocarbon emission was reduced by lean operation, increased manifold pressure, retarded spark, increased exhaust temperature, increased coolant temperature, increased exhaust back pressure, and decreased compression ratio. Carbon monoxide emission was affected by air-fuel ratio and premixing the charge. Oxides of nitrogen (NO + NO2 is called NOx) emission is primarily a function of the O2 available and the peak temperature attained during the cycle. Decreased manifold pressure and retarded spark decrease NOx emission. Hydrocarbons were found to react to some extent in the exhaust port and exhaust system.

The results of both theoretical and experimental studies on the self-ignition of single pure hydrocarbon drops are described. In this work single drops were subjected to air streams heated to such degrees that self-ignition of the drops would occur. Experimental heat and mass transfer parameters, as well as ignition delay data for different fuels and at different operating conditions were obtained. The experimental data were then used in conjunction with boundary layer correlations to evaluate the extent of the ignition delay that is physical (vaporization) and chemical (molecular interaction).