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The long-term goal of this work is to develop a conceptual model for multiple injections of diesel jets. The current work contributes to that effort by performing a detailed modeling investigation into mechanisms that are predicted to control 1st and 2nd stage ignition in single-pulse diesel (n-dodecane) jets under different conditions. One condition produces a jet with negative ignition dwell that is dominated by mixing-controlled heat release, and the other, a jet with positive ignition dwell and dominated by premixed heat release. During 1st stage ignition, fuel is predicted to burn similarly under both conditions; far upstream, gases at the radial-edge of the jet, where gas temperatures are hotter, partially react and reactions continue as gases flow downstream. Once beyond the point of complete fuel evaporation, near-axis gases are no longer cooled by the evaporation process and 1st stage ignition transitions to 2nd stage ignition.

Experiments were performed on a small-bore optically accessible engine to investigate diesel pilot ignition (DPI) and reactivity controlled compression ignition (RCCI) dual-fuel combustion strategies with direct injection of natural gas and diesel. Parametric variations of pilot ratio were performed. Natural luminosity and OH chemiluminescence movies of the combustion processes were captured at 28.8 and 14.4 kHz, respectively. These data were used to create ignition maps, which aided in comparing the propagation modes of the two combustion strategies. Lower pilot ratios resulted in lower initial heat release rates, and the initial ignition sites were generally smaller and less luminous; for increased pilot ratios the initial portion of the heat release was larger, and the ignition sites were large and bright. Comparisons between diesel pilot ignition and reactivity controlled compression ignition showed differences in combustion propagation mechanisms.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

One of the factors preventing widespread use of Homogeneous Charge Compression Ignition or HCCI is the challenge of controlling the process under transient conditions. Current engine control technology does not have the ability to accurately control the individual cylinder states needed for consistent HCCI combustion. The material presented here is a new approach to engine control using a physics-based individual cylinder real time model to calculate the engine states and then controlling the engine with this state information. The model parameters and engine state information calculated within the engine controller can be used to calculate the required actuator positions so that the desired mass of air, fuel, and residual exhaust gas are achieved for each cylinder event. This approach offers a solution to the transient control problem that works with existing sensors and actuators.

Reactivity Controlled Compression Ignition (RCCI) is an engine combustion strategy that produces low NO and PM emissions with high thermal efficiency. Previous RCCI research has been investigated in single-cylinder heavy-duty engines. The current study investigates RCCI operation in a light-duty multi-cylinder engine at 3 operating points. These operating points were chosen to cover a range of conditions seen in the US EPA light-duty FTP test. The operating points were chosen by the Ad Hoc working group to simulate operation in the FTP test. The fueling strategy for the engine experiments consisted of in-cylinder fuel blending using port fuel-injection (PFI) of gasoline and early-cycle, direct-injection (DI) of diesel fuel. At these 3 points, the stock engine configuration is compared to operation with both the original equipment manufacturer (OEM) and custom-machined pistons designed for RCCI operation.

Heat transfer in internal combustion engines is taking on greater importance as manufacturers strive to increase efficiency while keeping pollutant emissions low and maintaining adequate performance. Wall heat transfer is experimentally evaluated using temperature measurements both on and below the surface using a physical model of conduction in the wall. Three classes of model inversion are used to recover heat flux from surface temperature measurements: analytical methods, numerical methods and inverse heat conduction methods; the latter method has not been previously applied to engine data. This paper details the inherent assumptions behind, required steps for implementation of, and merits and weaknesses of these heat flux calculation methods. The analytical methods, which have been most commonly employed for engine data, are shown to suffer from sensitivity to measurement noise that requires a priori signal filtering.

More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number-based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample-handling methods have been implemented in an engine test cell with a spark-ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion.

The role of the fluid motion in a diesel engine on mixing and combustion was investigated using the CFD code Kiva-3v. The study considered pre-mixed charge compression ignition (PCCI) combustion that is a hybrid combustion system characterized by early injection timings and high amounts of EGR dilution to delay the start and lower the temperature of combustion. The fuel oxidizer mixture is not homogeneous at the start of combustion and therefore requires further mixing for complete combustion. PCCI combustion systems are characterized by relatively high CO and UHC emissions. This work investigates attenuating CO emissions by enhancing mixing processes through non-uniform flowfield motions. The fluid motion was characterized by the amount of average angular rotation about the cylindrical axis (swirl ratio) and the amount of non-uniform motion imparted by the relative amounts of mass inducted through tangential and helical intake ports in a 0.5L HSDI diesel engine.

This study investigates the potential of controlling premixed charge compression ignition (PCCI and HCCI) combustion strategies by varying fuel reactivity. In-cylinder fuel blending using port fuel injection of gasoline and early cycle direct injection of diesel fuel was used for combustion phasing control at both high and low engine loads and was also effective to control the rate of pressure rise. The first part of the study used the KIVA-CHEMKIN code and a reduced primary reference fuel (PRF) mechanism to suggest optimized fuel blends and EGR combinations for HCCI operation at two engine loads (6 and 11 bar net IMEP). It was found that the minimum fuel consumption could not be achieved using either neat diesel fuel or neat gasoline alone, and that the optimal fuel reactivity required decreased with increasing load. For example, at 11 bar net IMEP, the optimum fuel blend and EGR rate for HCCI operation was found to be PRF 80 and 50%, respectively.

The effects of spray targeting on mixing, combustion, and pollutant formation under a low-load, late-injection, low-temperature combustion (LTC) diesel operating condition are investigated by optical engine measurements and multi-dimensional modeling. Three common spray-targeting strategies are examined: conventional piston-bowl-wall targeting (152° included angle); narrow-angle floor targeting (124° included angle); and wide-angle piston-bowl-lip targeting (160° included angle). Planar laser-induced fluorescence diagnostics in a heavy-duty direct-injection optical diesel engine provide two-dimensional images of fuel-vapor, low-temperature ignition (H2CO), high-temperature ignition (OH) and soot-formation species (PAH) to characterize the LTC combustion process.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

The goal of this research is to investigate the physical parameters of stoichiometric operation of a diesel engine under a light load operating condition (6∼7 bar IMEP). This paper focuses on improving the fuel efficiency of stoichiometric operation, for which a fuel consumption penalty relative to standard diesel combustion was found to be 7% from a previous study. The objective is to keep NOx and soot emissions at reasonable levels such that a 3-way catalyst and DPF can be used in an aftertreatment combination to meet 2010 emissions regulation. The effects of intake conditions and the use of group-hole injector nozzles (GHN) on fuel consumption of stoichiometric diesel operation were investigated. Throttled intake conditions exhibited about a 30% fuel penalty compared to the best fuel economy case of high boost/EGR intake conditions. The higher CO emissions of throttled intake cases lead to the poor fuel economy.

The objective of this research is to develop a concept for a low cost, non-intrusive sensor to enable the monitoring of in-cylinder pressure on internal combustion engines. This research should enable the use of cylinder pressure information to be extended into smaller in-service internal combustion engines particularly when “closed loop” control is required to control combustion. This paper details the development results of a new concept for a low cost non-intrusive cylinder pressure sensor utilizing the movement of an engine valve when subjected to cylinder pressure. The conclusions drawn in this paper are that a system for measuring in-cylinder pressure using a valve movement sensor is possible at the required accuracy and could be lower cost than the current best technology.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

Low-temperature combustion (LTC) strategies for diesel engines are of increasing interest because of their potential to significantly reduce particulate matter (PM) and nitrogen oxide (NOx) emissions. LTC with late fuel injection further offers the benefit of combustion phasing control because ignition is closely coupled to the fuel injection event. But with a short ignition-delay, fuel jet mixing processes must be rapid to achieve adequate premixing before ignition. In the current study, mixing and pollutant formation of late-injection LTC are studied in a single-cylinder, direct-injection, optically accessible heavy-duty diesel engine using three laser-based imaging diagnostics. Simultaneous planar laser-induced fluorescence of the hydroxyl radical (OH) and combined formaldehyde (H2CO) and polycyclic aromatic hydrocarbons (PAH) are compared with vapor-fuel concentration measurements from a non-combusting condition.

Homogeneous charge compression ignition (HCCI) combustion is considered to be an attractive alternative to traditional internal combustion engine operation because of its extremely low levels of pollutant emissions. However, there are several difficulties that must be overcome for HCCI practical use, such as difficult ignition timing controllability. Indeed, too early or too late ignition can occur with obvious drawbacks. In addition, the increase in cyclic variation caused by the ignition timing uncertainty can lead to uneven engine operation. As a way to solve the combustion phasing control problem, dual-fuel combustion has been proposed. It consists of a diesel pilot injection used to ignite a pre-mixture of gasoline (or other high octane fuel) and air. Although dual-fuel combustion is an attractive way to achieve controllable HCCI operation, few studies are available to help the understanding of its in-cylinder combustion behavior.

Nowadays for small-scale power generation there are electrochemical batteries and mini engines. Many efforts have been done for improving the power density of the batteries but unfortunately the value of 1 MJ/kg seems to be asymptotic. If the energy source is an organic fuel which has an energy density of around 29 MJ/kg with a minimum overall efficiency of only 3.5%, this device would surpass the batteries. This paper is the fifth of a series of publications aimed to study the HCCI combustion process in the milli domain at high engine speed in order to design and develop VIMPA, Vibrating Microengine for Low Power Generation and Microsystems Actuation. Previous studies ranged from general characterization of the HCCI combustion process by using metal and optical engines, to more specific topics for instance the influence of the boundary layer and quenching distance on the quality of the combustion.

Prior HCCI optical engine experiments utilizing laser-induced fluorescence (LIF) measurements of stratified fuel-air mixtures have demonstrated the utility of probability density function (PDF) statistics for correlating mixture preparation with combustion. However, PDF statistics neglect all spatial details of in-cylinder fuel distribution. The current computational paper examines the effects of spatial fuel distribution on combustion using a novel combination of a 3-D CFD model with a 1-D linear-eddy model of turbulent mixing. In the simulations, the spatial coarseness of initial fuel distribution prior to the start of heat release is varied while keeping PDF statistics constant. Several cases are run, and as the initial mixture is made coarser, combustion phasing monotonically advances due to high local equivalence ratios that persist longer. The effect of turbulent mixing is more complex.

Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.

In HCCI you do not have the same control of the combustion like in SI and Diesel engines. Controlling the start of a combustion event is a difficult task and requires feedback from previous cycles. This feedback can be retrieved from ion current measurements. By applying a voltage over the spark gap, ions will lead a current and a signal that represents the combustion in the cylinder will be retrieved. Voltages of 450 V were used. The paper describes a new method to enhance the combustion phasing from the Ion current trace in HCCI engines. The method is using the knowledge of how the signal should look. This is known due to the fact that the shape of the ion current signal is similar from cycle to cycle. This new observation is shown in the paper. Also the correlation between the ion current and CA50 was studied. Later the signals have been used for combustion feedback.