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For the measurement of NO and NO2 the CLD-analyzer (chemiluminescense detector) has been used for more than twenty-five years. The disadvantage of the CLD is that NO can be measured only. To obtain total NOX (NO+NO2) the exhaust gas sample has to flow through a catalytic converter, which reduces NO2 to NO. The converter has a efficiency between 90 and 100%. For precise NO and NO2 values it is an advantage to analyze NO and NO2 directly. This paper describes a new UV NOX-analyzer for the simultaneous measurement of NO and NO2. Two different configurations, for high and low concentrations, eg. CVS-bag analysis are presented. The performance of the analyzers is documented in comparison to the UV-RAS analyzer with converter for NOX [1] and the conventional CLD-analyzer. The benefits of the new analyzer compared to analyzers equipped with a converter are given in detailed test results.

Sulfur content in gasoline is known to reduce the efficiency of the catalytic converters that are used to reduce pollutants in the exhaust gas of cars. There is some concern that nitrous oxide emissions (N2O) increase when fuel with a high sulfur content is used. The engine out and tailpipe mass emissions of two cars conforming to the California LEV-standard were analyzed. The influence of the fuel sulfur content on the emissions of the regulated and some unregulated pollutants during FTP test cycles was determined. Four fuels covering the range from less than 1 to 330 ppm sulfur content were used. Over that range of fuel sulfur concentration the engine out emissions of sulfur dioxide (SO2 ) of both cars increased. Tailpipe emissions of SO2 were only found at fuel sulfur concentrations of 150 and 330 ppm. For both vehicles a correlation between the N2O emissions and the fuel sulfur content was found.