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Journal Article

The Thermodynamics of Exhaust Gas Condensation

Water vapor is, aside from carbon dioxide, the major fossil fuel combustion by-product. Depending on its concentration in the exhaust gas mixture as well as on the exhaust gas pressure, its condensation temperature can be derived. For typical gasoline engine stoichiometric operating conditions, the water vapor dew point lies at about 53 °C. The exhaust gas mixture does however contain some pollutants coming from the fuel, engine oil, and charge air, which can react with the water vapor and affect the condensation process. For instance, sulfur trioxide present in the exhaust, reacts with water vapor forming sulfuric acid. This acid builds a binary system with water vapor, which presents a dew point often above 100 °C. Exhaust composition after leaving the combustion chamber strongly depends on fuel type, engine concept and operation point. Furthermore, the exhaust undergoes several chemical after treatments.
Journal Article

Sulfur Poisoning of a NOx Storage Catalyst - A Comprehensive Modelling Approach

This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.
Journal Article

Development and Demonstration of LNT+SCR System for Passenger Car Diesel Applications

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.
Journal Article

A Study on Operation Fluid Consumption for Heavy Duty Diesel Engine Application using both, EGR and SCR

This paper describes a method for optimization of engine settings in view of best total cost of operation fluids. Under specific legal NOX tailpipe emissions requirements the engine out NOX can be matched to the current achievable SCR NOX conversion efficiency. In view of a heavy duty long haul truck application various specific engine operation modes are defined. A heavy duty diesel engine was calibrated for all operation modes in an engine test cell. The characteristics of engine operation are demonstrated in different transient test cycles. Optimum engine operation mode (EOM) selection strategies between individual engine operation modes are discussed in view of legal test cycles and real world driving cycles which have been derived from on-road tests.
Journal Article

A Metal Fibrous Filter for Diesel Hybrid Vehicles

Trends towards lower vehicle fuel consumption and smaller environmental impact will increase the share of Diesel hybrids and Diesel Range Extended Vehicles (REV). Because of the Diesel engine presence and the ever tightening soot particle emissions, these vehicles will still require soot particle emissions control systems. Ceramic wall-flow monoliths are currently the key players in the Diesel Particulate Filter (DPF) market, offering certain advantages compared to other DPF technologies such as the metal based DPFs. The latter had, in the past, issues with respect to filtration efficiency, available filtration area and, sometimes, their manufacturing cost, the latter factor making them less attractive for most of the conventional Diesel engine powered vehicles. Nevertheless, metal substrate DPFs may find a better position in vehicles like Diesel hybrids and REVs in which high instant power consumption is readily offered enabling electrical filter regeneration.
Technical Paper

Gasoline HCCI/CAI on a Four-Cylinder Test Bench and Vehicle Engine - Results and Conclusions for the Next Investigation Steps

Internal combustion engines with lean homogeneous charge and auto-ignition combustion of gasoline fuels have the capability to significantly reduce fuel consumption and realize ultra-low engine-out NOx emissions. Group research of Volkswagen AG has therefore defined the Gasoline Compression Ignition combustion (GCI®) concept. A detailed investigation of this novel combustion process has been carried out on test bench engines and test vehicles by group research of Volkswagen AG and IAV GmbH Gifhorn. Experimental results confirm the theoretically expected potential for improved efficiency and emissions behavior. Volkswagen AG and IAV GmbH will utilize a highly flexible externally supercharged variable valve train (VVT) engine for future investigations to extend the understanding of gas exchange and EGR strategy as well as the boost demands of gasoline auto-ignition combustion processes.
Journal Article

Development of the Combustion System for a Flexible Fuel Turbocharged Direct Injection Engine

Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.
Journal Article

Three-Way Catalyst Light-off During the NEDC Test Cycle: Fully Coupled 0D/1D Simulation of Gasoline Combustion, Pollutant Formation and Aftertreatment Systems

The introduction of more stringent standards for engine emissions requires a steady development of engine control strategies in combination with efforts to optimize in-cylinder combustion and exhaust gas aftertreatment. With the goal of optimizing the overall emission performance this study presents the comprehensive simulation approach of a virtual vehicle model. A well established 1D gas dynamics and engine simulation model is extended by four key features. These are models for combustion and pollutant production in the cylinder, a model for the conversion of pollutants in a catalyst and a model for the effect of manifold wall wetting and fuel evaporation. The general species transport feature is linking these model together as it allows to transport an arbitrary number of chemical species in the entire system. Finally this highly detailed engine model is integrated into a vehicle model.
Technical Paper

Comparison of Different EGR Solutions

This paper compares 4 different EGR systems by means of simulation in GT-Power. The demands of optimum massive EGR and fresh air rates were based on experimental results. The experimental data were used to calibrate the model and ROHR, in particular. The main aim was to investigate the influence of pumping work on engine and vehicle fuel consumption (thus CO2 production) in different EGR layouts using optimum VG turbine control. These EGR systems differ in the source of pressure drop between the exhaust and intake pipes. Firstly, the engine settings were optimized under steady operation - BSFC was minimized while taking into account both the required EGR rate and fresh air mass flow. Secondly, transient simulations (NEDC cycle) were carried out - a full engine model was used to obtain detailed information on important parameters. The study shows the necessity to use natural pressure differences or renewable pressure losses if reasonable fuel consumption is to be achieved.
Journal Article

High Performance Cooling and EGR Systems as a Contribution to Meeting Future Emission Standards

In relation to further tightening of the emissions legislation for on-road heavy duty Diesel engines, the future potential of cooled exhaust gas recirculation (EGR) as a result of developments in the cooling systems of such engines has been evaluated. Four basic engine concepts were investigated: an engine with SCR exhaust gas aftertreatment for control of the nitrogen oxides (NOx), an engine with cooled EGR and particulate (PM) filtration, an engine with low pressure EGR and PM filtration and an engine with two stage low temperature cooled EGR also with a particulate filter. A 10.5 litre engine was calibrated and tested under conditions representative for each concept, such that 1.7 g/kWh (1.3 g/bhp-hr) NOx could be achieved over the ESC and ETC. This corresponds to emissions 15% below the Euro 5 legislation level.
Technical Paper

HD Base Engine Development to Meet Future Emission and Power Density Challenges of a DDI™ Engine

This paper describes development challenges for Heavy-Duty (HD) on-highway Diesel Direct Injection (DDI™) engines to meet the extremely advanced US-EPA 2010 (later named US 2010) emission limits while further increasing power density in combination with competitive engine efficiency. It discusses technologies and solutions for lowest engine-out emissions in combination with most competitive fuel consumption values and excellent dynamic behavior. To achieve these challenging targets, base engine hardware requirements are described. In detail the development of EGR systems, especially the challenges of running high EGR rates over the whole engine speed range also at high load, the dynamic EGR control for transient engine operation to achieve lowest NOx emissions at the smoke limit with excellent load response is discussed. Also the effect of the turbo-machinery on power density and transient engine behavior is shown.
Technical Paper

Locally Resolved Measurement of Gas-Phase Temperature and EGR-Ratio in an HCCI-Engine and Their Influence on Combustion Timing

Laser-based measurements of charge temperature and exhaust gas recirculation (EGR) ratio in an homogeneous charge compression ignition (HCCI) engine are demonstrated. For this purpose, the rotational coherent anti-Stokes Raman spectroscopy technique (CARS) was used. This technique allows temporally and locally resolved measurements in combustion environments through only two small line-of-sight optical accesses and the use of standard gasoline as a fuel. The investigated engine is a production-line four-cylinder direct-injection gasoline engine with the valve strategy modified to realize HCCI-operation. CARS-measurements were performed in motored and fired operation and the results are compared to polytropic calculations. Studies of engine speed, load, valve timing, and injection pressure were conducted showing the strong influence of charge temperature on the combustion timing.
Technical Paper

Engine-Independent Exhaust Gas Aftertreatment Using a Burner Heated Catalyst

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.
Technical Paper

NO Laser-Induced Fluorescence Imaging in the Combustion Chamber of a Spray-Guided Direct-Injection Gasoline Engine

In direct-injection gasoline (GDI) engines with charge stratification, minimizing engine-out nitrogen oxide (NOx) emission is crucial since exhaust-gas aftertreatment tolerates only limited amounts of NOx. Reduced NOx production directly lowers the frequency of energy-inefficient catalyst regeneration cycles. In this paper we investigate NO formation in a realistic GDI engine. Quantitative in-cylinder measurements of NO concentrations are carried out via laser-induced fluorescence imaging with excitation of NO (A-X(0,2) band at 248 nm), and subsequent fluorescence detection at 220-240 nm. Engine modifications were kept to a minimum in order to provide results that are representative of practical operating conditions. Optical access via a sapphire ring enabled identical engine geometry as a production line engine. The engine is operated with commercial gasoline (“Super-Plus”, RON 98).
Technical Paper

CSI - Controlled Auto Ignition - the Best Solution for the Fuel Consumption - Versus Emission Trade-Off?

In recent years several new gasoline engine technologies were introduced in order to reduce fuel consumption. Controlled autoignition seems to be an alternative to stratified part load operation, which is handicapped due to it's lean aftertreatment system for world wide application. The principal advantages of controlled auto ignition combustion under steady state operation - combining fuel economy benefits similar to stratified charge systems with nearly negligible NOx and soot emissions - are already well known. With the newly developed AVL- CSI system (Compression and Spark Ignition), a precise combustion control is achieved even under transient operation. For compensation of production and operation tolerances a cost optimized cylinder individual control was developed. Completely new functionalities of the engine management system are applied. This lean GDI concept complies with future emission standards without DeNOx catalyst and can be applied worldwide.
Technical Paper

VVT+Port Deactivation Application on a Small Displacement SI 4 Cylinder 16V Engine: An Effective Way to Reduce Vehicle Fuel Consumption

During recent years several VVT devices have been developed, in order to improve either peak power and low end torque, or part load fuel consumption of SI engines. This paper describes an experimental activity, concerning the integration of a continuously variable cam phaser (CVCP), together with an intake port deactivation device, on a small 4 cylinder 16V engine. The target was to achieve significantly lower fuel consumption under normal driving conditions, compared to a standard MPFI application. A single hydraulic cam phaser is used to shift both the intake and the exhaust cams to retarded positions, at constant overlap. Thus, high EGR rates in the combustion chamber and late intake valve closure (“reverse Miller cycle”) are combined, in order to reduce pumping losses at part load.
Technical Paper

A Study of the Thermochemical Conditions in the Exhaust Manifold Using Secondary Air in a 2.0 L Engine

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.
Technical Paper

New Physical and Chemical Models for the CFD Simulation of Exhaust Gas Lines: A Generic Approach

In the near future the effort on the development of exhaust gas treatment systems must be increased to meet the stringent emission requirements. If the relevant physical and chemical models are available, the numerical simulation is an important tool for the design of these systems. This work presents a CFD model that allows to cover the full range of applications in this area. After a detailed presentation of the theoretical background and the modeling strategies results for the simulation of a close-coupled catalyst are shown. The presented model is also applied to the oxidation of nitrogen oxides, to a diesel particle filter and a fuel-cell reformer catalyst.
Technical Paper

Exhaust Gas Aftertreatment of Volkswagen FSI Fuel Stratified Injection Engines

For substantial reduction of fuel consumption of their vehicle fleet, Volkswagen AG has decided to develop spark-ignition engines with direct fuel injection. To launch this new engine concept with stratified lean operation mode while at the same time meeting the stringent EU IV emission standards, it was necessary to develop a suitable exhaust gas aftertreatment system. This was achieved as part of an intensive co-operation between Volkswagen AG and OMG, formerly dmc2 Degussa Metals Catalysts Cerdec AG. The paper describes the demands for exhaust gas aftertreatment due to lean burn operation. In addition the main development steps of the exhaust gas aftertreatment system for Volkswagen FSI engines and catalyst durability over vehicle lifetime are discussed. Focus is laid on the catalyst system design and coating variations. Volkswagen developed a new closed-loop emission control management system which uses NOx-sensor signals for the first time worldwide.
Technical Paper

Research Results and Progress in LeaNOx II -A Co-operation for Lean NOx Abatement

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.