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This paper aims to validate chemical kinetic mechanisms of surrogate gasoline three components fuel by calculating one-dimensional laminar burning velocity of iso-octane/air mixture. Next, the application of level-set method on premixed combustion without consideration the effect of turbulence eddies on flame front is also studied in three-dimensional computational fluid dynamic (3D-CFD) simulation. In the 3D CFD simulation, there is an option to calculate laminar burning velocity by using empirical correlations, however it is applicable only for particular initial pressure and temperature in spark ignition engine cases. One-dimensional burning velocities from lean to rich of iso-octane/air mixture are calculated by using CHEMKIN-PRO with detailed chemistry and transport phenomena as a function of different equivalence ratios, different unburnt temperature and pressure ranges.

The objective of this paper is to investigate the potential of lean burn combustion to improve the thermal efficiency of spark ignition engine. Experiments used a single cylinder gasoline spark ignition engine fueled with primary reference fuel of octane number 90, running at 4000 revolution per minute and at wide open throttle. Experiments were conducted at constant fueling rate and in order to lean the mixture, more air is introduced by boosted pressure from stoichiometric mixture to lean limit while maintaining the high output engine torque as possible. Experimental results show that the highest thermal efficiency is obtained at excess air ratio of 1.3 combined with absolute boosted pressure of 117 kPa. Three dimensional computational fluid dynamic simulation with detailed chemical reactions was conducted and compared with results obtained from experiments as based points.

We have constructed a quasi-2-dimensional NH₃-SCR model with detailed surface reactions to analyze the NOx conversion mechanism and reasons for its inhibition at low temperatures. The model consists of seven detailed surface reactions proposed by Grozzale et al., and calculates longitudinal gas flow, gas phase-catalyst phase mass transfer, and mass diffusion within the catalyst phase in the depth dimension. Using the model, we have analyzed the results of pulsed ammonia (NH₃) feed tests at various catalyst temperatures, and results show that ammonium nitrate (NH₄NO₃) is the inhibitor in NH₃-SCR reactions at low temperatures. In addition, we found that cutting the supply of NH₃ causes decomposition of NH₄NO₃, providing surface ammonia (NH₄+), which rapidly reacts with adjacent NOx, leading to an instantaneous rise in nitrogen (N₂) formation.

Model based control design is an important method for optimizing engine operating conditions so as to simultaneously improve engines' thermal efficiency and emission profiles. Modeling of intake system that includes an intake throttle valve, an EGR valve and a variable geometry turbocharger was constructed based on conservation laws combined with maps. Calculated results were examined the predictive accuracy of fresh charge mass flow, EGR rate and boost pressure.

Compared with petroleum fuel, liquefied petroleum gas (LPG) demonstrates advantages in low CO₂ emission. This is because of propane (C₃H₈), n-butane (n-C₄H₁₀) and i-butane (i-C₄H₁₀), which are the main components of LPG, making H/C ratio higher. In addition, LPG is suitable for high efficient operation of a spark ignition (SI) engine due to its higher research octane number (RON). Because of these advantages, that is, diversity of energy source and reduction of CO₂, in the past several years, LPG vehicles have widely been used as the alternate gasoline vehicles all over the world. Consequently, it is absolutely essential for the performance increase in LPG vehicles to comprehend combustion characteristics of LPG. In this study, the differences of laminar burning velocity between C₃H₈, n-C4H10, i-C₄H₁₀ and regular gasoline were evaluated experimentally with the use of a constant volume combustion chamber (CVCC).

To facilitate research and development of diesel engines, the universal numerical code for predicting diesel combustion has been favored for the past decade. In this paper, the finite-rate elementary chemical reactions, sometimes called the detailed chemical reactions, are introduced into the KIVA-3V code through the use of the Partially Stirred Reactor (PaSR) model with the KH-RT break-up, modified collision and velocity interpolation models. Outcomes were such that the predicted pressure histories have favorable agreements with the measurements of single and double injection cases in the diesel engine for use in passenger cars. Thus, it is demonstrated that the present model will be a useful tool for predicting ignition and combustion characteristics encountered in the cylinder.

An experimental and numerical study has been conducted on the emission and reduction of HCHO (formaldehyde) and other pollutants formed in the cylinder of a direct-injection diesel engine fueled by methanol. Engine tests were performed under a variety of intake conditions including throttling, heating, and EGR (exhaust gas recirculation) for the purpose of improving these emissions by changing gas compositions and combustion temperatures in the cylinder. Moreover, a detailed kinetics model was developed and applied to methanol combustion to investigate HCHO formation and the reduction mechanism influenced by associated elementary reactions and in-cylinder mixing.