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Compared with petroleum fuel, liquefied petroleum gas (LPG) demonstrates advantages in low CO₂ emission. This is because of propane (C₃H₈), n-butane (n-C₄H₁₀) and i-butane (i-C₄H₁₀), which are the main components of LPG, making H/C ratio higher. In addition, LPG is suitable for high efficient operation of a spark ignition (SI) engine due to its higher research octane number (RON). Because of these advantages, that is, diversity of energy source and reduction of CO₂, in the past several years, LPG vehicles have widely been used as the alternate gasoline vehicles all over the world. Consequently, it is absolutely essential for the performance increase in LPG vehicles to comprehend combustion characteristics of LPG. In this study, the differences of laminar burning velocity between C₃H₈, n-C4H10, i-C₄H₁₀ and regular gasoline were evaluated experimentally with the use of a constant volume combustion chamber (CVCC).