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Technical Paper

Solid State Electrochemical Cell for NOx Reduction

1992-08-03
929418
An electrochemical cell is presented which reduces NOx emissions from a vehicle fueled by dedicated natural gas. The cell is comprised of a honeycomb shaped ceramic which is chemically coated with an electrically conductive material in two distinct regions which serve as electrodes such that, with the application of a voltage potential, a cathode and anode are formed. As the exhaust gas flows through the inner channels of the cell, the electrochemical reduction of NOx at the cathode yields nitrogen gas and oxide ions. The nitrogen continues to flow through the cell while the oxide ions dissolve in the solid electrolyte. At the anodic zone, oxide ions are converted to oxygen gas. The pressure drop across the cell was experimentally measured to insure that the back pressure created by the cell does not create a significant reduction in the efficiency of the engine.
Technical Paper

Analysis of RF Corona Discharge Plasma Ignition

1992-08-03
929502
Corona discharge from a RF quarter wave coaxial cavity resonator is considered as a plasma ignition source for spark ignited (SI) internal combustion (IC) engines. The gaseous discharge processes associated with this device are analyzed using principles of gas kinetics and gaseous electronics, with assumed values for the electric field strength. Corona discharge occurs when the electric field shaped and concentrated by a single electrode exceeds the breakdown potential of the surrounding gas. Ambient electrons, naturally present due to ionizing radiation, drift in the direction of the externally applied field, gaining energy while undergoing elastic collisions with neutral molecules. After gaining sufficient energy they dissociate, excite, or ionize the neutral particles through inelastic collision, creating additional electrons. This process leads to avalanche electrical breakdown of the gas within about 10-8 sec.
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