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Further growth of diesel engines in the light-duty and heavy-duty vehicular market is closely linked to the potential health risks of diesel exhaust. The California Air Resources Board and the Office of Environmental Health Hazard Assessment have identified diesel exhaust as a toxic air contaminant. The International Agency for Research on Cancer concluded that diesel particulate is a probable human carcinogen [1]. Cleaner burning liquid fuels, such as those derived from natural gas via the Fischer-Tropsch (FT) process, offer a potentially economically viable alternative to standard diesel fuel while providing reduced particulate emissions. Further understanding of FT operation may be realized by investigating the differences in toxicity and potential health effects between particulate matter(PM) derived from FT fuel and that derived from standard Federal diesel No. 2 (DF).

The emissions reduction of Fischer-Tropsch (FT) diesel fuel has been demonstrated in several recent publications in both laboratory engine testing and in-use vehicle testing. Reduced emission levels have been attributed to several chemical and physical characteristics of the FT fuels including reduced density, ultra-low sulfur levels, low aromatic content and high cetane rating. Some of the effects of these attributes on the combustion characteristics in diesel engines have only recently been documented. In this study, a Ricardo Proteous, single-cylinder, 4-stroke DI engine is instrumented for in-cylinder pressure measurements. The engine was run at several steady engine states at multiple timing conditions using both federal low sulfur and natural gas derived FT fuels. The emissions and performance data for each fuel at each steady state operating conditions were compared.

Specific aspects of a study aimed at developing a microwave assisted regeneration system for diesel particulate traps are discussed. Results from thermal and microwave characteristic studies carried out in the initial phase of the study are reported. The critical parameters that need to be optimized, for achieving controlled regeneration, are microwave preheating time period, regenerative air supply, regenerative air temperature, and soot deposition. Using a 1000 W magnetron, power measurements were made to select the best waveguide configuration for optimized transmission. A six cylinder naturally aspirated, indirect injection diesel engine was retrofitted with a customized exhaust system that included a Corning EX80 (5.66″ × 6.00″) type ceramic particulate trap. An automated exhaust bypass system enabled trap loading and subsequent regeneration with a customized microwave regeneration system. The paper discusses the salient details of both on-line and off-line regeneration setups.

Diesel soot interacts with the engine oil and leads to wear of engine parts. Engine oil additives play a crucial role in preventing wear by forming the anti-wear film between the wearing surfaces. The current study was aimed at investigating the interactions between engine soot and oil properties in order to develop high performance oils for diesel engines equipped with exhaust gas re-circulation (EGR). The effect of soot contaminated oil on wear of engine components was examined using a statistically designed experiment. To quantitatively analyze and simulate the extent of wear a three-body wear machine was designed and developed. The qualitative wear analysis was performed by examining the wear scars on an AISI 52100 stainless steel ball worn in the presence of oil test samples on a ball-on-flat disc setup. The three oil properties studied were base stock, dispersant level and zinc dithiophosphate level.

This paper presents results from a study on speciation of the emission profiles and on the ozone forming potential of heavy-duty diesel exhaust under steady state engine operation. Very limited attempts have been made at determining the ozone forming potential of heavy duty diesel exhaust emissions. In this study a proportional sample of the dilute exhaust was drawn from a CFV-CVS system using a temperature controlled sampling line. The particulate matter was collected on a 70 mm Teflon coated glass fiber filter (TX40HI20WW), the semi-volatiles on XAD-2 copolymer resin and volatiles in Tedlar bags. The samples were analyzed by gas chromatography after conditioning and chemical extractions. The initial phase of the study was directed towards developing techniques and establishing protocols to determine the ozone forming potential of heavy-duty diesel exhaust. A pre-chamber naturally aspirated engine was tested on steady-state modes 1, 3, 5, 7 and 8 of the ISO 8 mode cycle.

Data has been gathered using the West Virginia University Heavy Duty Transportable Emissions Laboratories from buses operating on diesel and a variety of alternate fuels in the field. Typically, the transportable chassis dynamo meter is set up at a local transit agency and the selected buses are tested using the fuel in the vehicle at the time of the test. The dynamometer may be set up to operate indoors or outdoors depending on the space available at the site. Samples of the fuels being used at the site are collected and sent to the laboratory for analysis and this information is then sent together with emissions data to the Alternate Fuels Data Center at the National Renewable Energy Laboratory. Emissions data are acquired from buses using the Central Business District cycle reported in SAE Standard J1376; this cycle has 14 ramps with 20 mph (32.2 km/h) peaks, separated by idle periods.

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

The federal emission standards for heavy duty vehicle engines require the exhaust emissions to be measured and calculated in unit form as grams per break horse-power-hour (g/bhp-hr). Correct emission results not only depend on the precise emission measurement but also rely on the correct determination of vehicle energy consumption. A Transportable Heavy-Duty Vehicle Emission Testing Laboratory (THDVETL) designed and constructed at West Virginia University provides accurate vehicle emissions measurements in grams over a test cycle. This paper contributes a method for measuring the energy consumption (bhp-hr) over the test cycle by a chassis dynamometer. Comparisons of analytical and experimental results show that an acceptable agreement is reached and that the THDVETL provides accurate responses as the vehicle is operated under transient loads and speeds. This testing laboratory will have particular value in comparing the behavior of vehicles operating on alternative fuels.

Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a Caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8″ x 10″ hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential.