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Technical Paper

Development of the HyStEP Device

2016-04-05
2016-01-1190
With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.
Technical Paper

Retail Infrastructure Costs Comparison for Hydrogen and Electricity for Light-Duty Vehicles

2014-04-01
2014-01-1969
Both hydrogen and plug-in electric vehicles offer significant social and environmental benefits to enhance energy security and reduce criteria and greenhouse gas emissions from the transportation sector. However, the rollout of electric vehicle supply equipment (EVSE) and hydrogen retail stations (HRS) requires substantial investments with high risks due to many uncertainties. We compare retail infrastructure costs on a common basis - cost per mile, assuming fueling service to 10% of all light-duty vehicles in a typical 1.5 million person city in 2025. Our analysis considers three HRS sizes, four distinct types of EVSE and two distinct EVSE scenarios. EVSE station costs, including equipment and installation, are assumed to be 15% less than today's costs. We find that levelized retail capital costs per mile are essentially indistinguishable given the uncertainty and variability around input assumptions.
Journal Article

Overcoming the Range Limitation of Medium-Duty Battery Electric Vehicles through the use of Hydrogen Fuel-Cells

2013-09-24
2013-01-2471
Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption.
Technical Paper

Cost Comparison of Wind Energy Delivered as Electricity or Hydrogen for Vehicles

2013-04-08
2013-01-1038
A simple cost analysis framework compares hydrogen and electricity as energy carriers delivering wind energy to light-duty vehicles (LDVs). We compare four wind energy pathways within a 2040-2050 timeframe and at large scale: a dedicated electricity transmission pathway and three distinct wind-hydrogen delivery pathways. Our results suggest that wind-hydrogen pathways will tend to be more costly than pure electricity transmission pathways on a per-mile driven cost basis ($/mile), but to a greater or lesser degree depending upon the pathway. The additional cost could be warranted to the degree that the hydrogen pathway adds value to consumers through full performance fuel cell electric vehicles (FCEV) compared to plug-in electric vehicles (PEVs), or through reduced variability in wind energy supply. If these benefits add value beyond the incremental costs suggested by our simple cost framework, some shift toward co-production or even dedicated hydrogen wind farms may be warranted.
Technical Paper

Innovative Dense Lightweight Design for On-Board Hydrogen Storage Tank

2012-09-24
2012-01-2061
The hydrogen economy envisioned in the future requires safe and efficient means of storing hydrogen fuel for either use on-board vehicles, delivery on mobile transportation systems or high-volume storage in stationary systems. The main emphasis of this work is placed on the high -pressure storing of gaseous hydrogen on-board vehicles. As a result of its very low density, hydrogen gas has to be stored under very high pressure, ranging from 350 to 700 bars for current systems, in order to achieve practical levels of energy density in terms of the amount of energy that can be stored in a tank of a given volume. This paper presents 3D finite element analysis performed for a composite cylindrical tank made of 6061-aluminum liner overwrapped with carbon fibers subjected to a burst internal pressure of 1610 bars. As the service pressure expected in these tanks is 700 bars, a factor of safety of 2.3 is kept the same for all designs.
Technical Paper

Quantification of Biodiesel Content in Fuels and Lubricants by FTIR and NMR Spectroscopy

2006-10-16
2006-01-3301
The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).
Technical Paper

The Department of Energy's Hydrogen Safety, Codes, and Standards Program: Status Report on the National Templates1

2006-04-03
2006-01-0325
A key to the success of the national hydrogen and fuel cell codes and standards developments efforts to date was the creation and implementation of national templates through which the U.S. Department of Energy (DOE), the National Renewable Energy Laboratory (NREL), and the major standards development organizations (SDOs) and model code organizations coordinate the preparation of critical standards and codes for hydrogen and fuel cell technologies and applications and maintain a coordinated national agenda for hydrogen and fuel cell codes and standards
Technical Paper

Predicting the Fuel Economy Impact of “Cold-Start” for Reformed Gasoline Fuel Cell Vehicles

2003-06-23
2003-01-2253
Hydrogen fuel cell vehicles (FCVs) appear to be a promising solution for the future of clean and efficient personal transportation. Issues of how to generate the hydrogen and then store it on-board to provide satisfactory driving range must still be resolved before they can compete with conventional vehicles. Alternatively, FCVs could obtain hydrogen from on-board reforming of gasoline or other fuels such as methanol or ethanol. On-board reformers convert fuel into a hydrogen-rich fuel stream through catalytic reactions in several stages. The high temperatures associated with fuel processing present an engineering challenge to warm up the reformer quickly and efficiently in a vehicle environment. Without a special warmup phase or vehicle hybridization, the reformer and fuel cell system must provide all power to move the vehicle, including ¼ power in 30 s, and ½ power in 3 min to satisfy the Federal Test Procedure (FTP) cycle demands.
Technical Paper

Water and Heat Balance in a Fuel Cell Vehicle with a Sodium Borohydride Hydrogen Fuel Processor

2003-06-23
2003-01-2271
The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.
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