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Li-ion power battery is the core component of the electric vehicle power system, and the battery temperature will increase because of the electrochemical reaction of the Li-ion battery. The heat accumulates inside of the battery, which can degrade the working performance of the power battery and shorten the battery cycle life. At present, the wind cooling technology is relatively mature. However, it cannot achieve ideal heat dissipation effect under the working conditions of the high-power or high ambient temperature. In this research, the battery thermal management is carried out by the characteristics of the working fluid’s flowing phase change heat transfer. The phase change working fluid is R-1233zd(E) which is a kind of environmentally friendly liquid with nonconductive and nonflammable. It can achieve the purpose of controlling the battery’s temperature using the characteristics of isothermal heat absorption under different gas phase rate of phase change working fluid.