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Proton Exchange Membrane (PEM) Fuel Cell (FC) presents itself as a promising technology in view of zero-tailpipe emission vehicles. In addition, the constant development of renewable energy sources will lead to an increase in green hydrogen availability, and thus completely eliminate emissions for devices that use H2 as an energy vector. However, PEM FCs are still far from being fully developed as a technology: thermal and water management are the main issues that researchers are studying through experiments and Computational Fluid Dynamics (CFD) simulations. For the numerical approach, H2O removal models often consider a simplified flat surface, but the microgeometry of the Gas Diffusion Layer (GDL) has a leading role in determining the critical dimension for droplet detachment and how much resistance the surface poses to water sliding. The aim of this paper is to investigate the influence of droplets number on a GDL.

It is well known that ethanol can be used in spark-ignition (SI) engines as a pure fuel or blended with gasoline. High enthalpy of vaporization of alcohols can affect air-fuel mixture formation prior to ignition and may form thicker liquid films around the intake valves, on the cylinder wall and piston crown. These liquid films can result in mixture non-homogeneities inside the combustion chamber and hence strongly influence the cyclic variability of early combustion stages. Starting from these considerations, the paper reports an experimental study of the initial phases of the combustion process in a single cylinder SI engine fueled with commercial gasoline and anhydrous ethanol, as well as their blend (50%vol alcohol). The engine was optically accessible and equipped with the cylinder head of a commercial power unit for two-wheel applications, with the same geometrical specifications (bore, stroke, compression ratio).

This paper reports the study of the effects of alternative diesel fuel and the impact for the air-fuel mixture preparation. The injection process characterization has been carried out in a non-evaporative high-density environment in order to measure the fuel injection rate and the spatial and temporal distribution of the fuel. The injection and vaporization processes have been characterized in an optically accessible single cylinder Common Rail diesel engine representing evaporative conditions similar to the real engine. The tests have been performed by means of a Bosch second generation common rail solenoid-driven fuel injection system with a 7-holes nozzle, flow number 440 cc/30s @100bar, 148deg cone opening angle (minisac type). Double injection strategy (pilot+main) has been implemented on the ECUs corresponding to operative running conditions of the commercial EURO 5 diesel engine.

The match among the increasing performance demands and the stringent requirements of emissions and the fuel consumption reduction needs a strong evolution in the two-wheel vehicle technology. In particular, many steps forward should be taken for the optimization of modern small motorcycles and scooters at low engine speeds and high loads. To this aim, detailed understanding of thermo-fluid dynamic phenomena that occur in the combustion chamber is fundamental. In this work, low-cost solutions are proposed to optimize ported fuel injection spark ignition (PFI SI) engines for two-wheel vehicles. The solutions are based on the change of phasing and on the splitting of the fuel injection in the intake manifold. The experimental activities were carried out in the combustion chamber of a single-cylinder 4-stroke optical engine fuelled with European commercial gasoline. The engine was equipped with a four-valve head of a commercial scooter engine.

High spatial and temporal resolution optical techniques were applied in a spark ignition (SI) engine in order to investigate the thermal and fluid dynamic phenomena occurring during the combustion process. The experiments were realized in the combustion chamber of an optically accessible single-cylinder port-fuel injection (PFI) SI engine. The engine was equipped with a four-valve head and with an external boost device. Two fuel injection strategies at closed-valve and open-valve occurring at wide open throttle were tested. Cycle-resolved digital imaging was used to follow the flame kernel growth and flame front propagation. Moreover, the effects of an abnormal combustion due to the firing of fuel deposition near the intake valves and on the piston surface were investigated. Natural emission spectroscopy in a wide wavelength range from ultraviolet to infrared was applied to detect the radical species that marked the combustion phenomena in the selected operating conditions.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

The flame front propagation in normal and abnormal combustion was investigated. Cycle-resolved flame emission imaging was applied in the combustion chamber of a port fuel injection boosted spark ignition engine. The engine was fuelled with a mixture of 90% iso-octane and 10% n-heptane by volume (PRF90). The effect of fuel injection phasing was studied. The combustion process was followed from the flame kernel formation until the opening of the exhaust valves. Different phenomena correlated to the abnormal combustion were analysed. Detailed information on ignition surfaces, end-gas auto-ignitions and knock were obtained. The appearance of autoignition centres in the end gas was evaluated in terms of timing, location and frequency of occurrence.

Electronic engine controls based on non-intrusive diagnostics can significantly help in complying with the stricter and stricter regulations on pollutants emissions and fuel consumption. The aim of this paper is the use of a low-cost linear capacitive accelerometer placed on the engine block for non-intrusive diagnosis of combustion process in spark ignition engines. In particular, good correspondences between the engine block vibrations and the combustion pressure signal were obtained. The angular position of pressure peak evaluated by accelerometer data can be used in a closed-loop control system for real time control of spark advance.

An experimental evaluation of the impact of the diesel/biodiesel blends is presented in terms of engine performances and pollutant emission analysis. In-cylinder combustion evolution and injection law characterization were carried out on a single cylinder engine, on an optical single cylinder engine and on an injection test rig. Different diesel/biodiesel blends were tested at three operating points, representative of the NEDC cycle. Increasing the biodiesel percentage a reduction mainly in terms of smoke emission was observed. The engine performance as well as the other pollutant emissions were not substantially changed. Therefore this study confirms the benefits of the biodiesel use also on the current automotive engines, reducing simultaneously their environmental impact in terms of GHG and smoke emissions.

A satisfactory answer to the future severe normative on emissions and to the market request for spark ignition engines seems to be the use of downsized engines for passenger cars. Downsizing permits the increase in engines power and torque without the increase in cylinder capacity. The downsizing benefits are evident at part loads; on the other hand, more work should be done to optimize boosted engines at higher and full load. To this goal, a detailed knowledge of the thermo-fluid dynamic processes that occur in the combustion chamber is fundamental. The aim of this paper is the experimental investigation of the effect of the fuel injection in the intake manifold on the combustion process and pollutant formation in a boosted spark ignition (SI) engine. The experiments were performed on a partially transparent single-cylinder port fuel injection (PFI) SI engine, equipped with a four-valve head and boost device.

A 1-D thermo-fluid dynamic simulation code, including a quasi-D combustion model coupled with a detailed kinetic scheme, is used to analyze the combustion process in HCCI engines. The chemical mechanism has previously been validated in comparison with experimental data over a wide range of operating conditions. To explore the impact on model predictions, the cylinder was divided into multiple zones to characterize the conditions of the in-cylinder charge. Particular attention is devoted to the numerical algorithm in order to ensure the robustness and efficiency of the large system solution. This numerical model allows study of the autoignition of the air fuel mixture and determines the chemical evolution of the system. The proposed model was compared with in-cylinder temperature and chemical species profiles. The experimental activity was carried out in the combustion chamber of a single cylinder air cooled engine operating in HCCI mode.

The growing demands on fuel economy and always stricter limitations on pollutant emissions has increased the interest in the ignition phenomena to guarantee successful flame development for all the spark ignition (SI) engine operating conditions. The initial size and the growth of the flame have a strong influence on the further development of the combustion process. In particular, for the new FIAT generation of turbocharged SI engines, the first times of spark ignition combustion are not yet fully understood. This is mainly due to the missing knowledge concerning the detailed physical and chemical processes taking place during the all set of the flame propagation. These processes often occur simultaneously, making difficult the interpretation of measurements. In the present paper, flame dynamic was followed by UV-visible emission imaging in an optical SI engine.

Aim of this work is to develop a general purpose model for combustion and knocking prediction in SI engines, by coupling a thermo-fluid dynamic model for engine simulation with a general detailed kinetic scheme, including the low-temperature oxidation mechanism, for the prediction of the auto-ignition behavior of hydrocarbons. A quasi-D approach is used to describe the in-cylinder thermodynamic processes, applying the conservation of mass and energy over the cylinder volume, modeled as a single open system. The complex chemistry model has been embedded into the code, by using the same integration algorithm for the conservation equations and the reacting species, and taking into account their mutual interaction in the energy balance. A flame area evolution predictive approach is used to evaluate the turbulent flame front propagation as function of the engine operating parameters.

This work presents a general model for the prediction of octane numbers and knock propensity of different fuels in SI engines. A detailed kinetic scheme of hydrocarbon oxidation is coupled with a two zone, 1-D thermo-fluid dynamic simulation code (GASDYN) [1]. The validation of the kinetic scheme is discussed on the basis of recent experimental measurements. CFR engine simulations for RON and MON evaluation are presented first to demonstrate the capabilities of the coupled model. The model is then used to compare the knock propensity of a gasoline “surrogate” (a pure hydrocarbon mixture) and PRFs in a current commercial engine, resulting in a simulation of “real world” octane number determination, such as Bench Octane Number (BON). The simulation results agree qualitatively with typical experimental trends.

This paper describes the development, application and comparison of two different non-linear numerical codes, respectively based on a 1D and 3D schematization of the geometrical domain, for the prediction of the acoustic behavior of common silencing devices for i.c. engine pulse noise abatement. A white noise approach has been adopted and applied to predict the attenuation curves of silencers in the frequency domain, while a non-reflecting boundary condition was used to represent an anechoic termination. Expansion chambers, Helmholtz and column resonators, Herschel-Quincke tubes have been simulated by both the 1D and the 3D codes and the results compared to the available linear acoustic analytical solutions. Finally, a hybrid approach, in which the CFD code has been integrated with the 1D model, is described and applied to the simulation of a single cylinder engine. The computed results are compared to the measured pressure waves and emitted sound pressure level spectra.

This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.

Aim of this work is to present and discuss the possibility and the limits of two zone models for spark-ignition engines using a detailed kinetic scheme for the characterization of the evolution of the air-fuel mixture, while an equilibrium approach is used for the burnt zone. Simple experimental measurements of knocking tendency of different fuels in ideal reactors, such as rapid compression machines and shock tube reactors, cannot be directly used for the analysis of octane numbers and sensitivity of hydrocarbon mixtures. Thus a careful investigation is very useful, not only of the combustion chamber behavior, including the modelling of the turbulent flame front propagation, but also of the fluid dynamic behavior of the intake and exhaust system, accounting for the volumetric efficiency of the engine.

The paper describes the results of a parallel 1D thermo-fluid dynamic simulation and experimental investigation of a DI turbocharged Diesel engine. The attention has been focused on the overall engine performances (air flow, torque, power, fuel consumption) as well as on the emissions (NO and particulate) along the after-treatment system, which presents a particulate filter. The 1D research code GASDYN for the simulation of the whole engine system has been enhanced by the introduction of a multi-zone quasi-dimensional combustion model for direct injection Diesel engines. The effect of multiple injections is taken into account (pilot and main injection). The prediction of NO and soot has been carried out respectively by means of a super-extended Zeldovich mechanism and by the Hiroyasu kinetic approach.

The paper describes the development and validation of a quasi-dimensional multi-zone combustion model for Gasoline Direct Injection engines. The model has been embedded in the 1D thermo-fluid-dynamic code for the simulation of the whole engine system named GASDYN and developed by the authors [1, 2 and 3]. The GDI engine combustion model solves mass, energy and species equations using a 4th order Runge-Kutta integration method; the fuel spray is initially divided into a number of zones fixed regardless of the injected amount and the time step, considering the following break-up, droplet evaporation and air entrainment in each single zone. Experimental correlations have been used for the spray penetration and spatial information. Once the ignition begins it is assumed that the flame propagates spherically, evaluating its velocity by means of a fractal combustion approach and considering the local air-fuel ratio, which is the result of the spray evolution within the combustion chamber.

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.