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Technical Paper

A Three-Way Catalyst Model for a Bio-Methane Heavy-Duty Engine: Characterization at Different Lambda

2024-04-09
2024-01-2084
Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio.
Technical Paper

Experimental and Numerical Investigation of a Particle Filter Technology for NG Heavy-Duty Engines

2023-04-11
2023-01-0368
The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.
Technical Paper

Methane Conversion and Ammonia Formation Model over a Pd-Rh Three-Way Catalyst for CNG Heavy-Duty Engines

2021-09-05
2021-24-0002
Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.
Technical Paper

Development of a Dedicated CNG Three-Way Catalyst Model in 1-D Simulation Platforms

2019-09-09
2019-24-0074
A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.
Technical Paper

Assessment of Engine Control Parameters Effect to Minimize GHG Emissions in a Dual Fuel NG/Diesel Light Duty Engine

2018-04-03
2018-01-0266
The interest in Natural Gas (NG) as alternative fuel for transportation is constantly growing, mostly due to its large availability and lower environmental impact with respect to gasoline or diesel fuel. In this scenario, the application of the Dual Fuel (DF) Diesel- Natural Gas (NG) combustion concept to light duty engines can represent an important route to increment the diffusion of natural gas use. Many studies have proven the benefits of DF with respect to conventional diesel combustion in terms of CO2, NOx, PM and PN emissions, with the main drawback of high unburned hydrocarbon, mainly at low/partial engine loads. This last aspect still prevents the application of DF mode to small displacement engines. In the present work, a 2.0 L Euro 5 compliant diesel engine, equipped with an advanced electronic closed-loop combustion control (CLCC) system, has been set up to operate in DF mode and tested on a dyno test bench.
Technical Paper

How Much Regeneration Events Influence Particle Emissions of DPF-Equipped Vehicles?

2017-09-04
2017-24-0144
Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.
Technical Paper

Parametric Analysis of the Effect of Pilot Quantity, Combustion Phasing and EGR on Efficiencies of a Gasoline PPC Light-Duty Engine

2017-09-04
2017-24-0084
In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions.
Technical Paper

Hydrocracked Fossil Oil and Hydrotreated Vegetable Oil (HVO) Effects on Combustion and Emissions Performance of “Torque-Controlled” Diesel Engines

2015-09-06
2015-24-2497
The present paper describes the results of a research activity aimed at studying the potential offered by the use of Hydrocracked fossil oil (HCK) and Hydrotreated Vegetable Oil (HVO) blends as premium fuels for next generation diesel engines. Five fuels have been tested in a light duty four cylinder diesel engine, Euro 5 version, equipped with closed loop control of the combustion. The set of fuels comprises four experimental fuels specifically formulated by blending high cetane HVO and HCK streams and oneEN590-compliant commercial diesel fuel representative of the current market fuel quality. A well consolidated procedure has been carried out to estimate, for the tested fuels, the New European Driving Cycle (NEDC) vehicle performance by means of the specific emissions at steady-state engine operating points.
Journal Article

Analysis of Nozzle Coking Impact on Emissions and Performance of a Euro5 Automotive Diesel Engine

2013-09-08
2013-24-0127
The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.
Technical Paper

Emission Reduction Technologies for the Future Low Emission Rail Diesel Engines: EGR vs SCR

2013-09-08
2013-24-0087
The EU emission standards for new rail Diesel engines are becoming even more stringent. EGR and SCR technologies can both be used to reduce NOx emissions; however, the use of EGR is usually accompanied by an increase in PM emissions and may require a DPF. On the other hand, the use of SCR requires on-board storage of urea. Thus, it is necessary to study these trade-offs in order to understand how these technologies can best be used in rail applications to meet new emission standards. The present study assesses the application of these technologies in Diesel railcars on a quantitative basis using one and three dimensional numerical simulation tools. In particular, the study considers a 560 kW railcar engine with the use of either EGR or SCR based solutions for NOx reduction. The NOx and PM emissions performances are evaluated over the C1 homologation cycle.
Technical Paper

Analysis of Diesel Injector Nozzle Flow Number Impact on Emissions and Performance of a Euro5 Automotive Diesel Engine

2012-04-16
2012-01-0891
The present paper describes the results of a research project aimed at studying the impact of nozzle flow number on a Euro5 automotive diesel engine, featuring Closed-Loop Combustion Control. In order to optimize the trade-offs between fuel economy, combustion noise, emissions and power density for the next generation diesel engines, general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle hole size. In this context, three nozzle configurations have been characterized on a 2.0L Euro5 Common Rail Diesel engine, coupling experimental activities performed on multi-cylinder and optical single cylinder engines to analysis on spray bomb and injector test rigs. More in detail, this paper deeply describes the investigation carried out on the multi-cylinder engine, specifically devoted to the combustion evolution and engine performance analysis, varying the injector flow number.
Technical Paper

Impact of Biodiesel on Particle Emissions and DPF Regeneration Management in a Euro5 Automotive Diesel Engine

2012-04-16
2012-01-0839
Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.
Technical Paper

Combustion Behaviour and Emission Performance of Neat and Blended Polyoxymethylene Dimethyl Ethers in a Light-Duty Diesel Engine

2012-04-16
2012-01-1053
The combustion behaviour, the mechanisms of soot formation, and the emission performance of a mixture of polyoxymethylene dimethyl ethers (POMDME) oligomers with a number of oxymethylene units ranging from 3 to 5, both neat and blended at 12.5% and 50% levels with commercial diesel fuel have been investigated. The goals were a first evaluation of the POMDME impact on the diesel injector behaviour, on the combustion process as well as on the emission performance of a light duty engine. Then a brief screening on the capability to improve the NOx-PM trade-off using POMDME by means of the exhaust gas recirculation (EGR) rate increment was also assessed.
Journal Article

Determination of Oxidation Characteristics and Studies on the Feasibility of Metallic Nanoparticles Combustion Under ICE-Like Conditions

2011-09-11
2011-24-0105
The present work relates to the investigation of the basic oxidation characteristics of iron and aluminium nanoparticles as well as the feasibility of their combustion under both Internal Combustion Engine (ICE)-like and real engine conditions. Based on a series of proof-of-concept experiments, combustion was found to be feasible taking place in a controllable way and bearing similarities to the respective case of conventional fuels. These studies were complimented by relevant in-situ and ex-situ/post-analysis, in order to elaborate the fundamental phenomena occurring during combustion as well as the extent and ‘quality’ of the process. The oxidation mechanisms of the two metallic fuels appear different and -as expected- the energy release during combustion of aluminium is significantly higher than that released in the case of iron.
Journal Article

Impact of RME and GTL Fuel on Combustion and Emissions of a “Torque-Controlled” Diesel Automotive Engines

2010-05-05
2010-01-1477
The present paper describes some results of a research project aimed at studying the impact of alternative fuels blends on the emissions and fuel consumption of an Euro 5 automotive diesel engine. Two alternative fuels were chosen for the experiments: RME and GTL. The tests were done in the three most important operating conditions for the engine emission calibration. Moreover, the NOx-PM trade-off by means of EGR sweep was performed in the same operating conditions, in order to evaluate the engine EGR tolerability when burning low sooting fuels as the RME. The investigations put in evidence that the impact of the alternative fuels on modern diesel engines remains significant. This also depends on the interaction between the alternative fuel characteristics and the engine-management strategies, as described in detail in the paper.
Journal Article

Experimental Investigation of the Benefits of Cooled and Extra-cooled Low-Pressure EGR on a Light Duty Diesel Engine Performance

2009-09-13
2009-24-0126
The present paper describes an experimental study on the application of a Low Pressure EGR system, equipped with an high efficiency cooler, to a LD diesel engine operating with both conventional combustion and PCCI mode. The research activity is aimed to carry out an analysis of the potentiality of the cooling (with engine water at 90°C) and super-cooling (with external water at 20°C) of the low pressure EGR flow gas on the simultaneous reduction of fuel consumption and pollutant emissions. The effects were evaluated running the engine with diesel conventional combustion and PCCI mode in several engine operating points. The employed engine was a 4-cyliders LD CR diesel engine of two liters of displacement at the state of art of the current engine technology. The overall results identified benefits on both the fuel consumption and emissions with the use of a low pressure EGR system with respect to the “classical” high pressure EGR one.
Technical Paper

The Effect of “Clean and Cold” EGR on the Improvement of Low Temperature Combustion Performance in a Single Cylinder Research Diesel Engine

2008-04-14
2008-01-0650
In the present paper, the effect of the clean and cold EGR flow on the performance of a diesel engine running under conventional and Low Temperature Combustion conditions is investigated by means of experimental tests on a single-cylinder research engine. The engine layout was “ad hoc” designed to isolate the effect of the clean and cold recirculated gas flow on the combustion quality. The results have shown that the thermodynamic temperature is the main factor affecting the engine performances, while the effect of a cleaner EGR flow, in terms of lower smoke and unburned compounds (HC and CO), is negligible.
Technical Paper

Experimental Analysis of the Operating Parameter Influence on the application of Low Temperature Combustion in the Modern Diesel Engines

2007-07-23
2007-01-1839
The present paper describes the effects of some operating parameters on the performance of a single cylinder research engine when it runs under Low Temperature Combustion (LTC) conditions. Aim of the experimental work was to explore the potential of the control of each parameter on the improvement of LTC application to the modern LD diesel engines for passenger cars. In particular, the effects on LTC performance of the following operating parameters in different engine test points were analyzed: intake air temperature, exhaust EGR cooler temperature, intake pipe pressure, exhaust pipe pressure and swirl ratio. Some parameters have shown a particular influence on the improvement of EGR tolerability for maximum NOx reduction preserving fuel consumption and smoke, while others have evidenced poor sensitivity.
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