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The premixed charge compression ignition (PCCI) combustion in a compression ignition (Cl) engine is one of countermeasures against the very much severe regulation for exhaust gas of engine out. The authors have been proposed to use the fuel mixed with high volatility component and low volatility component to actualize PCCI combustion. This kind of fuel injected forms a fine and lean spray by the flash boiling phenomena which depends on the pressure and the temperature. The role of the former fuel is to decrease in the generation of particulate matters (PM) and that of the latter one is to break out the ignition. Thus, it is very much significant to find the distribution of vapor concentration of both fuels in a spray. This paper describes both distributions in a single diesel spray by use of the technique of laser induced fluorescence (LIF) in a constant volume chamber with high temperature at high pressure as the fundamental research.

LES of non-evaporative diesel spray have been performed to investigate the effects of breakup models of Modified TAB, WAVE and KHRT model on computational results. KIVALES that is LES version of KIVA code was used for base code. In our KIVALES, CIP scheme was incorporated in order to suppress the numerical diffusion. Results showed that the breakup model is significantly affected on the calculated spray shape, because the droplet diameter determined by breakup models affects on the transmittance of the droplet momentum into the ambient gas, the evolution of the vortex structure in the gas phase and the droplet dispersion by the vortex structure.

It is very much necessary for researchers and engineers whose work is the field of combustion in a CI engine to find the information of droplets in a diesel spray. The information is strongly required to construct the model of spray built in the numerical code for its simulation and to be used for the verification of the accuracy of the calculation. This paper describes the photographing system with high spatial resolution, the distribution of droplet size and the vortex scale caused by the droplets motion by means of this system.

Three-dimensional large eddy simulation (LES) has been conducted for a diesel spray flame using KIVALES which is LES version of KIVA code. Modified TAB model, velocity interpolation model and rigid sphere model are used to improve the prediction of the fuel-mixture process in the diesel spray. Combustion is simulated using the Eddy-Dissipation model. CIP method was incorporated into the KIVALES in order to suppress the numerical instability on the combustible flow. The formation of soot and NO was simulated using Hiroyasu model and KIVA original model. Three different grid resolutions were used to examine the grid dependency. The result shows that the LES approach with 0.5 mm grid size is able to resolve the instantaneous spray with the intermittency in the spray periphery, the axi-symmetric shape and meandering flow after the end of injection as shown in the experimental results.

A diesel engine operating in premixed charge compression ignition (PCCI) mode promises the reduction of engine-out emissions of NOx and particulate matter. A serious issue for PCCI operation with the early injection timing during the compression stroke is the difficulty of controlling the mixture formation process. In this study, a mixed fuel consisting of high volatility fuel and high ignitability one is applied in order to develop a control technique for the mixture preparation. In particular, we focuses on a flash boiling phenomenon of mixed fuel. For pure substance, the quality of flashing spray is dominated by the degree of superheat. In contrast, that of mixed fuel is affected much by low boiling point fuel.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

A single cylinder engine has been run with direct-injection premixed charge compression ignition (PCCI) operation. The operation is fueled with primary reference fuels for a wide variety of injection timing and equivalence ratio to investigate the effect of charge stratification and octane rating on PCCI combustion. The test results showed that although the change of the injection timing can gain the high combustion efficiency for a wide range of equivalence ratio, the combustion phasing where the high combustion efficiency is accomplished is not varied only by changing the injection timings. Therefore, the only change of injection timings does not improve the thermal efficiency which is influenced by the combustion phasing. On the other hand, at the fixed compression ratio, inlet air temperature and so on, the octane rating is useful in altering the combustion phasing.

The authors have explored the potential of fuel to control spray and its combustion processes in a diesel engine. Fuel has some potential for low emission and high thermal efficiency because its volatility and ignitability are one of the ultimate performing factors of the engines. In present study, the ignition process of mixed fuel spray was investigated in a constant volume combustion vessel and in a rapid compression and expansion machine, The ignition delay based on the diagram of rate of the heat release, the imaging of natural flame emissions and the numerical simulation were carried out to clarify the effect of the physical and chemical properties of mixed fuel on ignition characteristics.

It is very significant to take the intermediate products in diesel combustion for understanding the generation of exhaust emissions like SOF, dry soot and so on. The products generated in a constant volume combustion chamber were sampled by pricking a sheet of polyester film installed in the chamber to freeze the chemical reaction. The gas was analyzed by a gas chromatography. The fuel used was n-heptane. It is able to explain the generation of exhaust emissions by the experimental results. The other objective is to simulate the intermediate products. It is capable of explaining the relation between the simulated and experimental results.

The mixed fuel composed of two kinds of fuel oil whose boiling temperature is different each other forms the fine spray with minute droplets when its condition crosses over the two-phase region. It is expected that the fuel with low volatility dominates the ignition delay and that with high volatility does the generation of particulate matter. The experiments were carried out in a rapid compression and expansion machine and in an actual high-speed small sized diesel engine by use of this kind of fuel. The experimental results prove this expectation.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

This work investigates the soot formation process in diesel jet flame using a detailed kinetic soot model implemented into the KIVA-3V multidimensional CFD code and 2D imaging by use of time-resolved laser induced incandescence (LII). The numerical model is based on the KIVA code which is modified to use CHEMKIN as the chemistry solver using Message Passing Interface (MPI). This allows for the chemical reactions to be simulated in parallel on multiple CPUs. The detailed soot model used is based on the method of moments, which begins with fuel pyrolysis, followed by the formation of polycyclic aromatic hydrocarbons, their growth and coagulation into spherical particles, and finally, surface growth and oxidation of the particles. The model can describe the spatial and temporal characteristics of soot formation processes such as soot precursors distributions, nucleation rate and surface reaction rate.

This work presents the ignition delay time characteristics of oxygenated fuel sprays under simulated diesel engine conditions. A constant volume combustion vessel is used for the experiments. The fuels used in the experiments were three oxygenated fuels: diethylene glycol dibutyl ether, diethylene glycol diethyl ether, and diethylene glycol dimethyl ether. JIS 2nd class gas oil was used as the reference fuel. The ambient gas temperature and oxygen concentration were ranging from 700 to 1100K and from 21 to 9%, respectively. The results show that the ignition delay of each oxygenated fuel tested in this experiments exhibits shorter than that of gas oil fuel for the wide range of ambient gas conditions. Also, NTC (negative temperature coefficient) behavior which appears under shock tube experiment for homogenous fuel-air mixture was observed on low ambient gas oxygen concentration for each fuel. And at the condition, the ignition behavior exhibits two-stage phase.

This paper provides new insights on the mechanism of the smokeless diesel combustion with oxygenated fuels, based on a combination of soot kinetic modeling and optical diagnostics. The chemical effects of fuel compositions, including aromatics - paraffins blend, neat oxygenated fuels and oxygenate additives, on sooting equivalence ratio ‘ϕ’ - temperature ‘T’ dependence were numerically examined using a detailed soot kinetic model. To better understand the physical factors affecting soot formation in oxygenated fuel sprays, the effects of injection pressure and ambient gas temperature on the flame lift-off length and relative soot concentration in oxygenated fuel jets were experimentally investigated. The computational results show that the leaner mixture side of soot formation peninsula on the ϕ - T map, rather than the lower temperature one, should be utilized to suppress the formation of PAHs and ultra-fine particles together with the large reduction in particulate mass.

Fuel design for internal combustion engines has been proposed in our study. In this concept, the multicomponent fuel with high and low volatility fuels are used in order to control the spray and combustion processes in internal combustion engine. Therefore, it is necessary to understand the spray and combustion characteristics of the multicomponent fuels in detail. In the present study, the modeling of multicomponent spray vaporization was conducted using KIVA3V code. The physical fuel properties of multicomponent fuel were estimated using the source code of NIST Mixture Property Database. Peng-Robinson equation of state and fugacity calculation were applied to the estimation of liquid-vapor equilibrium in order to take account for non-ideal vaporization process. Two-zone model in which fuel droplet was divided into droplet surface and inner core was introduced in order to simply consider the temperature distribution in fuel droplet.

In this study, the novel fuel design concept has been proposed in order to realize the low emission and combustion control in engine systems. In this fuel design concept, the mixed fuels with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components) are used in order to improve the spray characteristics by flash boiling. In our previous papers on this study, the fundamental characteristics of spray and its combustion of mixed fuel were reported. In this paper, heat release and exhaust emission (smoke, NOx and THC) characteristics of single cylinder diesel engine operated with the mixed fuels were investigated under each load. The exhaust performance of diesel engine could be improved using mixed fuel, because fuel properties and spray characteristics were controlled by changing mixing fraction of the mixed fuel.

Considering the bell-shaped temperature dependence of soot particle formation, the control of flame temperature has a possibility to drastically suppress of soot formation. Furthermore, oxygenated fuels are very effective on soot reduction, and the use of these kinds of fuels has a potentiality for smokeless diesel combustion. In this paper, the effects of flame lift-off and flame temperature on soot formation in oxygenated fuel sprays were experimentally investigated using a constant volume combustion vessel which simulated diesel engine conditions. The diffusion flame lift-off length was measured in order to estimate the amount of the oxygen entrained upstream of the flame lift-off length in the fuel jet. This was determined from time-averaged OH chemiluminescence imaging technique. Also, the flame temperature and soot concentration were simultaneously evaluated by means of two-color method.

In an SI engine with direct injection of gasoline (DGI), many small droplets disperse in premixed gas in the cylinder. In a CI engine, diesel spray is injected a cylinder, thus, the situation at the spray periphery is almost the same as that of DGI SI engine. From the standpoint it is useful for understanding the combustion phenomena in both engines to experiment the combined combustion of premixed gas where many small droplets exist. This paper describes this kind of combustion and it seems to be able to apply the results to the simulation of combustion in these engines.

This paper analyzes heterogeneous distribution of branch-like structure at downstream region of the diesel spray. The liquid and vapor phase of the spray are obtained by a 35mm still camera and CCD camera in order to investigate spray structure of evaporative diesel spray. The many previous studies about diesel spray structure have yet stayed in the analyses of 2-D structure, and there is little information which is concerned with 3-D structure analysis of evaporative spray. The heterogeneous distribution of droplets in inner spray affects the mixture formation of diesel spray, and the combustion characteristics of the diesel engines. In this study, the laser beam of 2-D plane was used in order to investigate 3-D structure of evaporative spray. The incident laser beam was offset on central axis of the spray.

In the actual spray combustion fields, coupled combustion process should be occurred, between the pre-evaporate fuel component and remaining liquid droplets. Therefore it is insufficient to clarify the fundamental spray combustion mechanism with use of only droplet or only premixed mixture analyze method. In this study, the premixed mixture - droplets coupled combustion field was focused as a model of the actual spray combustion field. In the experiments, the effect of the flame pattern and the combustion rate constant by the interference between the droplets were clarified with the variation of fuels used by droplets. Besides, the effect of the premixed gas surrounding the droplets was clarified by the experiment on coupled combustion. The experiments were carried out under the normal gravity field and the micro gravity field to estimate the effect of convection in combustion field