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The prediction of knock onset in spark-ignition engines requires a chemical model for the autoignition of the hydrocarbon fuel-air mixture, and a description of the unburned end-gas thermal state. Previous studies have shown that a reduced chemistry model developed by Keck et al. adequately predicts the initiation of autoignition. However, the combined effects of heat transfer and compression on the state of the end gas have not been thoroughly investigated. The importance of end-gas heat transfer was studied with the objective of improving the ability of our knock model to predict knock onset over a wide range of engine conditions. This was achieved through changing the thermal environment of the end gas by either varying the inlet air temperature or the coolant temperature. Results show that there is significant heating of the in-cylinder charge during intake and a substantial part of the compression process.

A rapid compression machine for chemical kinetic studies has been developed. The design objectives of the machine were to obtain: 1)uniform well-defined core gas; 2) laminar flow condition; 3) maximum ratio of cooling to compression time; 4) side wall vortex containment; and, 5) minimum mechanical vibration. A piston crevice volume was incorporated to achieve the side wall vortex containment. Tests with inert gases showed the post-compression pressure matched with the calculated laminar pressure indicating that the machine achieved these design objectives. Measurements of ignition delays for homogeneous PRF/O2/N2/Ar mixture in the rapid compression machine have been made with five primary reference fuels (ON 100, 90, 75, 50, and 0) at an equivalence ratio of 1, a diluent (s)/oxygen ratio of 3.77, and two initial pressures of 500 Torr and 1000 Torr. Post-compression temperatures were varied by blending Ar and N2 in different ratios.

This paper describes experimental and theoritical studies of a turbulent combustion bomb. We find a correlation between heat transfer to the wall and the Initial turbulence intensity. Wall temperature and pressure measurements were made for three levels of initial turbulence. All tests were performed with an equivalence ratio of 1.0, and the turbulence intensity was controlled by varying the time delay between mixture intake and spark ignition. Assuming one-dimensional conduction, the surface heat flux was computed from the wall temperature data. Gas temperatures were computed from the pressure data assuming isentropic compression. Based on turbulent velocity measurements made in previous studies, these results permitted a correlation of Nusselt number with turbulent Reynolds number. Using this correlation, we estimate the heat transfer in the end gas and its effect on the gas temperature.

A model for predicting the performance and emissions characteristics of Wankel engines has been developed and tested. Each chamber is treated as an open thermodynamic system and the effects of turbulent flame propagation, quench layer formation, gas motion, heat transfer and seal leakage are included. The experimental tests were carried out on a Toyo Kogyo 12B engine under both motoring and firing conditions and values for the effective seal leakage area and turbulent heat transfer coefficient were deduced. The agreement between the predicted and measured performances was reasonable. Parametric studies of the effects of reductions in seal leakage and heat transfer were carried out and the results are presented.

A performance model of a Wankel engine is developed which performs a leakage mass balance, accounts for heat transfer and flame quenching, and predicts the mass fraction burned as a function of chamber pressure. Experiments were performed on a production Wankel engine to obtain chamber pressure-time diagrams, and engine performance and emissions data. Model predictions of mass burned, global heat transfer, and hydrocarbon emission gave good agreement with measurements. Predictions of oxides of nitrogen are higher than measurements, especially at low loads. This is thought to be due to the adiabatic core gas assumption in the model. The need for a Wankel boundary layer study is identified.