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Second generation biomass is an attractive renewable feedstock for transport fuels. Its sulfur content is generally negligible and the carbon cycle is reduced from millions to tens of years. One hitherto non-valorized feedstock are so-called humins, a residual product formed in the conversion of sugars to platform chemicals, such as hydroxymethylfurfural and methoxymethylfurfural, intermediates in the production of FDCA, a building block used to produce the polyethylene furanoate (PEF) bottle by Avantium. The focus of this study is to investigate the spray combustion behavior of humins as a renewable alternative for heavy fuel oil (HFO) under large two-stroke engine-like conditions in an optically accessible constant volume chamber.

Recently introduced sulfur caps on marine fuels in so-called sulfur emission control areas (SECAs) are forcing shipping companies to sail on more or less automotive grade diesel in lieu of the considerably less expensive, but sulfur-laden heavy fuel oil (HFO) to which they were accustomed. This development is an opportunity for a bio-based substitute, given that most biomass is sulfur free by default. Moreover, given that biomass is typically solid to start with, cracking it to an HFO grade, which is highly viscous in nature, will involve fewer and/or less harsh process steps than would be the case if an automotive grade fuel were to be targeted. In this study, a renewable low sulfur heavy fuel oil (LSHFO) has been produced by means of subcritical water assisted lignin depolymerization in the presence of a short length surfactant, ethylene glycol monobutyl ether (EGBE).

Owing to environmental and health concerns, tetraethyl lead was gradually phased out from the early 1970's to mid-1990's in most developed countries. Advances in refining, leading to more aromatics (via reformate) and iso-paraffins such as iso-octane, along with the introduction of (bio) oxygenates such as MTBE, ETBE and ethanol, facilitated the removal of lead without sacrificing RON and MON. In recent years, however, legislation has been moving in the direction of curbing aromatic and olefin content in gasoline, owing to similar concerns as was the case for lead. Meanwhile, concerns over global warming and energy security have motivated research into renewable fuels. Amongst which are those derived from biomass. The feedstock of interest in this study is lignin, which, together with hemicellulose and cellulose, is amongst the most abundant organic compounds on the planet.

Lignocellulosic biomass consists of (hemi-) cellulose and lignin. Accordingly, an integrated biorefinery will seek to valorize both streams into higher value fuels and chemicals. To this end, this study evaluated the overall combustion performance of both cellulose- and lignin derivatives, namely the high cetane number (CN) di-n-butyl ether (DnBE) and low CN anisole, respectively. Said compounds were blended both separately and together with EN590 diesel. Experiments were conducted in a single cylinder compression ignition engine, which has been optimized for improved combustion characteristics with respect to low emission levels and at the same time high fuel efficiency. The selected operating conditions have been adopted from previous “Tailor-Made Fuels from Biomass (TMFB)” work.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

A Gasoline Compression Ignition combustion strategy was developed and showed its capabilities in the heavy duty single cylinder test-cell, resulting in indicated efficiencies up to 50% and low engine out emissions applying to EU VI and US 10 legislations while the soot remained at a controllable 1.5 FSN. For this concept a single-cylinder CI-engine was used running at a lambda of ∼1.6 and EGR levels of ∼50% and a modified injection strategy. Part of this strategy was also the use of a gasoline blended with an ignition improver, giving the blend a cetane number in the range of regular diesel; ∼50. In this paper a step is taken towards implementation of this combustion concept into a multi-cylinder light duty standalone CI-engine. A standard CI-engine was modified so that its gas-exchange system could deliver the requested amounts of EGR and lambda.

In an earlier study, a novel type of diesel fuel injector was proposed. This prototype injects fuel via porous (sintered) micro pores instead of via the conventional 6-8 holes. The micro pores are typically 10-50 micrometer in diameter, versus 120-200 micrometer in the conventional case. The expected advantages of the so-called Porous Fuel Air Mixing Enhancing Nozzle (PFAMEN) injector are lower soot- and CO2 emissions. However, from previous in-house measurements, it has been concluded that the emissions of the porous injector are still not satisfactory. Roughly, this may have multiple reasons. The first one is that the spray distribution is not good enough, the second one is that the droplet sizing is too big due to the lack of droplet breakup. Furthermore air entrainment into the fuel jets might be insufficient. All reasons lead to fuel rich zones and associated soot formation.

A literature and experimental study was done to create an overview of the behavior of gasoline combusted in a CI-engine. This paper creates a first overview of the work to be done before implementing this Gasoline Compression Ignition concept in a multi-cylinder engine. According to literature the gasoline blend will have advantages over diesel. First the shorter molecular chain of the gasoline makes it less prone to soot. Second the lower density gives the gasoline a higher nozzle exit speed resulting in better mixing capabilities. Third the lower density and higher volatility lets the spray length decrease. This lowers the chance of wall-impingement, but creates worse mixing conditions looking from a spray point of view. The CO and HC emissions tend to increase relative to operation with diesel fuel, NOx emissions largely depend on the choice of combustion strategy and could be influenced by the nitrogen bound to the EHN molecule that is used as an ignition improver.

This paper illustrates the results of an experimental study on the impact of a low cetane number (CN) oxygenated fuel on the combustion process and emissions of a light-duty (LD) single-cylinder research engine. In an earlier study, it was concluded that cyclic oxygenates consistently outperformed their straight and branched counterparts at equal oxygen content and with respect to lowering soot emissions. A clear correlation was reported linking soot and CN, with lower CN fuels leading to more favorable soot levels. It was concluded that a lower CN fuel, when realized by adding low reactive cyclic oxygenates to commercial diesel fuel, manifests in longer ignition delays and thus more premixing. Ultimately, a higher degree of premixing, in turn, was thought to suppress soot formation rates.

It is well known that the addition of gaseous fuels to the intake manifold of diesel engines can have significant benefits in terms of both reducing emissions of hazardous gases and soot and improving fuel economy. Particularly, the addition of LPG has been investigated in numerous studies. Drawbacks, however, of such dual fuel strategies can be found in storage complexity and end-user inconvenience. It is for this reason that on-board refining of a single fuel (for example, diesel) could be an interesting alternative. A second-generation fuel reformer has been engineered and successfully tested. The reformer can work with both gaseous and liquid fuels and by means of partial oxidation of a rich fuel-air mix, converts these into syngas: a mixture of H₂ and CO. The process occurs as partial oxidation takes place in an adiabatic ceramic reaction chamber. High efficiency is ensured by the high temperature inside the chamber due to heat release.

The goal of this paper is to acquire insight into the influence of cetane number (CN) and fuel oxygen on overall engine performance in the Premixed Charge Compression Ignition (PCCI) combustion mode. From literature, it is known that low reactive (i.e., low CN) fuels increase the ignition delay (ID) and therefore the degree of mixing prior to auto-ignition. With respect to fuel oxygen, it is known that this has a favorable impact on soot emissions by means of carbon sequestration. This makes the use of low CN oxygen fuels an interesting route to improve the applicability of PCCI combustion in diesel engines. In earlier studies, performed on a heavy-duty engine, cyclic oxygenates were found to consistently outperform their straight and branched counterparts with respect to curbing soot. This was attributed to a considerably lower CN.

The main goal of this paper is to acquire more insight into the relationship between wall and piston impingement of liquid fuel and unburnt hydrocarbon emissions (UHC) emissions, under early direct injection (EDI) premixed charge compression ignition (PCCI) operating conditions. To this end, the vaporization process is modeled for various operating conditions using a commercial CFD code (StarCD). Predicted values for liquid core penetration, or liquid length LL , have been successfully checked against experimental data from literature over a wide range of operating conditions. Next, the correlation between the CFD results for wall and piston impingement and measured UHC emissions is studied. The diesel fuel used in the experiments is modeled as n-dodecane and n-heptadecane, representing the low and high end of the diesel boiling range, respectively. A distinction is made between liquid spray impingement on the piston surface and cylinder liner.