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Water is of critical importance to space missions due to crew needs and the cost of supply. To control mission costs, it is essential to recycle water from all available wastes - both solids and liquids. Water recovery from liquid water wastes has already been accomplished on space missions. For instance, a Water Recycling System (WRS) is currently operational on the International Space Station (ISS). It recovers water from urine and humidity condensate and processes it to potable water specifications. However, there is more recoverable water in solid wastes such as uneaten food, wet trash, feces, paper and packaging material, and brine. Previous studies have established the feasibility of obtaining a considerable amount of water and oxygen from these wastes (Pisharody et al, 2002; Fisher et al, 2008; Wignarajah et al, 2008).

Since the mid 1980s, NASA has developed advanced waste management technologies that collect and process waste. These technologies include incineration, hydrothermal oxidation, pyrolysis, electrochemical oxidation, activated carbon production, brine dewatering, slurry bioreactor oxidation, composting, NOx control, compaction, and waste collection. Some of these technologies recover resources such as water, oxygen, nitrogen, carbon dioxide, carbon, fuels, and nutrients. Other technologies such as the Waste Collection System (WCS - the commode) collect waste for storage or processing. The need for waste processing varies greatly depending upon the mission scenario. This paper reviews the waste management technology development activities conducted by NASA since the mid 1980s and explores the drivers that determine the application of these technologies to future missions.

Management of human feces and wastes is a major challenge in space vehicles due to the potential biohazards and malodorous compounds emanating during collection and storage of feces and wastes. To facilitate safe, yet realistic human waste management research, we have previously developed human fecal simulants for research activities. The odoriferous compounds in feces and wastes reduce the quality of life for astronauts, can reduce performance, and can even cause health problems. The major odoriferous compounds of concern belong to four groups of chemicals, volatile fatty acids, volatile sulfurous compounds, nitrogenous compounds and phenols. This paper attempts to review the problem of odor detection and odor control with advanced technology. There has been considerable progress in odor detection and control in the animal industry and in the dental profession.

Handling and processing human feces in space habitats is a major concern and needs to be addressed for the Crew Exploration Vehicle (CEV) as well as for future exploration activities. In order to ensure crew health and safety, feces should either be isolated in a dried form to prevent microbial activity, or be processed to yield a non-biohazardous product using a reliable technology. During laboratory testing of new feces processing technologies, use of “real” feces can impede progress due to practical issues such as safety and handling thereby limiting experimental investigations. The availability of a non-hazardous simulant or analogue of feces can overcome this limitation. Use of a simulant can speed up research and ensure a safe laboratory environment. At Ames Research Center, we have undertaken the task of developing human fecal simulants. In field investigations, human feces show wide variations in their chemical/physical composition.

Pyrolysis processing of solid waste in space will inevitably lead to carbon formation as a primary pyrolysis product. The amount of carbon depends on the composition of the starting materials and the pyrolysis conditions (temperature, heating rate, residence time, pressure). Many paper and plastic materials produce almost no carbon residue upon pyrolysis, while most plant biomass materials or human wastes will yield up to 20-40 weight percent on a dry, as-received basis. In cases where carbon production is significant, it can be stored for later use to produce CO2 for plant growth. Alternatively it can be partly gasified by an oxidizing gas (e.g., CO2, H2O, O2) in order to produce activated carbon. Activated carbons have a unique capability of strongly absorbing a great variety of species, ranging from SO2 and NOx, trace organics, mercury, and other heavy metals.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid liquid and/or gaseous products. The main disadvantages of pyrolysis processing are: (1) the product stream is more complex than for many of the alternative treatments; (2) the product gases cannot be vented directly into the cabin without further treatment because of the high CO concentrations. One possible solution is to combine a pyrolysis step with catalytic oxidation (combustion) of the effluent gases. This integration takes advantage of the best features of each process, which is insensitivity to product mix, no O2 consumption, and batch processing, in the case of pyrolysis, and simplicity of the product effluent stream in the case of oxidation. In addition, this hybrid process has the potential to result in a significant reduction in Equivalent System Mass (ESM) and system complexity.

Newly outlined missions in the Vision for U.S. Space Exploration include extended human habitation on Mars. During these missions, large amounts of waste materials will be generated in solid, liquid and gaseous form. Returning these wastes to Earth will be extremely costly, and increase the opportunity for back contamination. Therefore, it is advantageous to investigate the potential for wastes to remain on Mars after mission completion. Untreated, these wastes are a reservoir of live/dead organisms and molecules considered “biomarkers” (i.e., indicators of life). If released to the planetary surface, these materials can potentially interfere with exobiology studies, disrupt any existent martian ecology and pose human safety concerns. Waste Management (WM) systems must therefore be specifically designed to control release of problematic materials both during the active phase of the mission, and for any specified post-mission duration.

One of the major problems associated with solid waste processing technologies is effluent contaminants that are released in gaseous forms from the processes. This is a concern in both biological as well as physicochemical solid waste processing. Carbon dioxide (CO2), the major gas released, does not present a serious problem and there are currently in place a number of flight-qualified technologies for CO2 removal. However, a number of other gases, in particular NOx, SO2, NH3, and various hydrocarbons (e.g. CH4) do present health hazards to the crew members in space habitats. In the present configuration of solid waste processing in the International Space Station (ISS), some of these gases are removed by the Trace Contaminant Control System (TCCS), demands a major resupply. Reduction of the resupply can be effective by using catalyst impregnated carbon nanotubes. For example, NO decomposition to N2 and O2 is thermodynamically favored.

NASA Ames Research Center and Lawrence Berkeley National lab have completed a three-year joint NRA research project on the use of waste biomass to make a gaseous contaminant removal system. The objective of the research was to produce activated carbon from life support wastes and to use the activated carbon to adsorb and remove incineration flue gas contaminants such as NOx. Inedible biomass waste from food production was the primary waste considered for conversion to activated carbon. Previous research at NASA Ames has demonstrated the adsorption of both NOx and SO2 on activated carbon made from biomass and the subsequent conversion of adsorbed NOx to nitrogen and SO2 to sulfur. This paper presents the results testing the whole process system consisting of making, using, and regenerating activated carbon with relevant feed from an actual incinerator. Factors regarding carbon preparation, adsorption and regeneration are addressed.

Incineration is a promising method for converting biomass and human waste into CO2 and H2O during extended planetary exploration. Unfortunately, it produces NOX and other pollutants. TDA Research has developed a safe and effective process to remove NOX from waste incinerator product gas streams. In our process, NO is catalytically oxidized to NO2, which is then removed with a wet scrubber. In a SBIR Phase II project, TDA designed and constructed a pilot scale system, which will be used with the incinerator at NASA Ames Research Center. In this paper, we present test results obtained with our system, which clearly demonstrate the effectiveness of this approach to NOX control.

Crop production in space habitats is currently under consideration as part of an advanced life support system. The scenarios for crop production vary depending on the mission objectives. For a mission scenario such as the International Space Station (ISS), current efforts propose only salad crop production. However in order to grow salad crops, there is a need for plant nutrients (elements) such as N, P, K, Ca, etc., which constitutes about 10% of dry weight of the plant. Nitrogen and potassium are the major elements needed by salad crops and currently require resupply on Station. However, it is feasible that these macronutrients could be recovered through the waste materials generated by the crew. The proposed concepts are non-oxidative and simple in design. This paper considers the potential for reclaiming macronutrients from urine and gray water concentrates from water recovery systems.

In this paper we have developed a unique approach to providing the elements required for crop production in a steady-state condition, which is essential for Space habitats. The approach takes into consideration human elemental requirements and crop requirements for healthy growth and develops a method for the calculation of the rates of nutrient uptake for the different elements for different crops. The uptake rates can be used to calculate the rate of nutrient supply required in the hydroponic solution. This approach ensures that crops produced will not have excessive levels of elements that may be harmful to humans. It also provides an opportunity to optimize the processes of crop production and waste processing through highly controlled feed rates.

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NOx and SO2 contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NOx and SO2 in activated carbon made from biomass. Conversion of adsorbed NOx to nitrogen has also been observed.

Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. An incinerator was used to recover and recycle part of the waste produced during the Early Human Testing Initiative Phase 3 (EHTI 3) at Johnson Space Center. The fluidized bed incinerator developed for the EHTI testing was a joint initiative between Ames Research Center, University of Utah and Johnson Space Center. Though in no way an optimized system at that time, the fluidized bed combustor fulfilled the basic requirements of a resource recovery system. Valuable data was generated and problem areas, technology development issues and future research directions were identified during the EHTI testing.

The electrosynthesis of expendable reagents including acids, bases, and oxidants from simple salts or salt mixtures has been demonstrated using a variety of electrochemical cells. A five chambered electrodialytic water splitting (EDWS) cell with bipolar membranes was utilized to efficiently convert sodium sulfate, sodium chloride, potassium nitrate, and potassium chloride to conjugate acids and bases. With the same cell, selective segregation of cations and anions from mixed salt solutions occurred, resulting in relatively pure acids and bases. These results suggest that pure acids and bases can be produced from composite spacecraft brines. Chemical oxidants such as sodium and ammonium persulfate were also synthesized with high current efficiencies by the electrooxidation of salts and acids in a two chambered electrochemical cell.

Terraforming of Mars is the long-term goal of colonization of Mars. However, this process is likely to be a very slow process and conservative estimates involving a synergetic, technocentric approach suggest that it may take around 10,000 years before the planet can be parallel to that of Earth and where humans can live in open systems (Fogg, 1995). Hence, for the foreseeable future, any missions will require habitation within small confined habitats with high biomass to atmospheric mass ratios, thereby requiring that all wastes be recycled. Processing of the wastes will ensure predictability and reliability of the ecosystem and reduce resupply logistics. Solid wastes, though smaller in volume and mass than the liquid wastes, contain more than 90% of the essential elements required by humans and plants.

For Supercritical Water Oxidation (SCWO), particle size is a key factor effecting requirements for feed preparation, slurry concentration and pumping, rate of reaction, and reactor size. To address these issues, an experimental research program was undertaken to evaluate the effect of particle size on the reaction kinetics in SCWO of solid particulates (wheat straw and cellulose particles in this case). The experiments also included evaluation of the effects of temperature, pressure, and agitation. Some corrosion data were obtained. A two-step reaction mechanism was revealed. Empirically based mathematical relationships were developed that can be used for SCWO system design.