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Technical Paper

Oxygenated Fuels as Reductants for Lean NOx Trap Regeneration

2024-04-09
2024-01-2132
The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.
Technical Paper

Study of Dimethyl Ether Fuel Spray Characteristics and Injection Profile

2024-04-09
2024-01-2702
The majority of transportation systems have continued to be powered by the internal combustion engine and fossil fuels. Heavy-duty applications especially are reliant on diesel engines for their high brake efficiency, power density, and robustness. Although engineering developments have advanced engines towards significantly fewer emissions and higher efficiency, the use of fossil-derived diesel as fuel sets a fundamental threshold in the achievable total net carbon reduction. Dimethyl ether can be produced from various renewable feedstocks and has a high chemical reactivity making it suitable for heavy-duty applications, namely compression ignition direct injection engines. Literature shows the successful use of DME fuels in diesel engines without significant hardware modifications.
Technical Paper

Effect of Spark Assisted Compression Ignition on the End-Gas Autoignition with DME-air Mixtures in a Rapid Compression Machine

2024-04-09
2024-01-2822
Substantial effort has been devoted to utilizing homogeneous charge compression ignition (HCCI) to improve thermal efficiency and reduce emission pollutants in internal combustion engines. However, the uncertainty of ignition timing and limited operational range restrict further adoption for the industry. Using the spark-assisted compression ignition (SACI) technique has the advantage of using a spark event to control the combustion process. This study employs a rapid compression machine to characterize the ignition and combustion process of Dimethyl ether (DME) under engine-like background temperature and pressures and combustion regimes, including HCCI, SACI, and knocking onsite. The spark ignition timing was swept to ignite the mixture under various thermodynamic conditions. This investigation demonstrates the presence of four distinct combustion regimes, including detonation, strong end-gas autoignition, mild end-gas autoignition, and HCCI.
Technical Paper

Characterization of an Integrated Three-Way Catalyst/Lean NOx Trap System for Lean Burn SI Engines

2023-10-31
2023-01-1658
The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.
Technical Paper

Investigation of Fuel Injection Pressure Impact on Dimethyl Ether Combustion

2023-10-31
2023-01-1644
Compression ignition engines used in heavy-duty applications are typically powered by diesel fuel. The high energy density and feedstock abundance provide a continuing source for the immense energy demand. However, the heavy-duty transportation sector is challenged with lowering greenhouse gas and combustion by-product emissions, including carbon dioxide, nitrogen oxides, and particulate matter. The continuing development of engine management and combustion strategies has proven the ability to meet current regulations, particularly with higher fuel injection pressure. Nonetheless, a transition from diesel to a renewable alternative fuel source will play a significant role in reducing greenhouse gases while maintaining the convenience and energy density inherent in liquid fuels. Dimethyl ether is a versatile fuel that possesses combustion properties suitable for compression ignition engines and physical properties helpful for clean combustion.
Technical Paper

Investigation of Dimethyl Ether Dual-Fuel Combustion Using Propane and Ethanol as Premixed Fuel

2023-09-29
2023-32-0018
The combustion and emission characteristics of dual-fuel combustion were investigated using dimethyl ether direct injection and premixed low-carbon fuels. Dimethyl ether was used as the direct injection fuel for its high reactivity and low propensity to form particulate matter. Ethanol and Propane, two fuels of low reactivity, were premixed in the intake port. An injection timing sweep of varying premixed energy shares and engine loads was tested. Combustion analysis was conducted based on in-cylinder pressure measurements while detailed speciation of engine-out emissions was performed via FTIR. The proper injection advance and premixed energy share can realize low NOx and high combustion efficiency. Ethanol showed stronger impact to DME ignition delay as compared with propane.
Technical Paper

Performance and Emission Characteristics of Direct Injection DME Combustion under Low NOx Emissions

2023-04-11
2023-01-0327
Compression ignition internal combustion engines provide unmatched power density levels, making them suitable for numerous applications including heavy-duty freight trucks, marine shipping, and off-road construction vehicles. Fossil-derived diesel fuel has dominated the energy source for CI engines over the last century. To mitigate the dependency on fossil fuels and lessen anthropogenic carbon released into the atmosphere within the transportation sector, it is critical to establish a fuel source which is produced from renewable energy sources, all the while matching the high-power density demands of various applications. Dimethyl ether (DME) has been used in non-combustion applications for several decades and is an attractive fuel for CI engines because of its high reactivity, superior volatility to diesel, and low soot tendency. A range of feedstock sources can produce DME via the catalysis of syngas.
Technical Paper

Active Plasma Probing for Lean Burn Flame Detection

2023-04-11
2023-01-0293
Combustion diagnostics of highly diluted mixtures are essential for the estimation of the combustion quality, and control of combustion timing in advanced combustion systems. In this paper, a novel fast response flame detection technique based on active plasma is introduced and investigated. Different from the conventional ion current sensing used in internal combustion engines, a separate electrode gap is used in the detecting probing. Further, the detecting voltage across the electrode gap is modulated actively using a multi-coil system to be slightly below the breakdown threshold before flame arrival. Once the flame front arrives at the probe, the ions on the flame front tend to decrease the breakdown voltage threshold and trigger a breakdown event. Simultaneous electrical and optical measurements are employed to investigate the flame detecting efficacy via active plasma probing under both quiescent and flow conditions.
Technical Paper

Effective Ignition of Lean Methane/Hydrogen Mixture in a Rapid Compression Machine

2023-04-11
2023-01-0255
The use of renewable natural gas and green hydrogen can significantly reduce the carbon footprint of engines. For future spark ignition engines, lean burn strategy and high compression ratio need to be adopted to further improve thermal efficiency, reducing energy consumption. The efficacy of the ignition system is essential to initiate self-sustainable flame under those extreme conditions. In this work, a rapid compression machine is employed to compress air-fuel mixture to engine-like boundary conditions before the spark event to experimentally investigate the ignition and combustion characteristics of the methane-air mixtures under extreme lean conditions. Hydrogen is also added to support the ignition process and enhance flame propagation speed. Lean methane-air mixtures with excess air ratio up to 2.8 are used, with 10 vol% hydrogen addition into the methane fuel. The ignition criteria under various ignition strategies are explored.
Technical Paper

A Study of Combustion Inefficiencies in SI Engines Powered by Alcohol and Ether Fuels Using Detailed Emission Speciation

2022-03-29
2022-01-0520
Advanced combustion engines, as power sources, dominate all aspects of the transportation sector. Stringent emission and fuel efficiency standards have promoted the research interest in advanced combustion strategies and alternative fuels. Owing to the comparable energy density to the existing fossil fuels and renewable production, alcohol and ether fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. Furthermore, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines. However, lean-burn or EGR dilution can introduce combustion inefficiencies in the form of excessive hydrocarbon, carbonyl species and carbon monoxide emissions.
Technical Paper

Combustion Characterization of DME-Fueled Dual Fuel Combustion with Premixed Ethanol

2022-03-29
2022-01-0461
The heterogeneous nature of direct injection (DI) combustion yields high combustion efficiencies but harmful emissions through the formation of high nitrogen oxide (NOx) and smoke emissions. In response, extensive empirical and computational research has focused on balancing the NOx-smoke trade-off to limit diesel DI combustion emissions. Dimethyl ether (DME) fuel is applicable in DI compression ignition engines and its high fuel oxygen produces near-smoke-free emissions. Moreover, the addition of a premixed fuel can improve mixture homogeneity and minimize the DI fuel energy demands lessening injection durations. For this technique, a low reactivity fuel such as ethanol is essential to avoid early autoignition in high compression ratio engines. In this work, empirical experiments of dual fuel operation have been conducted using premixed ethanol with high-pressure direct injection DME.
Technical Paper

Chemical Reactivity Control of DME/Ethanol Dual Fuel Combustion

2021-09-21
2021-01-1176
The use of renewable fuels in place of conventional hydrocarbon fuels can minimize the carbon footprint of internal combustion engines. DME has been treated as a suitable surrogate to diesel fuel because of its high reactivity and soot-less combustion characteristics. The lower energy density of DME fuel demands a higher fuel supply rate to match the engine loads compared to diesel, which was achieved through prolonged injection duration and larger nozzle holes. When used as a pilot fuel to control the combustion behavior in a dual-fuel application, the fuel energy delivery rate becomes less critical allowing the use of a standard diesel common-rail injector for DME direct injection. In this work, the combustion of DME-Ethanol dual-fuel reactivity-controlled compression ignition was experimentally investigated.
Technical Paper

Numerical Investigation on NO to NO2 Conversion in a Low-Temperature Combustion CI Engine

2021-04-06
2021-01-0506
Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.
Technical Paper

An Investigation on the Regeneration of Lean NOX Trap Using Dimethyl Ether

2020-04-14
2020-01-1354
The ever-stringent emission regulations are major challenges for the diesel fueled engines in automotive industry. The applications of advanced after-treatment technologies as well as alternative fuels [1] are considered as promising methodology to reduce exhaust emission from compression ignition (CI) engines. Using dimethyl ether (DME) as an alternative fuel has been extensively studied by many researchers and automotive manufactures since DME has demonstrated enormous potential in terms of emission reduction, such as low CO emission, and soot and sulfur free. However, the effect of employing DME in a lean NOX trap (LNT) based after-treatment system has not been fully addressed yet. In this work, investigations of the long breathing LNT system using DME as a reductant were performed on a heated after-treatment flow bench with simulated engine exhaust condition.
Technical Paper

Combustion Characterization of Neat n-Butanol in an SI Engine

2020-04-14
2020-01-0334
Increasingly stringent emission standards have promoted the interest in alternate fuel sources. Because of the comparable energy density to the existing fossil fuels and renewable production, alcohol fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. In this research, the combustion characteristics of neat n-butanol are analyzed under spark ignition operation using a single cylinder SI engine. The fuel is injected into the intake manifold using a port-fuel injector. Two modes of charge dilution were used in this investigation to test the limits of stable engine operation, namely lean burn using excess fresh air and exhaust gas recirculation (EGR). The in-cylinder pressure measurement and subsequently, heat release analysis are used to investigate the combustion characteristics of the fuel under low load SI engine operation.
Technical Paper

Combustion and Emission Characteristics of SI and HCCI Combustion Fueled with DME and OME

2020-04-14
2020-01-1355
DME has been considered an alternative fuel to diesel fuel with promising benefits because of its high reactivity and volatility. Research shows that an engine fueled with DME will produce zero smoke emissions. However, the storage and the handling of the fuel are underlying difficulties owing to its high vapour pressure (530 kPa @ 20 °C). In lieu, OME1 fuel, a derivate of DME, offers advantages exhibited with DME fuel, all the while being a liquid fuel for engine application. In this work, engine tests are performed to realize the combustion behaviour of DME and OME1 fuel on a single-cylinder research engine with a compression ratio of 9.2:1. The dilution ratio of the mixture is progressively increased in two manners, allowing more air in the cylinder and applying exhaust gas recirculation (EGR). The high reactivity of DME suits the capability to be used in compression ignition combustion whereas OME1 must be supplied with a supplemental spark to initiate the combustion.
Technical Paper

An Investigation on the Regeneration of Lean NOx Trap Using Ethanol and n-Butanol

2019-04-02
2019-01-0737
Reduction of nitrogen oxides (NOx) in lean burn and diesel fueled Compression Ignition (CI) engines is one of the major challenges faced by automotive manufacturers. Lean NOx Trap (LNT) and urea-based Selective Catalytic Reduction (SCR) exhaust after-treatment systems are well established technologies to reduce NOx emissions. However, each of these technologies has associated advantages and disadvantages for use over a wide range of engine operating conditions. In order to meet future ultra-low NOx emission norms, the use of both alternative fuels and advanced after-treatment technology may be required. The use of an alcohol fuel such as n-butanol or ethanol in a CI engine can reduce the engine-out NOx and soot emissions. In CI engines using LNTs for NOx reduction, the fuel such as diesel is utilized as a reductant for LNT regeneration.
Technical Paper

Early Pilot Injection Strategies for Reactivity Control in Diesel-ethanol Dual Fuel Combustion

2018-04-03
2018-01-0265
This paper examines the diesel-ethanol dual fuel combustion at medium engine loads on a single-cylinder research diesel engine with a compression ratio of 16.5:1. The effect of exhaust gas recirculation (EGR) and ethanol energy ratio was investigated for the dual fuel combustion to achieve simultaneously ultra-low NOx and soot emissions. A medium ethanol ratio of about 0.6 was found suitable to meet the requirements for mixing enhancement and ignition control, which resulted in the lowest NOx and soot emissions among the tested ethanol ratios. A double-pilot injection strategy was found competent to lower the pressure rise rate owing to the reduced fuel quantity in the close-to-TDC injection. The advancement of pilot injection timing tended to reduce the CO and THC emissions, which is deemed beneficial for high EGR operations. The reactivity mutual-modulation between the diesel pilot and the background ethanol mixture was identified.
Technical Paper

Mode Switching to Improve Low Load Efficiency of an Ethanol-Diesel Dual-Fuel Engine

2017-03-28
2017-01-0771
The dual-fuel application using ethanol and diesel fuels can substantially improve the classical trade-off between oxides of nitrogen (NOx) and smoke, especially at moderate-to-high load conditions. However, at low engine load levels, the use of a low reactivity fuel in the dual-fuel application usually leads to increased incomplete combustion products that in turn result in a significant reduction of the engine thermal efficiency. In this work, engine tests are conducted on a high compression ratio, single cylinder dual-fuel engine that incorporates the diesel direct-injection and ethanol port-injection. Engine load levels are identified, at which, diesel combustion offers better efficiency than the dual-fuel combustion while attaining low NOx and smoke emissions. Thereafter, a cycle-to-cycle based closed-loop controller is implemented for the combustion phasing and engine load control in both the diesel and dual-fuel combustion regimes.
Technical Paper

Measurement of Temperature and Soot (KL) Distributions in Spray Flames of Diesel-Butanol Blends by Two-Color Method Using High-Speed RGB Video Camera

2016-10-17
2016-01-2190
Taking advantages of high speed RGB video cameras, the two-color method can be implemented with a relatively simple setup to obtain the temporal development of the two dimensional temperature and soot (KL) distributions in a reacting diesel jet. However, several issues such as the selection of the two wavelengths, the role of bandpass filters, and the proper optical settings, etc. should be known to obtain a reliable measurement. This paper, at first, discusses about the uncertainties in the measurement of temperature and KL distributions in the diesel flame by the two-color method using the high speed RGB video camera. Since n-butanol, as an alternative renewable fuel, has the potential application in diesel engines, the characteristic of spray combustion of diesel-butanol blends under the diesel-like ambient conditions in a pre-burning constant-volume combustion chamber is studied.
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