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Typically ethanol is present in gasoline as a 10% blend by volume (E10), although E15, E85 (51 to 83%), and E0 are also available at selected stations. Numerous studies of tailpipe regulated emissions have been conducted to compare emissions from E10 and E0, and there is a growing body of literature addressing blends of E15 and higher. Isolating the effect of ethanol in a study is philosophically difficult, because the ethanol naturally displaces some hydrocarbons, because the ethanol interacts with the remaining gasoline, and because properties of mixing are often nonlinear. Some studies have used splash blending, simply mixing the ethanol with a reference gasoline to produce a blend for comparison to the reference. Others have used match blending, where the objective is to match selected properties of the blend to properties of a reference gasoline.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

Relationships between diesel particulate matter (PM) mass and gaseous emissions mass produced by engines have been explored to determine whether any gaseous species may be used as surrogates to infer PM quantitatively. It was recognized that sulfur content of fuel might independently influence PM mass, since PM historically is composed of elemental carbon, organic carbon, sulfuric acid, ash and wear particles. Previous research has suggested that PM may be correlated with carbon monoxide (CO) for an engine that is exercised through a variety of speed and load cycles, but that the correlation does not extend to a group of engines. Large databases from the E-55/59 and Gasoline/Diesel PM Split programs were employed, along with the IBIS bus emissions database and several additional data sets for on- and off-road engines to examine possible relationships.

Biodiesel may be derived from either plant or animal sources, and is usually employed as a compression ignition fuel in a blend with petroleum diesel (PD). Emissions differences between vehicles operated on biodiesel blends and on diesel have been published previously, but data do not cover the latest engine technologies. Prior studies have shown that biodiesel offers advantages in reducing particulate matter, with either no advantage or a slight disadvantage for oxides of nitrogen emissions. This paper describes a recent study on the emissions impact of two biodiesel blends B20A, made from 20% animal fat (tallow) biodiesel and 80% PD, and B20B, obtained from 20% soybean biodiesel and 80% PD. These blends used the same PD fuel for blending and were contrasted with the same PD fuel as a reference. The research was conducted on a 2007 medium heavy-duty diesel truck (MHDDT), with an engine equipped with Exhaust Gas Recirculation (EGR) and a Diesel Particulate Filter (DPF).

Most transient heavy duty diesel emissions data in the USA have been acquired using the Federal Test Procedure (FTP), a heavy-duty diesel engine transient test schedule described in the US Code of Federal Regulations. The FTP includes both urban and freeway operation and does not provide data separated by driving mode (such as rural, urban, freeway). Recently, a four-mode engine test schedule was created for use in the Advanced Collaborative Emission Study (ACES), and was demonstrated on a 2004 engine equipped with cooled Exhaust Gas Recirculation (EGR). In the present work, the authors examined emissions using these ACES modes (Creep, Cruise, Transient and High-speed Cruise) and the FTP from a Detroit Diesel Corporation (DDC) Series 60 1992 12.7 liter pre-EGR engine. The engine emissions were measured using full exhaust dilution, continuous measurement of gaseous species, and filter-based Particulate Matter (PM) measurement.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

Transit agencies across the United States operate bus fleets primarily powered by diesel, natural gas, and hybrid drive systems. Passenger loading affects the power demanded from the engine, which in turn affects distance-specific emissions and fuel consumption. Analysis shows that the nature of bus activity, taking into account the idle time, tire rolling resistance, wind drag, and acceleration energy, influences the way in which passenger load impacts emissions. Emissions performance and fuel consumption from diesel and natural gas powered buses were characterized by the West Virginia University (WVU) Transportable Emissions Testing Laboratory. A comparison matrix for all three bus technologies included three common driving cycles (the Braunschweig Cycle, the OCTA Cycle, and the ADEME-RATP Paris Cycle). Each bus was tested at three different passenger loading conditions (empty weight, half weight, and full weight).

As emission regulations become increasingly strict, the need for more accurate sampling systems becomes essential. When calculating emissions from a dilution system, a correction is made to remove the effects of contaminants in the dilution air. The dilution air correction was explored to determine why this correction is needed, when this correction is important, and what methods are available for calculating the dilution factor (DF). An experimental and error analysis investigation into the standard and recently proposed methods for calculating the DF was conducted. Five steady state modes were run on a 1992 Detroit Diesel engine series 60 and the DF from eleven different equations were investigated. The effects of an inaccurate dilution air correction on calculated fuel flow from a carbon balance and the mass emissions was analyzed. The dilution air correction was shown to be important only for hydrocarbons, particulate matter (PM), and CO2.

West Virginia University has conducted research to characterize the emissions from medium-duty vehicles operating on Fischer-Tropsch synthetic gas-to-liquid compression ignition fuel. The West Virginia University Transportable Heavy Vehicle Emissions Testing Laboratory was used to collect data for gaseous emissions (carbon dioxide, carbon monoxide, oxides of nitrogen, and total hydrocarbon) while the vehicles were exercised through a representative driving schedule, the New York City Bus Cycle (NYCB). Artificial neural networks were used to model emissions to enhance the capabilities of computer-based vehicle operation simulators. This modeling process is presented in this paper. Vehicle velocity, acceleration, torque at rear axel, and exhaust temperature were used as inputs to the neural networks. For each of the four gaseous emissions considered, one set of training data and one set of validating data were used, both based on the New York City Bus Cycle.

Heavy duty diesel vehicle (HDDV) emissions are known to affect air quality, but few studies have quantified the real-world contribution to the inventory. The objective of this study was to provide data that may enable ambient emissions investigators to m,odel the air quality more accurately. The 25 vehicles reported in this paper are from the first phase of a program to determine representative regulated emissions from Heavy Heavy-Duty Diesel Trucks (HHDDT) operating in Southern California. Emissions data were gathered using a chassis dynamometer, full flow dilution tunnel, and research grade analyzers. The subject program employed two truck test weights and four new test modes (one was idle operation), in addition to the Urban Dynamometer Driving Schedule (UDDS), and the AC50/80 cycle. The reason for such a broad test cycle scope was to determine thoroughly how HHDDT emissions are influenced by operating cycle to improve accuracy of models.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

Understanding the nitric oxide (NO) conversion process plays a major role in optimizing the Selective NOX Recirculation (SNR) technique. SNR has been proven in gasoline and diesel engines, with up to 90% NOX conversion rates being achieved. This technique involves adsorbing NOX from an exhaust stream, then selectively desorbing the NOX into a concentrated NOX stream, which is fed back into the engine's intake, thereby converting a percentage of the concentrated NOX stream into harmless gases. The emphasis of this paper is on the unique chemical kinetic modeling problem that occurs with high concentrations of NOX in the intake air of a spark ignited natural gas engine with SNR. CHEMKIN, a chemical kinetic solver software package, was used to perform the reaction modeling. A closed homogeneous batch reactor model was used to model the fraction of NOX versus time for varying initial conditions and constants.

The California Air Resources Board (ARB) developed a Medium Heavy-Duty Truck (MHDT) schedule by selecting and joining microtrips from real-world MHDT. The MHDT consisted of three modes; namely, a Lower Speed Transient, a Higher Speed Transient, and a Cruise mode. The maximum speeds of these modes were 28.9, 58.2 and 66.0 mph, respectively. Each mode represented statistically selected truck behavior patterns in California. The MHDT is intended to be applied to emissions characterization of trucks (14,001 to 33,000lb gross vehicle weight) exercised on a chassis dynamometer. This paper presents the creation of the MHDT and an examination of repeatability of emissions data from MHDT driven through this schedule. Two trucks were procured to acquire data using the MHDT schedule. The first, a GMC truck with an 8.2-liter Isuzu engine and a standard transmission, was tested at laden weight (90% GVW, 17,550lb) and at unladen weight (50% GVW, 9,750lb).

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

The goal of the Diesel Emissions Control-Sulfur Effects (DECSE) program was to determine the impact of diesel fuel sulfur levels on emissions control devices that could lower emissions of oxides of nitrogen (NOX) and particulate matter (PM) from on-highway trucks and buses. West Virginia University (WVU) performed evaluations of lean-NOx catalysts to determine the effects of fuel sulfur content on emissions reduction efficiency and catalyst durability in the first 250 hours of operation. A Cummins ISM370 engine (10.8 liter, 370 horsepower), typical of heavy -duty truck applications, was utilized to evaluate high-temperature lean-NOX catalyst while a Navistar T444E (7.3 liter, 210 horsepower), typical of medium-duty applications, was used to evaluate low-temperature catalyst. Catalysts were evaluated periodically during the first 250 hours of exposure to exhaust from engines operated on 3ppm, 30ppm, 150ppm and 350ppm sulfur content diesel fuel.

West Virginia University evaluated diesel oxidation catalysts (DOC) and lean-NOX catalysts as part of Diesel Emissions Control-Sulfur Effects (DECSE) project. In order to perform thermal aging of the DOC and lean-NOX catalysts simultaneously and economically, each catalyst was sized to accommodate half of the engine exhaust flow. Simultaneous catalyst aging was then achieved by splitting the engine exhaust into two streams such that approximately half of the total exhaust flowed through the DOC and half through the lean-NOX catalyst. This necessitated splitting the engine exhaust into two streams during emissions measurements. Throttling valves installed in each branch of the split exhaust were adjusted so that approximately half the engine exhaust passed though the active catalyst under evaluation and into a full flow dilution tunnel for emissions measurement.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Emissions from heavy-duty vehicles may be reduced through the introduction of clean diesel formulations, and through the use of catalyzed particulate matter filters that can enjoy increased longevity and performance if ultra-low sulfur diesel is used. Twenty over-the-road tractors with Detroit Diesel Series 60 engines were selected for this study. Five trucks were operated on California (CA) specification diesel (CARB), five were operated on ARCO (now BP Amoco) EC diesel (ECD), five were operated on ARCO ECD with a Johnson-Matthey Continuously Regenerating Technology (CRT) filter and five were operated on ARCO ECD with an Engelhard Diesel Particulate Filter (DPX). The truck emissions were characterized using a transportable chassis dynamometer, full-scale dilution tunnel, research grade gas analyzers and filters for particulate matter (PM) mass collection. Two test schedules, the 5 mile route and the city-suburban (heavy vehicle) route (CSR), were employed.