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Technical Paper

A Three-Way Catalyst Model for a Bio-Methane Heavy-Duty Engine: Characterization at Different Lambda

2024-04-09
2024-01-2084
Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio.
Technical Paper

Experimental and Numerical Investigation of a Particle Filter Technology for NG Heavy-Duty Engines

2023-04-11
2023-01-0368
The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.
Technical Paper

Model Development of a CNG Active Pre-chamber Fuel Injection System

2021-09-05
2021-24-0090
Natural gas as an internal combustion engine fuel is taking a predominant role as a mid-term solution to pollution due to combustion driven human activities both in the energy and transport sectors. Engine researchers and manufacturers are in the process of investigating and improving strategies that decrease emissions and fuel consumption, without compromising engine performance and efficiency; active pre-chamber configurations are to be accounted for as one of these. A relatively small amount of fuel (up to 10 % of the total fuel-energy requirement) is introduced in the confined volume of the pre-chamber and forms a close-to-stoichiometric mixture with fresh charge that is introduced from the main combustion chamber during the compression stroke. After spark-ignition the products of this early stage of combustion can ignite ultra-lean mixtures (with λ up to 2) through the Turbulent Jet Ignition mechanism, hence reducing fuel consumption as well as noxious emissions such as NOx.
Technical Paper

Methane Conversion and Ammonia Formation Model over a Pd-Rh Three-Way Catalyst for CNG Heavy-Duty Engines

2021-09-05
2021-24-0002
Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.
Technical Paper

Regulated Emissions and Detailed Particle Characterisation for Diesel and RME Biodiesel Fuel Combustion with Varying EGR in a Heavy-Duty Engine

2019-12-19
2019-01-2291
This study investigates particulate matter (PM) and regulated emissions from renewable rapeseed oil methyl ester (RME) biodiesel in pure and blended forms and contrasts that to conventional diesel fuel. Environmental and health concerns are the major motivation for combustion engines research, especially finding sustainable alternatives to fossil fuels and reducing diesel PM emissions. Fatty acid methyl esters (FAME), including RME, are renewable fuels commonly used from low level blends with diesel to full substitution. They strongly reduce the net carbon dioxide emissions. It is largely unknown how the emissions and characteristics of PM get altered by the combined effect of adding biodiesel to diesel and implementing modern engine concepts that reduce nitrogen oxides (NOx) emissions by exhaust gas recirculation (EGR).
Technical Paper

Development of a Dedicated CNG Three-Way Catalyst Model in 1-D Simulation Platforms

2019-09-09
2019-24-0074
A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.
Technical Paper

Measurement of Gasoline Exhaust Particulate Matter Emissions with a Wide-Range EGR in a Heavy-Duty Diesel Engine

2019-04-02
2019-01-0761
A large number of measurement techniques have been developed or adapted from other fields to measure various parameters of engine particulates. With the strict limits given by regulations on pollutant emissions, many advanced combustion strategies have been developed towards cleaner combustion. Exhaust gas recirculation (EGR) is widely applied to suppress nitrogen oxide (NOx) and reduce soot emissions. On the other hand, gasoline starts to be utilized in compression ignition engines due to great potential in soot reduction and high engine efficiency. New engine trends raise the need for good sensitivity and suitable accuracy of the PM measurement techniques to detect particulates with smaller size and low particulate mass emissions. In this work, we present a comparison between different measurement techniques for particulate matter (PM) emissions in a compression ignition engine running on gasoline fuel. A wide-range of EGR was used with lambda varied from 3 down to 1.
Journal Article

NOx-Conversion Comparison of a SCR-Catalyst Using a Novel Biomimetic Effervescent Injector on a Heavy-Duty Engine

2019-01-15
2019-01-0047
NOx pollution from diesel engines has been stated as causing over 10 000 pre-mature deaths annually and predictions are showing that this level will increase [1]. In order to decrease this growing global problem, exhaust after-treatment systems for diesel engines have to be improved, this is especially so for vehicles carrying freight as their use of diesel engines is expected to carry on into the future [2]. The most common way to reduce diesel engine NOx out emissions is to use SCR. SCR operates by injecting aqueous Urea solution, 32.5% by volume (AUS-32), that evaporates prior the catalytic surface of the SCR-catalyst. Due to a catalytic reaction within the catalyst, NOx is converted nominally into Nitrogen and Water. Currently, the evaporative process is enhanced by aggressive mixer plates and long flow paths.
Technical Paper

Assessment of Engine Control Parameters Effect to Minimize GHG Emissions in a Dual Fuel NG/Diesel Light Duty Engine

2018-04-03
2018-01-0266
The interest in Natural Gas (NG) as alternative fuel for transportation is constantly growing, mostly due to its large availability and lower environmental impact with respect to gasoline or diesel fuel. In this scenario, the application of the Dual Fuel (DF) Diesel- Natural Gas (NG) combustion concept to light duty engines can represent an important route to increment the diffusion of natural gas use. Many studies have proven the benefits of DF with respect to conventional diesel combustion in terms of CO2, NOx, PM and PN emissions, with the main drawback of high unburned hydrocarbon, mainly at low/partial engine loads. This last aspect still prevents the application of DF mode to small displacement engines. In the present work, a 2.0 L Euro 5 compliant diesel engine, equipped with an advanced electronic closed-loop combustion control (CLCC) system, has been set up to operate in DF mode and tested on a dyno test bench.
Technical Paper

Combined Low and High Pressure EGR for Higher Brake Efficiency with Partially Premixed Combustion

2017-10-08
2017-01-2267
The concept of Partially Premixed Combustion (PPC) in internal combustion engines has shown to yield high gross indicated efficiencies, but at the expense of gas exchange efficiencies. Most of the experimental research on partially premixed combustion has been conducted on compression ignition engines designed to operate on diesel fuel and relatively high exhaust temperatures. The partially premixed combustion concept on the other hand relies on dilution with high exhaust gas recirculation (EGR) rates to slow down the combustion which results in low exhaust temperatures, but also high mass flows over cylinder, valves, ports and manifolds. A careful design of the gas exchange system, EGR arrangement and heat exchangers is therefore of utter importance. Experiments were performed on a heavy-duty, compression ignition engine using a fuel consisting of 80 volume % 95 RON service station gasoline and 20 volume % n-heptane.
Technical Paper

Humid Air Motor: A Novel Concept to Decrease the Emissions Using the Exhaust Heat

2017-10-08
2017-01-2369
Humid air motor (HAM) is an engine operated with humidified inlet charge. System simulations study on HAM showed the waste heat recovery potential over a conventional system. An HAM setup was constructed, to comprehend the potential benefits in real-time, the HAM setup was built around a 13-litre six cylinder Volvo diesel engine. The HAM engine process is explained in detail in this paper. Emission analysis is also performed for all three modes of operation. The experiments were carried out at part load operating point of the engine to understand the effects of humidified charge on combustion, efficiency, and emissions. Experiments were conducted without EGR, with EGR, and with humidified inlet charge. These three modes of operation provided the potential benefits of each system. Exhaust heat was used for partial humidification process. Results show that HAM operation, without compromising on efficiency, reduces NOx and soot significantly over the engine operated without EGR.
Journal Article

Evaluation of Different Turbocharger Configurations for a Heavy-Duty Partially Premixed Combustion Engine

2017-09-04
2017-24-0164
The engine concept partially premixed combustion (PPC) has proved higher gross indicated efficiency compared to conventional diesel combustion engines. The relatively simple implementation of the concept is an advantage, however, high gas exchange losses has made its use challenging in multi-cylinder heavy duty engines. With high rates of exhaust gas recirculation (EGR) to dilute the charge and hence limit the combustion rate, the resulting exhaust temperatures are low. The selected boost system must therefore be efficient which could lead to large, complex and costly solutions. In the presented work experiments and modelling were combined to evaluate different turbocharger configurations for the PPC concept. Experiments were performed on a multi-cylinder engine. The engine was modified to incorporate long route EGR and a single-stage turbocharger, however, with compressed air from the building being optionally supplied to the compressor.
Technical Paper

How Much Regeneration Events Influence Particle Emissions of DPF-Equipped Vehicles?

2017-09-04
2017-24-0144
Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.
Technical Paper

Parametric Analysis of the Effect of Pilot Quantity, Combustion Phasing and EGR on Efficiencies of a Gasoline PPC Light-Duty Engine

2017-09-04
2017-24-0084
In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions.
Technical Paper

Control-Oriented Modeling of Soot Emissions in Gasoline Partially Premixed Combustion with Pilot Injection

2017-03-28
2017-01-0511
In this paper, a control-oriented soot model was developed for real-time soot prediction and combustion condition optimization in a gasoline Partially Premixed Combustion (PPC) Engine. PPC is a promising combustion concept that achieves high efficiency, low soot and NOx emissions simultaneously. However, soot emissions were found to be significantly increased with high EGR and pilot injection, therefore a predictive soot model is needed for PPC engine control. The sensitivity of soot emissions to injection events and late-cycle heat release was investigated on a multi-cylinder heavy duty gasoline PPC engine, which indicated main impact factors during soot formation and oxidation processes. The Hiroyasu empirical model was modified according to the sensitivity results, which indicated main influences during soot formation and oxidation processes. By introducing additional compensation factors, this model can be used to predict soot emissions under pilot injection.
Technical Paper

NOx-Conversion and Activation Temperature of a SCR-Catalyst Whilst Using a Novel Biomimetic Flash-Boiling AdBlue Injector on a LD Engine

2016-10-17
2016-01-2212
Yearly 3.3 million premature deaths occur worldwide due to air pollution and NOx pollution counts for nearly one seventh of those [1]. This makes exhaust after-treatment a very important research and has caused the permitted emission levels for NOx to decrease to very low levels, for EURO 6 only 0.4 g/kWh. Recently new legislation on ammonia slip with a limit of 10 ppm NH3 has been added [2], which makes the SCR-technology more challenging. This technology injects small droplets of an aqueous Urea solution into the stream of exhaust gases and through a catalytic reaction within the SCR-catalyst, NOx is converted into Nitrogen and Water. To enable the catalytic reaction the water content in the Urea solution needs to be evaporated and the ammonia molecules need to have sufficient time to mix with the gases prior to the catalyst.
Technical Paper

Influence of Injection Timing on Exhaust Particulate Matter Emissions of Gasoline in HCCI and PPC

2016-10-17
2016-01-2300
In order to reduce nitrogen oxides (NOx) and soot emissions while maintaining high thermal efficiency, more advanced combustion concepts have been developed over the years, such as Homogeneous Charge Compression Ignition (HCCI) and Partially Premixed Combustion (PPC), as possible combustion processes in commercial engines. Compared to HCCI, PPC has advantages of lower unburned hydrocarbon (UHC) and carbon monoxide (CO) emissions; however, due to increased fuel stratifications, soot emissions can be a challenge when adding Exhaust-Gas Recirculation (EGR) gas. The current work presents particle size distribution measurements performed from HCCI-like combustion with very early (120 CAD BTDC) to PPC combustion with late injection timing (11 CAD BTDC) at two intake oxygen rates, 21% and 15% respectively. Particle size distributions were measured using a differential mobility spectrometer DMS500.
Technical Paper

An Experimental Investigation of a Multi-Cylinder Engine with Gasoline-Like Fuel towards a High Engine Efficiency

2016-04-05
2016-01-0763
Partially Premixed Combustion (PPC) is a promising combustion concept with high thermodynamic efficiency and low emission level, and also with minimal modification of standard engine hardware. To use PPC in a production oriented engine, the optimal intake charge conditions for PPC should be included in the analysis. The experiments in this paper investigated and confirmed that the optimal intake conditions of net indicated efficiency for PPC are EGR between 50% and 55% as possible and the lambda close to 1.4. Heat-transfer energy and exhaust gas waste-energy contribute to the majority of the energy loss in the engine. The low EGR region has high heat-transfer and low exhaust gas enthalpy-waste, while the high EGR region has low heat-transfer and high exhaust gas waste-enthalpy. The optimal EGR condition is around 50% where the smallest energy loss is found as a trade-off between heat transfer and exhaust-gas enthalpy-waste.
Technical Paper

Hydrocracked Fossil Oil and Hydrotreated Vegetable Oil (HVO) Effects on Combustion and Emissions Performance of “Torque-Controlled” Diesel Engines

2015-09-06
2015-24-2497
The present paper describes the results of a research activity aimed at studying the potential offered by the use of Hydrocracked fossil oil (HCK) and Hydrotreated Vegetable Oil (HVO) blends as premium fuels for next generation diesel engines. Five fuels have been tested in a light duty four cylinder diesel engine, Euro 5 version, equipped with closed loop control of the combustion. The set of fuels comprises four experimental fuels specifically formulated by blending high cetane HVO and HCK streams and oneEN590-compliant commercial diesel fuel representative of the current market fuel quality. A well consolidated procedure has been carried out to estimate, for the tested fuels, the New European Driving Cycle (NEDC) vehicle performance by means of the specific emissions at steady-state engine operating points.
Technical Paper

Sensitivity Analysis of Partially Premixed Combustion (PPC) for Control Purposes

2015-04-14
2015-01-0884
Partially Premixed Combustion (PPC) is a promising advanced combustion mode for future engines. In order to investigate the sensitivity of PPC to exhaust gas recirculation (EGR) rate, intake gas temperature, intake gas pressure, and injection timing, these parameters were swept individually at three different loads in a single cylinder diesel engine with gasoline-like fuel. A factor of sensitivity was defined to indicate the combustion's controllability and sensitivity to inlet gas parameters and injection timings. Through analysis of experimental results, a control window of inlet gas parameters and injection timings is obtained at different loads in PPC mode from 5 bar to 10 bar IMEPg load at 1200 rpm. To further study the PPC controllability with injection timing, main injection timing was adjusted to sustain steady combustion phasing subject to perturbation of inlet gas state.
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