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Technical Paper

Efficient Electro-Thermal Model for Lithium Iron Phosphate Batteries

2018-04-03
2018-01-0432
The development of a comprehensive battery simulator is essential for future improvements in the durability, performance and service life of lithium-ion batteries. Although simulations can never replace actual experimental data, they can still be used to provide valuable insights into the performance of the battery, especially under different operating conditions. In addition, a single-cell model can be easily extended to the pack level and can be used in the optimization of a battery pack. The first step in building a simulator is to create a model that can effectively capture both the voltage response and thermal behavior of the battery. Since these effects are coupled together, creating a robust simulator requires modeling both components. This paper will develop a battery simulator, where the entire battery model will be composed of four smaller submodels: a heat generation model, a thermal model, a battery parameter model and a voltage response model.
Technical Paper

Degradation Testing and Modeling of 200 Ah LiFePO4 Battery

2018-04-03
2018-01-0441
In this paper, a degradation testing of a lithium-ion battery used for an electric vehicle (EV) is performed and the capacity fade is measured over 400 cycles. For this, a 200 Ah LiFePO4 battery cell is tested under ambient temperature conditions with charge-discharge cycles at rate of 1C (constant current). Additionally, individual cell characterization is conducted using a C/25 (0.8A) charge-discharge cycle and hybrid pulse power characterization (HPPC). Later, the Thevenin battery model was constructed in MATLAB along with an empirical degradation model and validated in terms of voltage for all cycles. It is also found that the presented model closely estimated the profiles observed in the experimental data. Data collected from the experimental results showed that a capacity fade occurred over the 400 cycles and the discharge capacity at the end of 400th cycle is found to be 137.73 Ah. The error between model/experiments is found to be less than 3.5% for all cycles.
Technical Paper

Extended Range Electric Vehicle Powertrain Simulation, and Comparison with Consideration of Fuel Cell and Metal-Air Battery

2017-03-28
2017-01-1258
The automobile industry has been undergoing a transition from fossil fuels to a low emission platform due to stricter environmental policies and energy security considerations. Electric vehicles, powered by lithium-ion batteries, have started to attain a noticeable market share recently due to their stable performance and maturity as a technology. However, electric vehicles continue to suffer from two disadvantages that have limited widespread adoption: charging time and energy density. To mitigate these challenges, vehicle Original Equipment Manufacturers (OEMs) have developed different vehicle architectures to extend the vehicle range. This work seeks to compare various powertrains, including: combined power battery electric vehicles (BEV) (zinc-air and lithium-ion battery), zero emission fuel cell vehicles (FCV)), conventional gasoline powered vehicles (baseline internal combustion vehicle), and ICE engine extended range hybrid electric vehicle.
Technical Paper

Measurement of Temperature Gradient (dT/dy) and Temperature Response (dT/dt) of a Prismatic Lithium-Ion Pouch Cell with LiFePO4 Cathode Material

2017-03-28
2017-01-1207
Lithium-ion batteries, which are nowadays common in laptops, cell phones, toys, and other portable electronic devices, are also viewed as a most promising advanced technology for electric and hybrid electric vehicles (EVs and HEVs), but battery manufacturers and automakers must understand the performance of these batteries when they are scaled up to the large sizes needed for the propulsion of the vehicle. In addition, accurate thermo-physical property input is crucial to thermal modeling. Therefore, a designer must study the thermal characteristics of batteries for improvement in the design of a thermal management system and also for thermal modeling. This work presents a purely experimental thermal characterization in terms of measurement of the temperature gradient and temperature response of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration.
Journal Article

Thermal Management of Lithium-Ion Pouch Cell with Indirect Liquid Cooling using Dual Cold Plates Approach

2015-04-14
2015-01-1184
The performance, life cycle cost, and safety of electric and hybrid electric vehicles (EVs and HEVs) depend strongly on their energy storage system. Advanced batteries such as lithium-ion (Li-ion) polymer batteries are quite viable options for storing energy in EVs and HEVs. In addition, thermal management is essential for achieving the desired performance and life cycle from a particular battery. Therefore, to design a thermal management system, a designer must study the thermal characteristics of batteries. The thermal characteristics that are needed include the surface temperature distribution, heat flux, and the heat generation from batteries under various charge/discharge profiles. Therefore, in the first part of the research, surface temperature distribution from a lithium-ion pouch cell (20Ah capacity) is studied under different discharge rates of 1C, 2C, 3C, and 4C.
Technical Paper

Three-Dimensional Electrochemical Analysis of a Graphite/LiFePO4 Li-Ion Cell to Improve Its Durability

2015-04-14
2015-01-1182
Lithium-ion batteries (LIBs) are one of the best candidates as energy storage systems for automobile applications due to their high power and energy densities. However, durability in comparison to other battery chemistries continues to be a key factor in prevention of wide scale adoption by the automotive industry. In order to design more-durable, longer-life, batteries, reliable and predictive battery models are required. In this paper, an effective model for simulating full-size LIBs is employed that can predict the operating voltage of the cell and the distribution of variables such as electrochemical current generation and battery state of charge (SOC). This predictive ability is used to examine the effect of parameters such as current collector thickness and tab location for the purpose of reducing non-uniform voltage and current distribution in the cell. It is identified that reducing the non-uniformities can reduce the ageing effects and increase the battery durability.
Technical Paper

Internal Resistance Optimization Utilizing “Just in Time” Control

2015-04-14
2015-01-1234
Inspection of cell internal resistance (Rint) derived by the hybrid pulse power characterization (HPPC) tests indicates that Rint is a function of relative capacity (state of charge, or SOC), thus some SOC ranges are more efficient than others. Therefore energy losses can be minimized by placing charge sustaining operation in a more efficient SOC range. This creates three operational stages; the initial charge depleting stage to an efficient SOC, a charge sustaining stage until a recharge station is within reach, and a final charge depleting stage until arrival. When coupled with a known drive distance, this three segment Internal Resistance Based (IRB) control strategy increases the extended range electric vehicle (EREV) net battery efficiency from 96.8 to 97.3 % with an associated 14 % decrease in energy losses across the urban domestic drive schedule.
Technical Paper

Experimental Measurements of Thermal Characteristics of LiFePO4 Battery

2015-04-14
2015-01-1189
A major challenge in the development of the next generation electric and hybrid electric vehicle (EV and HEV) technology is the control and management of heat generation and operating temperatures. Vehicle performance, reliability and ultimately consumer market adoption are integrally dependent on successful battery thermal management designs. In addition to this, crucial to thermal modeling is accurate thermo-physical property input. Therefore, to design a thermal management system and for thermal modeling, a designer must study the thermal characteristics of batteries. This work presents a purely experimental thermal characterization of thermo-physical properties of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration. In this research, the thermal resistance and corresponding thermal conductivity of prismatic battery materials is evaluated.
Technical Paper

Thermal Behavior of Two Commercial Li-Ion Batteries for Plug-in Hybrid Electric Vehicles

2014-04-01
2014-01-1840
In electrified vehicle applications, the heat generated of lithium-ion (Li-ion) cells may significantly affect the vehicle range and state of health (SOH) of the pack. Therefore, a major design task is creation of a battery thermal management system with suitable control and cooling strategies. To this end, the thermal behavior of Li-ion cells at various temperatures and operating conditions should be quantified. In this paper, two different commercial pouch cells for plug-in hybrid electric vehicles (PHEVs) are studied through comprehensive thermal performance tests. This study employs a fractional factorial design of experiments to reduce the number of tests required to characterize the behavior of fresh cells while minimizing the effects of ageing. At each test point, the effects of ambient temperature and charge/discharge rate on several types of cell efficiencies and surface heat generation are evaluated.
Technical Paper

Modeling and Evaluation of Li-Ion Battery Performance Based on the Electric Vehicle Field Tests

2014-04-01
2014-01-1848
In this paper, initial results of Li-ion battery performance characterization through field tests are presented. A fully electrified Ford Escape that is equipped by three Li-ion battery packs (LiFeMnPO4) including an overall 20 modules in series is employed. The vehicle is in daily operation and data of driving including the powertrain and drive cycles as well as the charging data are being transferred through CAN bus to a data logger installed in the vehicle. A model of the vehicle is developed in the Powertrain System Analysis Toolkit (PSAT) software based on the available technical specification of the vehicle components. In this model, a simple resistive element in series with a voltage source represents the battery. Battery open circuit voltage (OCV) and internal resistance in charge and discharge mode are estimated as a function of the state of charge (SOC) from the collected test data.
Technical Paper

Evaluation of Air Conditioning Impact on the Electric Vehicle Range and Li-Ion Battery Life

2014-04-01
2014-01-1853
Despite significant progress toward application of Li-ion batteries in electric vehicles, there are still major concerns about the range of electric vehicles and battery life. Depending on the climate of the region where the vehicle is in use, auxiliary loads could also play a significant role on the battery performance and durability. In this paper, the effect of air conditioning (AC) load on the electric range and Li-ion battery life is evaluated. For this purpose, a thermodynamic model for the vehicle cabin is developed and integrated to a battery model. The thermodynamic model takes the ambient conditions, solar load, and the vehicle drive cycle as inputs and calculates the instantaneous cabin temperature and humidity. The battery model, which represents a Li-on battery pack installed on a fully electrified Ford Escape 2009, consists of a voltage source in series with a lump resistance, a thermal sub-model, and a degradation sub-model to predict the battery capacity fade.
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