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The global push towards reducing green-house gas and criteria pollutant emissions is leading to tighter emission standards for heavy-duty engines. Among the most stringent of these standards are the California Air Resource Board (CARB) 2024+ HD Omnibus regulations adopted by the agency in August 2020. The CARB 2024+ HD Omnibus regulations require up to 90% reduction in NOx emissions along with updated compliance testing methods for on-road heavy-duty engines. Subsequently, the agency announced development of new Tier 5 standards for off-road engines in November 2021. The Tier 5 standards aim to reduce NOx/PM emissions by 90%/75% respectively from Tier 4 final levels, along with introduction of greenhouse gas emission standards for CO2/CH4/N2O/NH3. Furthermore, CARB is also considering similar updates on compliance testing as those implemented in 2024+ HD Omnibus regulations including, low-load cycle, idle emissions and 3-bin moving average in-use testing.

The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.

This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.

Vehicle OEM’s for MHD applications are facing significant challenges in meeting the stringent 2027 low-NOx and GHG emissions regulations. To meet such challenges, advanced engine and aftertreatment technologies along with powertrain electrification are being applied to achieve robust solutions. FEV has previously conducted model-based assessments to show the potential of 48V engine and aftertreatment technologies to simultaneously meet GHG and low NOx emission standards. This study focuses on evaluating the full potential of 48V electrification technology through addition of 48V P3 hybrid system to the previously developed 48V advanced engine and aftertreatment technology package. Previously, a model-based approach was utilized for selection and sizing of a 48V system-enabled engine and aftertreatment package for class 6-7 MHD application.

The Environmental Protection Agency (EPA) and California Air Resources Board (CARB) have recently announced rulemakings focused on tighter emission limits for oxides of nitrogen (NOx) from heavy-duty trucks. As part of the new rulemaking CARB has proposed a Low Load Cycle (LLC) to specifically evaluate NOx emission performance over real-world urban and vocational operation typically characterized by low engine loads, thereby demanding the implementation of continuous active thermal management of the engine and aftertreatment system. This significant drop in NOx levels along with continued reduction in the Green House Gas (GHG) limits poses a more significant challenge for the engine developer as the conventional emission reduction approaches for one species will likely result in an undesirable increase in the other species.

Conventional diesel engines will continue to hold a vital role in the heavy- and medium-duty markets for the transportation of goods along with many other uses. The ability to offset traditional diesel fuels with low-net-carbon biofuels could have a significant impact on reducing the carbon footprint of these vehicles. A prior study screened several hundred candidate biofuel blendstocks based on required diesel blendstock properties and identified 12 as the most promising. Eight representative biofuel blendstocks were blended at a 30% volumetric concentration with EPA certification ultra-low-sulfur diesel (ULSD) and were investigated for emissions and fuel efficiency performance. This study used a single cylinder engine (based on the Ford 6.7L engine) using Conventional Diesel Combustion (CDC), also known as Mixing Control Compression Ignition (MCCI). The density, cetane number, distillation curve and sooting tendency (using the yield sooting index method) of the fuels were measured.

Electrification of heavy-duty trucks has received significant attention in the past year as a result of future regulations in some states. For example, California will require a certain percentage of tractor trailers, delivery trucks and vans sold to be zero emission by 2035. However, the relatively low energy density of batteries in comparison to diesel fuel, as well as the operating profiles of heavy-duty trucks, make the application of electrified powertrain in these applications more challenging. Heavy-duty vehicles can be broadly classified into two main categories; long-haul tractors and vocational vehicles. Long-haul tractors offer limited benefit from electrification due to the majority of operation occurring at constant cruise speeds, long range requirements and the high efficiency provided by the diesel engine.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

While significant progress has been made in recent years to develop hybrid and battery electric vehicles for passenger car and light-duty applications to meet future fuel economy targets, the application of hybrid powertrains to heavy-duty truck applications has been very limited. The relatively lower energy and power density of batteries in comparison to diesel fuel and the operating profiles of most heavy-duty trucks, combine to make the application of hybrid powertrain for these applications more challenging. The high torque and power requirements of heavy-duty trucks over a long operating range, the majority of which is at constant cruise point, along with a high payback period, complexity, cost, weight and range anxiety, make the hybrid and battery electric solution less attractive than a conventional powertrain.

When considered along with Phase 2 Greenhouse Gas (GHG) requirements, the proposed Air Resource Board (ARB) nitrogen oxide (NOx) emission limit of 0.02 g/bhp-hr will be very challenging to achieve as the trade-off between fuel consumption and NOx emissions is not favorable. To meet any future ultra-low NOx emission regulation, the NOx conversion efficiency during the cold start of the emission test cycles needs to be improved. In such a scenario, apart from changes in aftertreatment layout and formulation, additional heating measures will be required. In this article, a physics-based model for an advanced aftertreatment system comprising of a diesel oxidation catalyst (DOC), an SCR-catalyzed diesel particulate filter (SDPF), a stand-alone selective catalytic reduction (SCR), and an ammonia slip catalyst (ASC) was calibrated against experimental data.

In-use compliance under LEV III emission standards, GHG, and fuel economy targets beyond 2025 poses a great opportunity for all ICE-based propulsion systems, especially for light-duty diesel powertrain and aftertreatment enhancement. Though diesel powertrains feature excellent fuel-efficiency, robust and complete emissions controls covering any possible operational profiles and duty cycles has always been a challenge. Significant dependency on aftertreatment calibration and configuration has become a norm. With the onset of hybridization and downsizing, small steps of improvement in system stability have shown a promising avenue for enhancing fuel economy while continuously improving emissions robustness. In this paper, a study of current key technologies and associated emissions robustness will be discussed followed by engine and aftertreatment performance target derivations for LEV III compliant powertrains.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

In view of changing climatic conditions all over the world, Green House Gas (GHG) saving related initiatives such as reducing the CO2 emissions from the mobility and transportation sectors have gained in importance. Therefore, with respect to the large U.S. market, the corresponding legal authorities have defined aggressive and challenging targets for the upcoming time frame. Due to several aspects and conditions, like hesitantly acting clients regarding electrically powered vehicles or low prices for fossil fuels, convincing and attractive products have to be developed to merge legal requirements with market constraints. This is especially valid for the market segment of Light-Duty vehicles, like SUV’S and Pick-Up trucks, which are in high demand.

For renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement.

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

Several high octane number oxygenates that could be derived from biomass were blended with gasoline and examined for performance properties and their impact on knock resistance and fine particle emissions in a single cylinder direct-injection spark-ignition engine. The oxygenates included ethanol, isobutanol, anisole, 4-methylanisole, 2-phenylethanol, 2,5-dimethyl furan, and 2,4-xylenol. These were blended into a summertime blendstock for oxygenate blending at levels ranging from 10 to 50 percent by volume. The base gasoline, its blends with p-xylene and p-cymene, and high-octane racing gasoline were tested as controls. Relevant gasoline properties including research octane number (RON), motor octane number, distillation curve, and vapor pressure were measured. Detailed hydrocarbon analysis was used to estimate heat of vaporization and particulate matter index (PMI). Experiments were conducted to measure knock-limited spark advance and particulate matter (PM) emissions.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.

Substitution of diesel fuel with natural gas in heavy-duty diesel engines offers significant advantages in terms of operating cost, as well as NOx, PM emissions and greenhouse gas emissions. However, the challenges of high THC and CO emissions, combustion stability, exhaust temperatures and pressure rise rates limit the substitution levels across the engine operating map and necessitate an optimized combustion strategy. Reactivity controlled compression ignition (RCCI) combustion has shown promise in regard to improving combustion efficiency at low and medium loads and simultaneously reducing NOx emissions at higher loads. RCCI combustion exploits the difference in reactivity between two fuels by introducing a less reactive fuel, such as natural gas, along with air during the intake stroke and igniting the air-CNG mixture by injecting a higher reactivity fuel, such as diesel, later in the compression stroke.

Upcoming motor vehicle emission regulations, such as California's LEVIII, continue to tighten emission limitations in diesel vehicles. These increasingly challenging emission requirements will be met by improving the combustion process (reducing engine-out emissions), as well as improving the exhaust gas aftertreatment efficiency. Furthermore, intricate On-Board Diagnostics (OBD) systems are required to properly diagnose and meet OBD regulation requirements for complex aftertreatment systems. Under these conditions, current monitoring strategies are unable to guarantee reliable detection of partially failed systems. Additionally, new OBD regulations require aftertreatment systems to be diagnosed as a whole. This paper covers potential OBD strategies for LEVIII aftertreatment concepts with regard to regulation compliance and robustness, while striving to use existing sensor concepts.