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Increasingly stringent emission standards have promoted the interest in alternate fuel sources. Because of the comparable energy density to the existing fossil fuels and renewable production, alcohol fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. In this research, the combustion characteristics of neat n-butanol are analyzed under spark ignition operation using a single cylinder SI engine. The fuel is injected into the intake manifold using a port-fuel injector. Two modes of charge dilution were used in this investigation to test the limits of stable engine operation, namely lean burn using excess fresh air and exhaust gas recirculation (EGR). The in-cylinder pressure measurement and subsequently, heat release analysis are used to investigate the combustion characteristics of the fuel under low load SI engine operation.

The control of combustion phasing in homogeneous charge compression ignition (HCCI) combustion is investigated with neat n-butanol in this work. HCCI is a commonly researched combustion mode, owing to its improved thermal efficiency over conventional gasoline combustion, as well as its lower nitrogen oxide (NOx) and particulate matter emissions compared to those of diesel combustion. Despite these advantages, HCCI lacks successful widespread implementation with conventional fuels, primarily due to the lack of effective combustion phasing control. In this preliminary study, chemical kinetic simulations are conducted to study the auto-ignition characteristics of n-butanol under varied background pressures, temperatures, and dilution levels using established mechanisms in CHEMKIN software. Increasing the pressure or temperature lead to a shorter ignition delay, whereas increasing the dilution by the application of exhaust gas recirculation (EGR) leads to a longer ignition delay.

Owing to the stochastic nature of engine knock, determination of the knock limited spark angle (KLSA) is difficult in engine cycle simulation. Therefore, the state-of-the-art knock modeling is mostly limited to either merely predicting knock onset (i.e. auto-ignition of end gas) or combining a simple unburned mass fraction (UMF) model representative of knock intensity (KI). In this study, a newly developed KLSA model, which takes both predictions of knock onset and intensity into account, is firstly introduced. Multiple variables including the excess air ratio, EGR ratio, cylinder pressure and the end gas temperature are included in the knock onset model. Based on the auto-ignition theory of hot spots in end gas, both the energy density and heat release rate in hot spots are taken into consideration in the KI model.

This paper examines the diesel-ethanol dual fuel combustion at medium engine loads on a single-cylinder research diesel engine with a compression ratio of 16.5:1. The effect of exhaust gas recirculation (EGR) and ethanol energy ratio was investigated for the dual fuel combustion to achieve simultaneously ultra-low NOx and soot emissions. A medium ethanol ratio of about 0.6 was found suitable to meet the requirements for mixing enhancement and ignition control, which resulted in the lowest NOx and soot emissions among the tested ethanol ratios. A double-pilot injection strategy was found competent to lower the pressure rise rate owing to the reduced fuel quantity in the close-to-TDC injection. The advancement of pilot injection timing tended to reduce the CO and THC emissions, which is deemed beneficial for high EGR operations. The reactivity mutual-modulation between the diesel pilot and the background ethanol mixture was identified.

The combustion of dual-fuel engines usually uses a pilot flame to burn out a background fuel inside a cylinder under high compression. The background fuel can be either a gaseous fuel or a volatile liquid fuel, commonly with low reactivity to prevent premature combustion and engine knocking; whereas the pilot flame is normally set off with the direct injection of a liquid fuel with adequate reactivity that is suitable for deterministic auto-ignition with a high compression ratio. In this work, directly injected butanol is used to generate the pilot flame, while intake port injected ethanol or butanol is employed as the background fuel. Compared with the conventional diesel-only combustion, dual-fuel operations not only broaden the fuel applicability, but also enhance the potential for clean combustion, in high efficiency engines. The amount of background fuel and the scheduling of pilot flame are investigated through extensive laboratory experiments.

The improvement mechanism of fuel consumption at partial and full loads of a boosted direction-injection gasoline engine with the elevated geometrical compression ratio and Miller cycle by either early or late intake valve closing (EIVC or LIVC) are analyzed based on the first law of thermodynamics and one dimensional engine simulation. An increase in geometric compression ratio increases the theoretical thermal efficiency for all the operating loads, but deteriorates the fuel economy at full loads, owing primarily to the full-load knock limit. Use of Miller cycle improves the fuel economy for both the partial and full load operations by reducing the pumping loss and optimizing the combustion phasing, respectively. A comparison between EIVC and LIVC on the influencing factors on the thermal efficiency at the partial load shows that EIVC leads to higher mechanical efficiency and less heat transfer loss than LIVC, and hence its efficiency improvement is superior over LIVC.

This paper studies the effect of cooled EGR on fuel consumption and anti-knock performance of a boosted port fuel injection (PFI) SI engine. Experimental results show that the cooled EGR increases the thermal efficiency by 2%∼18% depending on the operation conditions. Compared to low load operations, more improvements of the thermal efficiency are obtained at higher loads, primarily owing to the enhanced anti-knock performance, advanced combustion phasing, elimination of fuel-rich operations as well as reduced heat transfer loss with cooled EGR. The anti-knock performance of cooled EGR provides further potential to improve the thermal efficiency by increasing the compression ratio. To this end, a 1-D thermodynamic model of the engine is built and calibrated using the GT-Power code. A knock prediction correlation considering EGR is developed and validated with the experimental data.

Characteristics of diesel combustion with low cetane number fuels with similar distillation temperatures to ordinary diesel fuel, including fuels with cetane number 32 and 39 (LC32, LC39), and a blend of n-cetane (n-hexadecane) and iso-cetane (2, 2, 4, 4, 6, 8, 8-heptamethylnonane) with cetane number 32 (CN32), were investigated. The effects of cooled exhaust gas recirculation (EGR) and pilot injection on characteristics of combustion and exhaust gas emissions with these fuels were examined in a naturally aspirated, single cylinder, diesel engine equipped with a common-rail fuel injection system. Even with the low cetane number fuels, quiet combustion with low levels of exhaust gas emissions comparable to ordinary diesel fuel was established by suitable control of intake oxygen levels and pilot injections.

This study makes use of the detailed mechanisms of n-heptane combustion, from gas reactions to soot particle formation and oxidation, and a two-stage model based on the CHEMKIN reactor network is developed and used to investigate the trade-off between soot and NOx emissions. The effects of the equivalence ratio, EGR, ambient pressure and temperature, and initial particle diameter are observed for various residence times. The results show that high rates of NOx formation are unavoidable under conditions where high reduction rates of soot particles are obtained. This suggests that suppression of the amount of soot during the formation stage is essential for simultaneous reductions in engine-out soot and NOx emissions.

The characteristics of smokeless low temperature diesel combustion in various fuel-air mixing was investigated by engine tests with high rates of cooled exhaust gas recirculation (EGR), three compression ratios, and fuels of various cetane numbers, as well as by computational fluid dynamics (CFD) simulation of the in-cylinder distributions of mixture concentration and temperature. The results show that besides combustion temperature, fuel-air mixing is also vital to efficient, smokeless, and low NOx diesel combustion. Smokeless and low NOx diesel combustion can be realized even with insufficient fuel-air mixing as long as the combustion temperature is sufficiently low. However low combustion temperature and insufficient oxygen due to ultra-high EGR cause very high UHC and CO emissions, and a severe deterioration in combustion efficiency.

Unregulated emissions from a DI diesel engine with ultra-high EGR low temperature combustion were analyzed using Fourier transform infrared (FTIR) spectroscopy and the reduction characteristics of both regulated and unregulated emissions by two exhaust catalysts were investigated. With ultra-high EGR suppressing the in-cylinder soot and Nox formation as well as with the exhaust catalysts removing the engine-out THC and CO emissions, clean diesel operation in terms of ultra-low regulated emissions (Nox, PM, THC, and CO) is established in an operating range up to 50% load. To realize smokeless low temperature combustion at higher loads, EGR has to be increased to a rate with the overall (average) excess air ratio less than the stoichiometric ratio.

The effects of blending ETBE to diesel fuel on the characteristics of low temperature diesel combustion and exhaust emissions were investigated in a naturally-aspirated DI diesel engine with large rates of cooled EGR. Low temperature smokeless diesel combustion in a wide EGR range was established with ETBE blended diesel fuel as mixture homogeneity is promoted with increased premixed duration due to decreases in ignitability as well as with improvement in fuel vaporization due to the lower boiling point of ETBE. Increasing the ETBE content in the fuel helps to suppress smoke emissions and maintain efficient smokeless operation when increasing EGR, however a too high ETBE content causes misfiring at larger rates of EGR. While the NOx emissions increase with increases in ETBE content at high intake oxygen concentrations, NOx almost completely disappears when reducing the intake oxygen content below 14 % with cooled EGR.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

The dependence of ultra-high EGR low temperature diesel combustion on fuel properties including cetane number and distillation temperature was investigated with a single-cylinder, naturally aspirated, 1.0 L, common rail DI diesel engine. Decreasing cetane number in fuels significantly reduces smoke emission due to an extension in ignition delay and the subsequent improvement in mixture formation. Smokeless combustion, ultra-low NOx, and efficient operating range with regard to EGR and IMEP are significantly extended by decreasing fuel cetane number. Changes in fuel distillation temperature do not result in significant differences in smoke emission and thermal efficiency for ultra-high EGR operation, and smokeless operation is established even with higher distillation temperature fuels as long as fuel cetane number is sufficiently low.

A sensor that passively monitors the driver for intoxication has been demonstrated. The driver's blood alcohol concentration (BAC) is obtained by sensing alcohol and CO2 in air drawn from the vehicle cabin. With a legally drunk driver, the steady state alcohol concentration can be as low as 0.3 ppm, even with the doors and windows closed. The sensor uses infrared transmission to quantify alcohol vapor and CO2. A vapor concentrator increases alcohol sensitivity - an adsorber collects alcohol vapor and releases it as a concentrated burst at 1 minute intervals. A valid measure of driver BAC is ordinarily available 1.5 minutes after the driver gets in. Sensed CO2 must be above a threshold for a valid measurement.

In the previous study of the authors, it was found that some benefits for the mixture preparation of DI gasoline engines can be offered by splitting the fuel injection, such as the phenomenon of high density liquid phase fuel piling up at the leading edge of the spray can be circumvented. In a further analysis, the vapor quantity in the “stable operating” range (equivalence ratio of vapor ϕv in a range of 0.7≤ϕv≤1.3) was significantly increased by the split injection compared to the single injection. In this work, the mechanism of the effect of the split injection on the mixture formation process was studied by combining the laser-sheet imaging, LIF-PIV and the LAS (Laser Absorption Scattering) technique. As a result, it is found that the spray-induced ambient air motion can help the formation of the more combustible mixture of the split injection whereas it played a minus role of diluting the spray by the single injection.

Mixture formation processes play a vital role on the performance of a D.I. Gasoline engine. Quantitative measurement of liquid and vapor phase concentration distribution in a D.I. gasoline spray is very important in understanding the mixture formation processes. In this paper, an unique laser absorption scattering (LAS) technique was employed to investigate the mixture formation processes of a fuel spray injected by a D.I. gasoline injector into a high pressure and temperature constant volume vessel. P-xylene, which is quite suitable for the application of the LAS technique, was selected as the test fuel. The temporal variations of the concentration distribution of both the liquid and vapor phases in the spray were quantitatively clarified. Then the effects of injection pressure and quantity on the concentration distributions of both the liquid and vapor phases in the spray were analyzed.

To get quantitative measurements of liquid and vapor phase concentration distributions in a gasoline spray, a laser-based absorption and scattering (LAS) technique was developed. The LAS technique adopts ultraviolet and visible lasers as light sources and a test fuel, which absorbs the ultraviolet light but does not absorb the visible light, instead of gasoline. The LAS principle is based on the incident light extinction in the ultraviolet band due to both vapor absorption and droplets scattering, whereas in the visible band, the incident light extinction is due only to the droplet scattering. The absorption spectra and molar absorption coefficients of the candidate test fuels including p-xylene, benzene and toluene, all of which have physical properties similar to gasoline, were investigated, and p-xylene was finally selected as a test fuel. Measurement accuracy of the LAS technique was discussed.