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With the development of downsized spark ignition (SI) engines, low-speed pre-ignition (LSPI) has been observed more frequently as an abnormal combustion phenomenon, and there is a critical need to solve this issue. It has been acknowledged that LSPI is not directly triggered by autoignition of the fuel, but by some other material with a short ignition delay time. It was previously reported that LSPI can be caused by droplets of lubricant oil intermixed with the fuel. In this work, the ignition behavior of lubricant component containing fuel droplets was experimentally investigated by using a constant volume chamber (CVC) and a rapid compression and expansion machine (RCEM), which enable visualization of the combustion process in the cylinder. Various combinations of fuel compositions for the ambient fuel-air mixture and fractions of base oil/metallic additives/fuel for droplets were tested.

A mixed time-scale subgrid large eddy simulation was used to simulate mixture formation, combustion and soot formation under the influence of turbulence during diesel engine combustion. To account for the effects of engine wall heat transfer on combustion, the KIVA code's standard wall model was replaced to accommodate more realistic boundary conditions. This were carried out by implementing the non-isothermal wall model of Angelberger et al. with modifications and incorporating the log law from Pope's method to account for the wall surface roughness. Soot and NOx emissions predicted with the new model are compared to experimental data acquired under various EGR conditions.

The objective of this paper is to investigate the potential of lean burn combustion to improve the thermal efficiency of spark ignition engine. Experiments used a single cylinder gasoline spark ignition engine fueled with primary reference fuel of octane number 90, running at 4000 revolution per minute and at wide open throttle. Experiments were conducted at constant fueling rate and in order to lean the mixture, more air is introduced by boosted pressure from stoichiometric mixture to lean limit while maintaining the high output engine torque as possible. Experimental results show that the highest thermal efficiency is obtained at excess air ratio of 1.3 combined with absolute boosted pressure of 117 kPa. Three dimensional computational fluid dynamic simulation with detailed chemical reactions was conducted and compared with results obtained from experiments as based points.

The objective of the present study is to analyze soot formation in diesel engine combustion by using multi-dimensional combustion simulations with a parallelized explicit ODE solver. Parallelized CHEMEQ2 was used to perform detailed chemical kinetics in KIVA-4 code. CHEMEQ2 is an explicit stiff ODE solver developed by Mott et al. which is known to be faster than traditional implicit ODE solvers, e.g., DVODE. In the present study, about eight times faster computation was achieved with CHEMEQ2 compared to DVODE when using a single thread. Further, by parallelizing CHEMEQ2 using OpenMP, the simulations could be run not only on calculation servers but also on desktop machines. The computation time decreases with the number of threads used. The parallelized CHEMEQ2 enabled combustion and emission characteristics, including detailed soot formation processes, to be predicted using KIVA-4 code with detailed chemical kinetics without the need for reducing the reaction mechanism.

As the petroleum depletion, some of this demand will probably have to be met by increasing the production of diesel fuels from heavy oil or unconventional oil in the near future. Such fuels may inevitably have a lower cetane number (CN) with a higher concentration of aromatic components. The objective of the present research is to identify the effects of a typical biodiesel fuel as a CN improver for a light-duty diesel engine for passenger cars. Our previous study indicates that methyl oleate (MO), which is an oxygenated fuel representative of major constituents of many biodiesel types, can reduce soot and NOx emissions simultaneously by optimizing performance under exhaust gas recirculation (EGR) when used as a diesel fuel additive. In addition, it was found that MO tends to reduce the ignition delay. We employed a 2.2 L passenger car DI diesel engine complying with the Euro 4 emissions regulation.

The objective of the present research is to analyze the effects of using oxygenated fuels (FAMEs) on diesel engine combustion and emission (NOx and soot). We studied methyl oleate (MO), which is an oxygenated fuel representative of major constituents of many types of biodiesels. Engine tests and numerical simulations were performed for 100% MO (MO100), 40% MO blended with JIS#2 diesel (MO40) and JIS#2 diesel (D100). The effects of MO on diesel combustion and emission characteristics were studied under engine operating conditions typically encountered in passenger car diesel engines, focusing on important parameters such as pilot injection, injection pressure and exhaust gas recirculation (EGR) rate. We used a diesel engine complying with the EURO4 emissions regulation, having a displacement of 2.2 L for passenger car applications. In engine tests comparing MO with diesel fuel, no effect on engine combustion pressure was observed for all conditions tested.

N₂O is known to have a significantly high global warming potential. We measured N₂O emissions in engine-bench tests by changing the NO/NH₃ ratio and exhaust gas temperature at the oxidation catalyst inlet in a heavy-duty diesel engine equipped with a urea SCR (selective catalytic reduction) system. The results showed that the peak N₂O production ratio occurred at an exhaust gas temperature of around 200°C and the maximum value was 84%. Moreover, the N₂O production ratio increased with increasing NO/NH₃. Thus, we concluded that N₂O is produced via the NO branching reaction. Based on our results, two methods were proposed to decrease N₂O formation. At low temperatures ~200°C, NO should be reduced by controlling diesel combustion to lower the contribution of NO to N₂O production. This is essential because the SCR system cannot reduce NOx at low temperatures.

A urea SCR system was combined with a DPF system to reduce NOx and PM in a four liters turbocharged with intercooler diesel engine. Significant reduction in NOx was observed at low exhaust gas temperatures by increasing NH3 adsorption quantity in the SCR catalyst. Control logic of the NH3 adsorption quantity for transient operation was developed based on the NH3 adsorption characteristics on the SCR catalyst. It has been shown that NOx can be reduced by 75% at the average SCR inlet gas temperature of 158 deg.C by adopting the NH3 adsorption quantity control in the JE05 Mode.

Urea-SCR system has a high NOx reduction potential in the steady-state diesel engine operation. In complicated transient operations, however, there are certain problems with the urea-SCR system in that NOx reduction performance degrades and adsorbed NH3 would be emitted. Here, optimum urea injection methods and exhaust bypass control to overcome these problems are studied. This exhaust bypass control enables NO/NOx ratio at the inlet of SCR catalyst to be decreased widely, which prevents over production of NO2 at the pre-oxidation catalyst. Steady-state and simple transient engine tests were conducted to clarify NOx reduction characteristics when optimum urea injection pattern and exhaust bypass control were applied. In simple transient test, only the engine load was rapidly changed for obtaining the fundamental knowledge concerning the effect of those techniques.

To improve urban air pollution, stringent emissions regulations for heavy-duty diesel engines have been proposed and will become effective in Japan, the EU, and the United States in a few years. To comply with such future regulations, it is critical to investigate the effects of intake and injection parameters and fuel properties on engine performance, efficiency and emissions characteristics, associated with the use of aftertreatment systems. An experimental study was carried out to identify such effects. In addition, the KIVA-3 code was used to gain insight into cylinder events. The results showed improvements in NOx-Smoke and BSFC trade-offs at high-pressure injection in conjunction with EGR and supercharging.

A numerical study was carried out to investigate combustion characteristics of a dual-fuel gas diesel engine, using a multi-dimensional model combined with detailed chemical kinetics, including 43 chemical species and 173 elementary reactions. In calculations, the effects of initial temperature, EGR ratios on ignition, and combustion were examined. The results indicated EGR combined with intake preheating can favorably reduced NOx and THC emissions simultaneously. This can be explained by the fact that combustion mechanism is changed from flame propagation to HCCl like combustion.

An experimental and numerical study has been conducted on the emission and reduction of HCHO (formaldehyde) and other pollutants formed in the cylinder of a direct-injection diesel engine fueled by methanol. Engine tests were performed under a variety of intake conditions including throttling, heating, and EGR (exhaust gas recirculation) for the purpose of improving these emissions by changing gas compositions and combustion temperatures in the cylinder. Moreover, a detailed kinetics model was developed and applied to methanol combustion to investigate HCHO formation and the reduction mechanism influenced by associated elementary reactions and in-cylinder mixing.

Dual-fuel operation of a direct-injection diesel engine with natural gas fuel can yield a high thermal efficiency almost comparable to the diesel operation at higher loads. The dual-fuel operation, however, at lower loads inevitably suffers from lower thermal efficiency and higher unburned fuel. To improve this problem, engine tests were carried out on a variety of engine parameters including diesel fuel injection timing advance, intake throttling and hot and cooled exhaust gas recirculation (EGR). It was found that diesel injection timing advance gave little improvement in thermal efficiency and increased NOx. Intake throttling promoted better combustion and shortened its duration with a consequent improvement in efficiency at higher natural gas fractions. Hot EGR raised thermal efficiency, reduced smoke levels, and maintained low NOx levels. Cooled EGR reduced NOx emissions but lowered thermal efficiency.

An experimental study has been made of a single cylinder, direct-injection diesel engine having a re-entrant combustion chamber designed to enhance combustion so as to reduce exhaust emissions. Special emphasis has been placed on controlling the inert gas concentration in the localized fuel-air mixture to lower combustion gas temperatures, thereby reduce exhaust NOx emission. For this specific purpose, an exhaust gas recirculation (EGR) system, which has been widely used in gasoline engines, was applied to the DI diesel engine to control the intake inert gas concentration. In addition, supercharging and increasing fuel injection pressure prevent the deterioration of smoke and unburned hydrocarbons and improve fuel economy, as well.