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Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.

Introduction of modern diesel aftertreatment, primarily selective catalytic reduction (SCR) designed to reduced NOx, has increased the presence of urea decomposition byproducts, mainly ammonia, in the aftertreatment system. This increase in ammonia has been shown to lead to particle formation in the aftertreatment system. In this study, a state of the art diesel exhaust fluid (DEF)-SCR system was investigated in order to determine the influence of DEF dosing on solid particle count. Post diesel particulate filter (DPF) particle count (> 23 nm) is shown to increase by over 400% during the World Harmonized Transient Cycle (WHTC) due to DEF dosing. This increase in tailpipe particle count warranted a detailed parametric study of DEF dosing parameters effect on tailpipe particle count. Global ammonia to NOx ratio, DEF droplet residence time, and SCR catalyst inlet temperature were found to be significant factors in post-DPF DEF based particle formation.

U.S. and European nonroad diesel emissions regulations have led to the implementation of various exhaust aftertreatment solutions. One approved configuration, a vanadium-based selective catalytic reduction catalyst followed by an ammonia oxidation catalyst (V-SCR + AMOX), does not require the use of a diesel oxidation catalyst (DOC) or diesel particulate filter (DPF). While certification testing has shown the V-SCR + AMOX system to be capable of meeting the nitrogen oxides, carbon monoxide, and particulate matter requirements, open questions remain regarding the efficacy of this aftertreatment for volatile and nonvolatile organic emissions removal, especially since the removal of this class of compounds is generally attributed to both the DOC and DPF.

Diesel engines have been identified as contributing to more than half of the transport sectors black carbon (BC) emissions in the US. This large contribution to atmospheric BC concentrations has raised concern about source specific emission rates, including off-highway engines. The European Union has recently implemented more stringent particulate regulations in the form of particle number via the Particle Measurement Programme (PMP) methodology. The PMP method counts the non-volatile fraction of particulate matter (PM) above 23 nm and below 2.5 μm via a condensation particle counter. This study evaluates a surrogate black carbon method which uses the PMP particle count method with a correlation factor to the BC fraction. The transient capable Magee Scientific Aethalometer (AE-33) 880 nm wavelength channel was used to determine the BC fraction.

Light absorbing components of aerosols, often called black carbon (BC), are emitted from combustion sources and are believed to play a considerable role in direct atmospheric radiative forcing by a number of climate scientists. In addition, it has been shown that BC is associated with adverse health effects in a number of epidemiological studies. Although the optical properties (both absorbing and scattering) of combustion aerosols are needed in order to accurately assess the impact of emissions on radiative forcing, many models use radiative properties of diesel particulate matter that were determined over two decades ago. In response to concerns of the human health impacts of particulate matter (PM), regulatory bodies around the world have significantly tightened PM emission limits for diesel engines. These requirements have resulted in considerable changes in engine technology requiring updated BC measurements from modern engines equipped with aftertreatment systems.

Titanium dioxide supported vanadium oxide catalysts have been successfully utilized for the selective catalytic reduction (SCR) of nitrogen oxides emitted from both stationary and mobile sources. Because of their cost and performance advantages in certain applications, vanadium-based SCR catalysts are now also being considered for integration into some U.S. Tier IV off-highway aftertreatment systems. However, concern exists that toxic vanadium compounds, such as vanadium pentoxide, could be released from these catalysts as a result of mechanical attrition or high temperature volatility. An experimental study has been conducted to compare various techniques for measuring the release of particle and vapor-phase vanadium from SCR catalysts. Previous research has utilized a powder reactor-based method to measure the vapor-phase release of vanadium, but there are inherent limitations to this technique.

A comparative analysis was made on the emissions from a 2004 and a 2007 heavy-duty diesel engine to determine how new engine and emissions technologies have affected the chemical compounds found in the exhaust gases. Representative samples were collected from a source dilution sampling system and analyzed for both criteria and unregulated gaseous and particulate emissions. Results have shown that the 2007 regulations compliant engine and emissions technology not only reduced the specifically regulated exhaust pollutants, but also significantly reduced the majority of unregulated chemical species. It is believed that these reductions were achieved through the use of engine optimization, aftertreatment system integration, and ultra-low sulfur diesel fuel.

Studies have shown that there are a significant number of chemical species present in engine exhaust particulate matter emissions. Additionally, the majority of current world-wide regulatory methods for measuring engine particulate emissions are gravimetrically based. As modern engines considerably reduce particulate mass emissions, these methods become less stable and begin to display higher levels of measurement uncertainty. In this study, a characterization of mass emissions from three heavy-duty diesel engines, with a range of particulate emission levels, was made in order to gain a better understanding of the variability and uncertainty associated with common mass measurement methods, as well as how well these methods compare with each other. Two gravimetric mass measurement methods and a reconstructed mass method were analyzed as part of the present study.

Diesel particulate filters are designed to reduce the mass emissions of diesel particulate matter and have been proven to be effective in this respect. Not much is known, however, about their effects on other unregulated chemical species. This study utilized source dilution sampling techniques to evaluate the effects of a catalyzed diesel particulate filter on a wide spectrum of chemical emissions from a heavy-duty diesel engine. The species analyzed included both criteria and unregulated compounds such as particulate matter (PM), carbon monoxide (CO), hydrocarbons (HC), inorganic ions, trace metallic compounds, elemental and organic carbon (EC and OC), polycyclic aromatic hydrocarbons (PAHs), and other organic compounds. Results showed a significant reduction for the emissions of PM mass, CO, HC, metals, EC, OC, and PAHs.

The effects of fuel sulfur content and dilution conditions on diesel engine PM number emissions have been researched extensively through steady state testing. Most results show that the concentration of nuclei-mode particles emitted increases with fuel sulfur content. A few studies further observed that fuel sulfur content has little effect on the emissions of heavily-used engines. It has also been found that primary dilution conditions can have a large impact on the size and number distribution of the nuclei-mode particles. These effects, however, have not yet been fully understood through transient testing, the method used by governments worldwide to certify engines and regulate emissions, and a means of experimentation which generates realistic conditions of on-road vehicles by varying the load and speed of the engine.

The performance of diesel particulate filters (DPF) has historically been evaluated by gravimetric efficiency, which measures the mass of particulate matter (PM) trapped in the filters. This method does not measure the filtration efficiency at different PM size ranges and, therefore, cannot provide information on fractional performance of DPFs. This fact becomes significant because the adverse effects of diesel PM emissions on human health and the environment are size dependent. A previous study investigated the fractional performance of DPFs under steady state conditions using a scanning mobility particle sizer (SMPS). In the real world, however, nearly all engines operate under transient conditions. DPFs also have to perform under such conditions, so any measurement of performance must be able to react to quickly changing DPF conditions.

While most reductions in diesel particulate matter (PM) have been implemented through internal engine improvements and aftertreatment systems, additional reductions may be found by controlling intake contaminants. Under the ideal conditions of operating with ultra low sulfur diesel fuel and filtered and conditioned intake air, a diesel engine produces a certain amount of PM. The PM emission levels may increase when intake air is polluted during harsh on- or off-road conditions. In this study, contaminants were allowed to enter the intake tract of the engine to determine whether or not increased particle ingestion leads to increased particulate matter expulsion. Diesel and test dust contaminants dispersed in intake air were filtered using both a conventional filtering medium and a nano-medium to determine their effects on diesel engine-out PM emissions. The paper characterizes the two media by microstructure, permeability, porosity, and fractional efficiency.

The characterization of engine particulate matter size distributions has become an important topic in the investigation of particulate matter formation, transport, and emission reduction technology. The majority of current size distribution analyses are conducted during steady state engine conditions. Although steady state analysis is valuable, most engines in mobile applications are operated under transient conditions, creating a demand for the transient state analysis of particulate emission patterns. In order to measure the instantaneous emissions of an engine under transient conditions, instrumentation must respond to the changing engine conditions as quickly as possible. In this study, a fast-scanning nanometer Aerosol Size Analyzer (n-ASA) was used to measure the emitted particles of a heavy duty diesel engine during transient simulations. The results showed patterns of PM emissions at key areas throughout the test.

In order to comply with tightening environmental standards, diesel particulate filters will be used for engine particle emission control. A well-defined testing method is needed to characterize and evaluate the diesel particulate filters. A previously developed testing method yielded unexpected results which were believed to be caused by dilution air contamination and particle formation downstream of the filters. In this study, the testing method has been modified in order to address these issues. Various wall-flow diesel particulate filters of fibrous and porous materials were tested using the modified method in this study. The results were compared with the previous data to evaluate the level of improvement. The results were also analyzed using particle size distributions and filtration mechanisms described by various theories. Particle size distributions demonstrated significant improvement of the modified testing method.

To meet stringent emission regulations, particulate filters will be required for diesel engines. Effective filters should reduce both the mass and number concentrations of particulate matter. For this reason, the performance of diesel particulate filters (DPFs) should be evaluated by measuring both gravimetric and fractional efficiency. This paper reports on a method developed for measuring particulate emissions on a mass and number basis. A two-stage dilution process was used in which the entire engine exhaust gas is directed into a primary dilution tunnel with a critical flow venturi. This constant volume system maintains proportional sampling throughout temperature excursions. A portion of the diluted exhaust gas is directed to a secondary dilution tunnel, for further dilution and determination of particle size distribution using a scanning mobility particle sizer. The engine was run at ISO 8178 modes.

The gravimetric method is commonly used in engine air filtration technology for air cleaner, filter element and filter media testing. An “absolute” filter is employed in-line to collect any dust particles passing through the test filter. Air filter efficiency is calculated by comparing the mass of dust collected by the test filter with that fed to the filter. This method measures only the mass of dust penetrating the filter. It does not provide information on contaminant particle size. Moreover, this method, in many cases, has inadequate precision to distinguish between filters. Both the dust mass and its particle size are needed to estimate engine wear. Therefore, the SAE J726 Air Cleaner Committee initiated work on a test method to measure engine air cleaner fractional efficiency. This paper discusses problems associated with development of the fractional efficiency method for engine air cleaners.