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Journal Article

Pollutants Emissions During Mild Catalytic DPF Regeneration In Light-Duty Vehicles

2009-04-20
2009-01-0278
La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367°C and the half conversion of CO reached at 141°C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.
Journal Article

Mild Catalytic DPF Regeneration and Related CO Emissions in Commercial Vehicles

2008-10-07
2008-01-2643
La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.
Technical Paper

DPF Supporting Nano-Structured Perovskite Catalysts for NOx and Diesel Soot Emission Control in Commercial Vehicles

2007-10-30
2007-01-4173
Nano-structured perovskite-type oxides catalysts La1-xAxFe1-yByO3 (where A = Na, K, Rb and B = Cu), prepared by the Solution Combustion Synthesis (SCS) method and characterized by BET, XRD, FESEM, AAS and catalytic activity tests in microreactors and engine bench, proved to be effective in the simultaneous removal of soot and NO, the two prevalent pollutants in diesel exhaust gases in the temperature range 350-450°C. The best compromise between soot and nitrogen oxide abatement was shown by La-K-Cu-FeO3 catalyst which displayed the highest catalytic activity towards carbon combustion and the highest NO conversion activity.
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