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SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications [1,2,3,4]. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH3 storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH3 storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH3 slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.
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Performance of Particle Oxidation Catalyst and Particle Formation Studies with Sulphur Containing Fuels

2012-06-18
The aim of this paper is to analyse the quantitative impact of fuel sulphur content on particulate oxidation catalyst (POC) functionality, focusing on soot emission reduction and the ability to regenerate. Studies were conducted on fuels containing three different levels of sulphur, covering the range of 6 to 340 parts per million, for a light-duty application. The data presented in this paper provide further insights into the specific issues associated with usage of a POC with fuels of higher sulphur content. A 48-hour loading phase was performed for each fuel, during which filter smoke number, temperature and back-pressure were all observed to vary depending on the fuel sulphur level. The Fuel Sulphur Content (FSC) affected also soot particle size distributions (particle number and size) so that with FSC 6 ppm the soot particle concentration was lower than with FSC 65 and 340, both upstream and downstream of the POC.
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SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
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Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
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Development of a 3rd Generation SCR NH3-Direct Dosing System for Highly Efficient DeNOx

2012-06-18
In this project funded by the Bayerische Forschungsstiftung two fundamental investigations had been carried out: first a new N-rich liquid ammonia precursor solution based on guanidine salts had been completely characterized and secondly a new type of side-flow reactor for the controlled catalytic decomposition of aqueous NH3 precursor to ammonia gas has been designed, applied and tested in a 3 liter passenger car diesel engine. Guanidine salts came into the focus due to the fact of a high nitrogen-content derivate of urea (figure 1). Specially guanidinium formate has shown extraordinary solubility in water (more than 6 kg per 1 liter water at room temperature) and therefore a possible high ammonia potential per liter solution compared to the classical 32.5% aqueous urea solution (AUS32) standardized in ISO 22241 and known as DEF (diesel emission fluid), ARLA32 or AdBlue®. Additionally a guanidine based formulation could be realized with high freezing stability down to almost ?30 °C (?
Video

Hydrocarbon Fouling of SCR During PCCI Combustion

2012-06-18
The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust.
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Experimental Study into a Hybrid PCCI/CI Concept for Next-Generation Heavy-Duty Diesel Engines

2012-06-18
This paper presents the first results of an experimental study into a hybrid combustion concept for next-generation heavy-duty diesel engines. In this hybrid concept, at low load operating conditions, the engine is run in Pre-mixed Charge Compression Ignition (PCCI) mode, whereas at high load conventional CI combustion is applied. This study was done with standard diesel fuel on a flexible multi-cylinder heavy-duty test platform. This platform is based on a 12.9 liter, 390 kW heavy-duty diesel engine that is equipped with a combination of a supercharger, a two-stage turbocharging system and low-pressure and high-pressure EGR circuitry. Furthermore, Variable Valve Actuation (VVA) hardware is installed to have sufficient control authority. Dedicated pistons, injector nozzles and VVA cam were selected to enable PCCI combustion for a late DI injection strategy, free of wall-wetting problems.
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DPF's Regeneration Procedures and Emissions with RME Blend Fuels

2012-06-18
The fatty acid methyl esters (FAME's) - in Europe mostly RME (Rapeseed methyl ester) - are used in several countries as alternative biogene Diesel fuels in various blending ratios with fossil fuels (Bxx). Questions often arise about the influences of these biocomponents on the modern exhaust aftertreatment systems and especially on the regeneration of Diesel particle filters (DPF). In the present work different regeneration procedures of DPF systems were investigated with biofuels B0, B20 & B100. The tested regeneration procedures were: passive regenerations: DOC + CSF; CSF alone, active regenerations: standstill burner; fuel injections & DOC. During each regeneration on-line measurements of regulated and unregulated emission components (nanoparticles & FTIR) were conducted. It can be stated that the increased portion of RME in fuel provokes longer time periods to charge the filter with soot.
Video

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO3 (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn4+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/?-Al2O3 (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO2).
Video

Characterization of a New Advanced Diesel Oxidation Catalyst with Low Temperature NOx Storage Capability for LD Diesel

2012-06-18
Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.
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Impact of Biodiesel on Particle Emissions and DPF Regeneration Management in a Euro5 Automotive Diesel Engine

2012-06-18
Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.
Video

Metal Oxide Particle Emissions from Diesel and Petrol Engines

2012-06-18
All internal combustion piston engines emit solid nanoparticles. Some are soot particles resulting from incomplete combustion of fuels, or lube oil. Some particles are metal compounds, most probably metal oxides. A major source of metal compound particles is engine abrasion. The lube oil transports these abraded particles into the combustion zone. There they are partially vaporized and ultrafine oxide particles formed through nucleation [1]. Other sources are the metallic additives to the lube oil, metallic additives in the fuel, and debris from the catalytic coatings in the exhaust-gas emission control devices. The formation process results in extremely fine particles, typically smaller than 50 nm. Thus they intrude through the alveolar membranes directly into the human organism. The consequent health risk necessitates a careful investigation of these emissions and effective curtailment.
Video

On-Road Evaluation of an Integrated SCR and Continuously Regenerating Trap Exhaust System

2012-06-18
Four-way, integrated, diesel emission control systems that combine selective catalytic reduction for NOx control with a continuously regenerating trap to remove diesel particulate matter were evaluated under real-world, on-road conditions. Tests were conducted using a semi-tractor with an emissions year 2000, 6-cylinder, 12 L, Volvo engine rated at 287 kW at 1800 rpm and 1964 N-m. The emission control system was certified for retrofit application on-highway trucks, model years 1994 through 2002, with 4-stroke, 186-373 kW (250-500 hp) heavy-duty diesel engines without exhaust gas recirculation. The evaluations were unique because the mobile laboratory platform enabled evaluation under real-world exhaust plume dilution conditions as opposed to laboratory dilution conditions. Real-time plume measurements for NOx, particle number concentration and size distribution were made and emission control performance was evaluated on-road.
Video

Development and Demonstration of a Low Emissions Four-Stroke Outboard Marine Engine Utilizing Catalyst Technology

2012-06-18
A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.
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An Experimental Analysis on Diesel/n-Butanol Blends Operating in Partial Premixed Combustion in a Light Duty Diesel Engine

2012-06-18
This paper reports results of an experimental investigation performed on a commercial diesel engine supplied with fuel blends having low cetane number to attain a simultaneous reduction in NOx and smoke emissions. Blends of 20% and 40% of n-butanol in conventional diesel fuel have been tested, comparing engine performance and emissions to diesel ones. Taking advantage of the fuel blend higher resistance to auto ignition, it was possible to extend the range in which a premixed combustion is achieved. This allowed to match the goal of a significant reduction in emissions without important penalties in fuel consumption. The experimental activity was carried on a turbocharged, water cooled, 4 cylinder common rail DI diesel engine. The engine equipment included an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injector.
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Teardown-Based Cost Assessment for Use in Setting Greenhouse Gas Emissions Standards

2012-06-18
The U.S. Environmental Protection Agency (EPA) contracted with FEV, Inc. to estimate the per-vehicle cost of employing selected advanced efficiency-improving technologies in light-duty motor vehicles. The development of transparent, reliable cost analyses that are accessible to all interested stakeholders has played a crucial role in establishing feasible and cost effective standards to improve fuel economy and reduce greenhouse gas (GHG) emissions. The FEV team, together with engineering staff from EPA's National Vehicle and Fuel Emissions Laboratory, and FEV's subcontractor, Munro & Associates, developed a robust costing methodology based on tearing down, to the piece part level, relevant systems, sub-systems, and assemblies from vehicles ?with and without? the technologies being evaluated.
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Development of DPF/SCR System for Heavy Duty Diesel Engine

2012-06-15
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Video

Impact of Supervisory Control on Criteria Tailpipe Emissions for an Extended-Range Electric Vehicle

2012-06-05
The Hybrid Electric Vehicle Team of Virginia Tech participated in the three-year EcoCAR Advanced Vehicle Technology Competition organized by Argonne National Laboratory, and sponsored by General Motors and the U.S. Department of Energy. The team established goals for the design of a plug-in, range-extended hybrid electric vehicle that meets or exceeds the competition requirements for EcoCAR. The challenge involved designing a crossover SUV powertrain to reduce fuel consumption, petroleum energy use, regulated tailpipe emissions, and well-to-wheel greenhouse gas emissions. To interface with and control the hybrid powertrain, the team added a Hybrid Vehicle Supervisory Controller, which enacts a torque split control strategy. This paper builds on an earlier paper [1] that evaluated the petroleum energy use, criteria tailpipe emissions, and greenhouse gas emissions of the Virginia Tech EcoCAR vehicle and control strategy from the 2nd year of the competition.
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Impact of Auxiliary Loads on Fuel Economy and Emissions in Transit Bus Applications

2012-05-25
In this paper we present the results of full-scale chassis dynamometer testing of two hybrid transit bus configurations, parallel and series and, in addition, quantify the impact of air conditioning. We also study the impact of using an electrically controlled cooling fan. The main trend that is noted, and perhaps expected, is that a significant fuel penalty is encountered during operation with air conditioning, ranging from 17-27% for the four buses considered. The testing shows that the series hybrid architecture is more efficient than the parallel hybrid in improving fuel economy during urban, low speed stop and go transit bus applications. In addition, smart cooling systems, such as the electrically controlled cooling fan can show a fuel economy benefit especially during high AC (or other increased engine load) conditions.
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Reduction of CO2 Emissions using Variable Compression Ratio MCE-5 VCRi Technology - Facts & Prospects

2012-05-10
Downsizing and downspeeding are two efficient strategies to reduce vehicles CO2 emission, provided that high BMEP can be achieved at any engine speed under clean, safe, stable and efficient combustion. With a 6:1 minimum compression ratio, the MCE-5 VCRi achieves 40 bar peak BMEP at 1200 rpm with no irregular combustion. If peak BMEP is maintained below 35 bar, fuel enrichment is no longer necessary. When running at part loads, the engine operates at high compression ratios (up to 15:1) to minimize BSFC and maximize the sweet spot area on the map. Next generation MCE-5 VCRi engines will combine VCR and stoichiometric charges, highly diluted with external cooled EGR, in order to improve part loads efficiency by means of both the reduction in heat and pumping losses, and the optimization of compression-expansion ratio. This strategy, added to downsizing-donwspeeding, requires high-energy ignition systems to promote repeatable, stable, rapid and complete combustion.
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