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Piston temperature plays a major role in determining details of fuel spray vaporization, fuel film deposition and the resulting combustion in direct-injection engines. Due to different heat transfer properties that occur in optical and all-metal engines, it becomes an inevitable requirement to verify the piston temperatures in both engine configurations before carrying out optical engine studies. A novel Spot Infrared-based Temperature (SIR-T) technique was developed to measure the piston window temperature in an optical engine. Chromium spots of 200 nm thickness were vacuum-arc deposited at different locations on a sapphire window. An infrared (IR) camera was used to record the intensity of radiation emitted by the deposited spots. From a set of calibration experiments, a relation was established between the IR camera measurements of these spots and the surface temperature measured by a thermocouple.