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It is well known that ethanol can be used in spark-ignition (SI) engines as a pure fuel or blended with gasoline. High enthalpy of vaporization of alcohols can affect air-fuel mixture formation prior to ignition and may form thicker liquid films around the intake valves, on the cylinder wall and piston crown. These liquid films can result in mixture non-homogeneities inside the combustion chamber and hence strongly influence the cyclic variability of early combustion stages. Starting from these considerations, the paper reports an experimental study of the initial phases of the combustion process in a single cylinder SI engine fueled with commercial gasoline and anhydrous ethanol, as well as their blend (50%vol alcohol). The engine was optically accessible and equipped with the cylinder head of a commercial power unit for two-wheel applications, with the same geometrical specifications (bore, stroke, compression ratio).

This paper reports the study of the effects of alternative diesel fuel and the impact for the air-fuel mixture preparation. The injection process characterization has been carried out in a non-evaporative high-density environment in order to measure the fuel injection rate and the spatial and temporal distribution of the fuel. The injection and vaporization processes have been characterized in an optically accessible single cylinder Common Rail diesel engine representing evaporative conditions similar to the real engine. The tests have been performed by means of a Bosch second generation common rail solenoid-driven fuel injection system with a 7-holes nozzle, flow number 440 cc/30s @100bar, 148deg cone opening angle (minisac type). Double injection strategy (pilot+main) has been implemented on the ECUs corresponding to operative running conditions of the commercial EURO 5 diesel engine.

The match among the increasing performance demands and the stringent requirements of emissions and the fuel consumption reduction needs a strong evolution in the two-wheel vehicle technology. In particular, many steps forward should be taken for the optimization of modern small motorcycles and scooters at low engine speeds and high loads. To this aim, detailed understanding of thermo-fluid dynamic phenomena that occur in the combustion chamber is fundamental. In this work, low-cost solutions are proposed to optimize ported fuel injection spark ignition (PFI SI) engines for two-wheel vehicles. The solutions are based on the change of phasing and on the splitting of the fuel injection in the intake manifold. The experimental activities were carried out in the combustion chamber of a single-cylinder 4-stroke optical engine fuelled with European commercial gasoline. The engine was equipped with a four-valve head of a commercial scooter engine.

High spatial and temporal resolution optical techniques were applied in a spark ignition (SI) engine in order to investigate the thermal and fluid dynamic phenomena occurring during the combustion process. The experiments were realized in the combustion chamber of an optically accessible single-cylinder port-fuel injection (PFI) SI engine. The engine was equipped with a four-valve head and with an external boost device. Two fuel injection strategies at closed-valve and open-valve occurring at wide open throttle were tested. Cycle-resolved digital imaging was used to follow the flame kernel growth and flame front propagation. Moreover, the effects of an abnormal combustion due to the firing of fuel deposition near the intake valves and on the piston surface were investigated. Natural emission spectroscopy in a wide wavelength range from ultraviolet to infrared was applied to detect the radical species that marked the combustion phenomena in the selected operating conditions.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

The flame front propagation in normal and abnormal combustion was investigated. Cycle-resolved flame emission imaging was applied in the combustion chamber of a port fuel injection boosted spark ignition engine. The engine was fuelled with a mixture of 90% iso-octane and 10% n-heptane by volume (PRF90). The effect of fuel injection phasing was studied. The combustion process was followed from the flame kernel formation until the opening of the exhaust valves. Different phenomena correlated to the abnormal combustion were analysed. Detailed information on ignition surfaces, end-gas auto-ignitions and knock were obtained. The appearance of autoignition centres in the end gas was evaluated in terms of timing, location and frequency of occurrence.

A satisfactory answer to the future severe normative on emissions and to the market request for spark ignition engines seems to be the use of downsized engines for passenger cars. Downsizing permits the increase in engines power and torque without the increase in cylinder capacity. The downsizing benefits are evident at part loads; on the other hand, more work should be done to optimize boosted engines at higher and full load. To this goal, a detailed knowledge of the thermo-fluid dynamic processes that occur in the combustion chamber is fundamental. The aim of this paper is the experimental investigation of the effect of the fuel injection in the intake manifold on the combustion process and pollutant formation in a boosted spark ignition (SI) engine. The experiments were performed on a partially transparent single-cylinder port fuel injection (PFI) SI engine, equipped with a four-valve head and boost device.

A 1-D thermo-fluid dynamic simulation code, including a quasi-D combustion model coupled with a detailed kinetic scheme, is used to analyze the combustion process in HCCI engines. The chemical mechanism has previously been validated in comparison with experimental data over a wide range of operating conditions. To explore the impact on model predictions, the cylinder was divided into multiple zones to characterize the conditions of the in-cylinder charge. Particular attention is devoted to the numerical algorithm in order to ensure the robustness and efficiency of the large system solution. This numerical model allows study of the autoignition of the air fuel mixture and determines the chemical evolution of the system. The proposed model was compared with in-cylinder temperature and chemical species profiles. The experimental activity was carried out in the combustion chamber of a single cylinder air cooled engine operating in HCCI mode.

The growing demands on fuel economy and always stricter limitations on pollutant emissions has increased the interest in the ignition phenomena to guarantee successful flame development for all the spark ignition (SI) engine operating conditions. The initial size and the growth of the flame have a strong influence on the further development of the combustion process. In particular, for the new FIAT generation of turbocharged SI engines, the first times of spark ignition combustion are not yet fully understood. This is mainly due to the missing knowledge concerning the detailed physical and chemical processes taking place during the all set of the flame propagation. These processes often occur simultaneously, making difficult the interpretation of measurements. In the present paper, flame dynamic was followed by UV-visible emission imaging in an optical SI engine.

Aim of this work is to develop a general purpose model for combustion and knocking prediction in SI engines, by coupling a thermo-fluid dynamic model for engine simulation with a general detailed kinetic scheme, including the low-temperature oxidation mechanism, for the prediction of the auto-ignition behavior of hydrocarbons. A quasi-D approach is used to describe the in-cylinder thermodynamic processes, applying the conservation of mass and energy over the cylinder volume, modeled as a single open system. The complex chemistry model has been embedded into the code, by using the same integration algorithm for the conservation equations and the reacting species, and taking into account their mutual interaction in the energy balance. A flame area evolution predictive approach is used to evaluate the turbulent flame front propagation as function of the engine operating parameters.

This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.

Aim of this work is to present and discuss the possibility and the limits of two zone models for spark-ignition engines using a detailed kinetic scheme for the characterization of the evolution of the air-fuel mixture, while an equilibrium approach is used for the burnt zone. Simple experimental measurements of knocking tendency of different fuels in ideal reactors, such as rapid compression machines and shock tube reactors, cannot be directly used for the analysis of octane numbers and sensitivity of hydrocarbon mixtures. Thus a careful investigation is very useful, not only of the combustion chamber behavior, including the modelling of the turbulent flame front propagation, but also of the fluid dynamic behavior of the intake and exhaust system, accounting for the volumetric efficiency of the engine.

The paper describes the development and validation of a quasi-dimensional multi-zone combustion model for Gasoline Direct Injection engines. The model has been embedded in the 1D thermo-fluid-dynamic code for the simulation of the whole engine system named GASDYN and developed by the authors [1, 2 and 3]. The GDI engine combustion model solves mass, energy and species equations using a 4th order Runge-Kutta integration method; the fuel spray is initially divided into a number of zones fixed regardless of the injected amount and the time step, considering the following break-up, droplet evaporation and air entrainment in each single zone. Experimental correlations have been used for the spray penetration and spatial information. Once the ignition begins it is assumed that the flame propagates spherically, evaluating its velocity by means of a fractal combustion approach and considering the local air-fuel ratio, which is the result of the spray evolution within the combustion chamber.

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.

The paper describes the research work carried out on the thermo-fluid dynamic modeling of an S.I. engine coupled to the vehicle in order to predict the engine and tailpipe emissions during the ECE European driving cycle. The numerical code GASDYN has been extended to simulate the engine + vehicle operation during the first 90 seconds of the NEDC driving cycle, taking account of the engine and exhaust system warm-up after the cold start. The chemical composition of the engine exhaust gas is calculated by means of a thermodynamic multi-zone combustion model, augmented by kinetic emission sub-models for the prediction of pollutant emissions. A simple procedure has been implemented to model the vehicle dynamic behavior (one degree of freedom model). A closed-loop control strategy (proportional-derivative) has been introduced to determine the throttle opening angle, corresponding to the engine operating point when the vehicle is following the ECE cycle.

Multidimensional simulation of the soot formation process in a diesel engine is realised exploiting quantitative measurements of the soot volume fraction and diameter obtained by optical techniques. Broadband extinction and scattering measurements are performed on an optically accessible 4-stroke engine where a forced air motion allows a strong prevalence of the premixed stage of combustion with respect to the non-premixed one. Two semi-empirical models for soot formation are tested in the numerical simulation, which is performed using a customized version of the KIVA-3 code. The need of furnishing coherent values of the soot particles density and mean diameter to the one of the two models requiring this kind of information, is highlighted and demonstrated to be crucial in avoiding over-prediction of the soot concentration.

Polychromatic extinction and chemiluminescence techniques, from ultraviolet to visible, were applied in an optical diesel engine, in order to analyze the temporal and spatial evolution of a high pressure fuel jet interacting with a swirling air motion. A fully flexible Common Rail fuel injection system equipped with a single hole nozzle was used. The experiments were performed at fixed engine speed and air/fuel ratio for three injection strategies. The first one consisted of a main injection to compare with those operating at low pressure injection. The other ones were based on a pilot and main injections, typical of current direct injection diesel engines, with different dwell time. A detailed investigation of the mixture formation process inside the combustion chamber during the ignition delay time was performed. The liquid and vapor fuel distribution in the combustion chamber was obtained analyzing the polychromatic extinction spectra.

The paper describes the research work concerning the simulation of 1D unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN has been developed to enable the concurrent prediction of the wave motion in the intake and exhaust ducts, the chemical composition of the gas discharged by the cylinder of a s.i. engine, the chemical and thermal behavior of catalytic converters. The effect of considering the transport of chemical species with reactions in gas phase (post-oxidation of unburned HC in the exhaust manifold) and in solid phase (conversion of pollutants in the catalyst) on the predicted wave motion is reported.

Nowadays 1D fluid dynamic models are widely used by engine designers, since they can give sufficiently accurate predictions in short times, allowing to support the optimization and development work of any prototype. According to the last requirements in terms of pollutant emission control, some enhancements have been introduced in the 1D code GASDYN, to improve its ability in predicting the composition of the exhaust gas discharged by the cylinders and the transport of the chemical species along the exhaust system. The main aspects of the methods adopted to model the combustion process and the related formation of pollutants are described in the paper. To account for the burnt gas stratification, two different approaches have been proposed, depending on the expected turbulence levels inside the combustion chamber. The reliability of the simulation of the pollutant formation process has been enhanced by the integration of the thermodynamic module with the Chemkin code.

Conventional methods to measure gas concentrations and, in particular, NO are typically based on sampling by valve, sample treatment and subsequent analysis. These methods suffer low spatial and temporal resolution. The introduction of high energy lasers in combination with fast detection systems allowed to detect the NO distribution inside optically accessible Diesel engines. In this paper, a high spatial and temporal resolution in-situ technique based on ultraviolet - visible absorption spectroscopy is proposed. The characterization of the combustion process by the detection of gaseous compounds from the start of combustion until the exhaust phase was performed. In particular, this technique allows the simultaneous detection of NO and OH absolute concentrations inside an optically accessible Diesel combustion chamber.