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In this study, the effect of autoignition behavior in the unburned end-gas region on pressure wave formation and knock intensity was investigated. A single-cylinder gasoline engine capable of high-speed observation of the end gas was used in the experiments. Visualization in the combustion chamber and spectroscopic measurement of light absorption by the end gas were carried out to analyze autoignition behavior in the unburned end-gas portion and the reaction history before autoignition. The process of autoignition and pressure wave growth was investigated by analyzing multipoint pressure histories. As a result, it was found that knocking intensity increases through interaction between autoignition and pressure waves.

The purpose of this research was to obtain a better understanding of engine knocking phenomena. Measurements were made of the behavior of formaldehyde (HCHO), an important intermediate product of cool flame reactions, and of the HCO radical, characterized by distinctive light emission during blue flame reactions. The test engine was operated on a blended fuel (50 RON) of n-heptane and iso-octane. Simultaneous measurements were made of the behavior of HCHO and the OH radical using absorption spectroscopy and of the behavior of HCO and OH radicals using emission spectroscopy. Absorbance spectroscopic measurements revealed behavior thought to correspond to the passage of a cool flame and emission spectroscopic measurements showed behavior thought to correspond to the passage of a blue flame.