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Analysis of non-legislated engine-emission components, with different exhaust-gas after-treatment techniques, is an important air quality objective. This paper reports the results for various nitrogen oxides, ammonia and differentiated hydrocarbons emitted at part load from a small 4-S SI engine. It was operated with gasoline, with CNG and with two different three-way catalytic converters. CNG produces less HC and less aromatics. But the HC conversion rate is insufficient. This is due to the lower exhaust gas temperatures, at part load with CNG, and due to the higher stability of light HCs. CNG affects the λ-regulation window, of the investigated system, such that the NOx conversion rate is lowered. In the rich domain of the λ-regulation window, the NO & NOx emissions after catalyst were lowest, while the NH₃ formation was most intense, and vice versa.

Concern for engine particle emission led to EC regulations of the number of solid particles emitted by LDV and HDV. However, all conventional piston-driven combustion engines emit metal oxide particles of which only little is known. The main sources are abrasion between piston ring and cylinder, abrasion of bearing, cams and valves, catalyst coatings, metal-organic lubrication oil additives, and fuel additives. While abrasion usually generates particles in the μm range, high concentrations of nanosize metal oxide particles are also observed, probably resulting from nucleation processes during combustion. In general, metal oxides, especially from transition metals, have high surface reactivity and can therefore be very toxic, especially nanosize particles, which evidently provide a high specific bioactive surface and are suspected to penetrate into the organism. Hence, these particles must be scrutinized for quantity, size distribution and composition.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.