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A major challenge for researchers and engineers in the field of diesel engine development is the simultaneous reduction of both NOx and soot emissions from diesel engines to comply with strict future emission legislation. One of the promising internal measures that focus on the reduction of soot emissions is post fuel injection which does not have a serious effect on NOx emissions. The main parameters involved when using this technique are post fuel quantity and dwell angle between the main and the post fuel injection events. In the present work a detailed computational investigation has been conducted to determine the effect of post fuel injection on engine performance and pollutant emissions (NOx and soot). To this scope, a phenomenological multi-zone combustion model has been used, properly modified to take into account the interaction of post and main injected fuel amounts.