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Technical Paper

Heat Transfer Characterization of Catalytic Converter Substrates During Warm-Up

2019-09-09
2019-24-0163
The transient heat transfer behavior of a real size automotive catalytic reactor has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO and C3H6 oxidations, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters have been chosen based on the tuning of experimental data. The impact of different initial catalytic converter temperatures, inlet flow temperatures and inlet flow rates have been quantified, even in terms of overall cumulative emissions. . A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinate are defined. Using this suitably modified coordinates, for the case of negligible axial solid conduction, computed solid temperature at the reactor outlet lay on the typical S-curve.
Technical Paper

Development of Metal Foam Based Aftertreatment System on a Diesel Passenger Car

2008-04-14
2008-01-0619
An alternative metal foam substrate for exhaust aftertreatment applications has been recently presented and characterized. The present paper focuses on the potential of the metal foam technology as an efficient DOC and CDPF substrates on real-world conditions. The target platform is a mid-size passenger car and the methodology includes both modeling and experiments. The experimental testing starts from small-scale reactor characterization of the basic heat/mass transfer properties and chemical kinetics. The results show that the foam structure exhibits excellent mass-transport properties offering possibilities for precious metal and catalyst volume savings for oxidation catalyst applications. These results are also used to calibrate an advanced 2-dimensional model which is able to predict the transient filtration and reaction phenomena in axial and radial flow systems.
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