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In order to meet the severe emission restrictions imposed by SULEV and EURO V standards the catalytic converter must reach light-off temperature during the first 20 seconds after engine cold start. Thermal losses in the exhaust manifold are driven by the heat transfer of the pulsating and turbulent exhaust flow and affect significantly the warm-up time of the catalyst. In the present paper an investigation concerning the gas-side heat transfer in the exhaust system of a spark ignited (SI) combustion engine with retarded ignition timing and secondary air injection into the exhaust port is reported. Based on this analysis, the warm-up simulation of a one-dimensional flow simulation tool is improved for an evaluation of different exhaust system configurations.