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In-cylinder concentrations of nitric oxide (NO) in a diesel engine were studied using a laser-induced fluorescence (LIF) technique that employs two-photon excitation. Two-photon NO LIF images were acquired during the expansion and exhaust portions of the engine cycle providing useful NO fluorescence signal levels from 60° after top dead center through the end of the exhaust stroke. The engine was fueled with the oxygenated compound diethylene glycol diethyl ether to minimize soot within the combustion chamber. Results of the two-photon NO LIF technique from the exhaust portion of the cycle were compared with chemiluminescence NO exhaust-gas measurements over a range of engine loads from 1.4 to 16 bar gross indicated mean effective pressure. The overall trend of the two-photon NO LIF signal showed good qualitative agreement with the NO exhaust-gas measurements.

The detailed mechanisms by which oxygenated diesel fuels reduce engine-out soot emissions are not well understood. The literature contains conflicting results as to whether a fuel's overall oxygen content is the only important parameter in determining its soot-reduction potential, or if oxygenate molecular structure or other variables also play significant roles. To begin to resolve this controversy, experiments were conducted at a 1200-rpm, moderate-load operating condition using a modern-technology, 4-stroke, heavy-duty DI diesel engine with optical access. Images of broadband natural luminosity (i.e., light emission without spectral filtering) from the combustion chamber, coupled with heat-release and efficiency analyses, are presented for three test-fuels. One test-fuel (denoted GE80) was oxygenated with tri-propylene glycol methyl ether; the second (denoted BM88) was oxygenated with di-butyl maleate. The overall oxygen contents of these two fuels were matched at 26% by weight.