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A solid particle number measurement system (SPNMS) was developed using a catalytic stripper (CS) technology instead of an evaporation tube (ET). The ET is used in commercially available systems, compliant with the Particle Measurement Program (PMP) protocol developed for European Union (EU) solid particle number regulations. The catalytic stripper consists of a small core of a diesel exhaust oxidation catalyst. The SPNMS/CS met all performance requirements under the PMP protocol. It showed a much better performance in removing large volatile tetracontane particles down to a size well below the PMP lower cut-size of 23 nm, compared to a SPNMS equipped with an ET instead of a CS. The SPNMS/CS also showed a similar performance to a commercially available system when used on a gasoline direct injection (GDI) engine exhaust.

This paper summarizes the validation testing of the Horiba Instruments OBS-2200 gaseous portable emissions measurement system (PEMS) for in-use compliance testing per Title 40 of the Code of Federal Regulations (CFR) Part 1065.920 (Section 1065.920). The qualification process included analyzer verifications as well as engine testing on a model-year 2007 heavy-duty diesel engine produced by Volvo Powertrain. The measurements of brake-specific emissions with the OBS-2200 were compared to those of a CFR Part 1065-compliant CVS test cell over a series of not-to-exceed (NTE) events. The OBS-2200 passed all linearity verifications and analyzer checks required of PEMS. Engine test validation was achieved for all three regulated gaseous emissions (CO, NMHC, and NOX) per 40 CFR Part 1065.920(b)(5)(i), which requires a minimum of 91 percent of the measurement allowance adjusted deltas to be less than or equal to zero.

Particle size distribution, number, and mass emissions from the exhaust of a 92 kW 1999 Isuzu 6BG1 nonroad naturally aspirated diesel engine were measured. The engine exhaust was equipped with a Dry System Technologies® (DST) auxiliary emission control device that included an oxidation catalyst, a heat exchanger, and a disposable paper particulate filter. Particle measurement was taken during the ISO 8178 8-mode test for engine out and engine with the DST using a scanning mobility particle sizer (SMPS) in parallel to the standard filter method (SFM), specified in 40 CFR, Part 89. The DST efficiency of removing particles was about 99.9 percent based on particle number, 99.99 percent based on particle mass derived from number and size. However, the efficiency based on mass derived from the SFM was much lower on the order of 90 to 93 percent.

Particle number concentrations and size distributions were measured for the diluted exhaust of a 1991 diesel engine during the US FTP transient cycle for heavy-duty diesel engines. The engine was operated on US 2-D on-highway diesel fuel. The particle measurement system consisted of a full flow dilution tunnel as the primary dilution stage, an air ejector pump as the secondary dilution stage, and an electrical low pressure impactor (ELPI) for particle size distribution measurements. Particle number emission rate was the highest during the Los Angeles Non Freeway (LANF) and the Los Angeles Freeway (LAF) segments of the transient cycle. However, on brake specific number basis the LAF had the lowest emission level. The particle size distribution was monomodal in shape with a mode between 0.084 μm and 0.14 μm. The shape of the size distribution suggested no presence of nanoparticles below the lower detection limit of the instrument (0.032 μm), except during engine idle.

Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.