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Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.

The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.

This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.

This program involved the detailed evaluation of a novel laser-based in-exhaust ammonia sensor using a diesel fuel-based burner platform integrated with an ammonia injection system. Test matrix included both steady-state modes and transient operation of the burner platform. Steady-state performance evaluation included tests that examined impact of exhaust gas temperature, gas velocity and ammonia levels on sensor response. Furthermore, cross sensitivity of the sensor was examined at different levels of NOX and water vapor. Transient tests included simulation of the FTP test cycles at different ammonia and NOX levels. A Fourier transform infrared (FTIR) spectrometer as well as NIST traceable ammonia gas bottles (introduced into the exhaust stream via a calibrated flow controller) served as references for ammonia measurement.

Stringent emissions regulations and the need for lower tailpipe emissions are pushing the development of low-carbon alternative fuels. H2 is a zero-carbon fuel that has the potential to lower CO2 emissions from internal combustion engines (ICEs) significantly. Moreover, this fuel can be readily implemented in ICEs with minor modifications. Batteries can be argued to be a good zero tailpipe emission solution for the light-duty sector; however, medium and heavy-duty sectors are also in need of rapid decarbonization. Current strategies for H2 ICEs include modification of the existing spark ignition (SI) engines to run on port fuel injection (PFI) systems with minimal changes from the current compressed natural gas (CNG) engines. This H2 ICE strategy is limited by knock and pre-ignition. One solution is to run very lean (lambda >2), but this results in excessive boosting requirements and may result in high NOx under transient conditions.

As governmental agencies focus on low levels of the oxides of nitrogen (NOx) emissions compliance, new off-road applications are being reviewed for both regulated and unregulated emissions to understand the technological challenges and requirements for improved emissions performance. The California Air Resources Board (CARB) has declared its intention to pursue more stringent NOX standards for the off-road market. As part of this effort, CARB initiated a program to provide a detailed characterization of emissions meeting the current Tier 4 off-road standards [1]. This work focused on understanding the off-road market, establishing a current technology emissions baseline, and performing initial modeling on potential low NOx solutions. This paper discusses a part of this effort, focuses on the emissions characterization from two non-road engine platforms, and compares the emissions species from different approaches designed to meet Tier 4 emissions regulations.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

The size and distribution of a vehicle’s tailpipe particulate emissions can have a strong impact on human health, especially if the particles are small enough to enter the human respiratory system. Gasoline direct injection (GDI) has been adopted widely to meet stringent fuel economy and CO2 regulations across the globe for recent engine architectures. However, the introduction of GDI has led to challenges concerning the particulate matter (PM) and particle number (PN) emissions from such engines. This study aimed to compare the particulate emissions of three SI combustion strategies: conventional SI, conventional stoichiometric low-pressure exhaust gas recirculation (LP-EGR), and Dedicated-EGR (D-EGR) at four specific test conditions. It was shown that the engine-out PM/PN for both the EGR strategies was lower than the conventional SI combustion under normal operating conditions. The test conditions were chosen to represent the WLTC test conditions.

Particulate matter (PM) and NOX are two major pollutants generated by diesel engines. Modern diesel aftertreatment systems include selective catalytic reduction (SCR) technology that helps reduce tailpipe NOX emissions when coupled with diesel exhaust fluid (DEF/urea) injection. However, this process also results in the formation of urea derived byproducts that can influence non-volatile particle number (PN) measurement conducted in accordance with the European Union (EU) Particle Measurement Program (PMP) protocol. In this program, an experimental investigation of the impact of DEF injection on tailpipe PN and its implications for PMP compliant measurements was conducted using a 2015 model year 6.7 L diesel engine equipped with a diesel oxidation catalyst, diesel particulate filter and SCR system. Open access to the engine controller was available to manually override select parameters.

Euro VI regulations in Europe and its adaptors recently extended the regulation to include Particle Number (PN) for in-use conformity testing. However, the in-use PN Portable Emissions Measurement System (PEMS) is still evolving and has higher measurement uncertainty when compared against laboratory-grade PN systems. The PN systems for laboratory require a condensation particle counter (CPC). Thus, in this study, a CPC-based Horiba PN-PEMS was selected for performance evaluation against the laboratory-grade PN systems. This study was divided into four phases. The first two phases’ measurements were conducted from the Constant Volume Sampler (CVS) tunnel where the brake-specific particle number (BSPN) levels of 1010-12 and 1013 (#/bhp-h) were measured from the engines equipped with diesel particulate filter (DPF) and without DPF, respectively. In comparison against PN systems, PN-PEMS, on average, reported 14% lower BSPN from 82 various tests for the BSPN levels of 1010-11.

The confluence of increasing fuel economy requirements and increased use of ethanol as a gasoline blend component has led to various studies into the efficiency and performance benefits of higher octane numbers and high ethanol content fuels in modern engines. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engine and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were prepared with varying composition, octane numbers and ethanol blend levels. The paper reports on the third part of this study where cylinder pressures were recorded for fuels under knocking conditions in both a single-cylinder research engine (SCE), utilizing a GM LHU head and piston, as well as the CFR engines used for octane ratings.

It is widely acknowledged that the CFR octane rating engines are not representative of modern engines and that there is a gap in the quantification of knock severity between the two engine types. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engines and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were tested with varying composition, octane numbers and ethanol blend levels. The paper reports on the fourth part of this study where cylinder pressures were recorded under standard knock conditions in CFR engines under RON and MON conditions using the ASTM prescribed instrumentation. By the appropriate signal conditioning of the D1 detonation pickups on the CFR engines, a quantification of the knock severity was possible that had the same frequency response as a cylinder pressure transducer.

As agencies and governing bodies evaluate the feasibility of reduced emission standards, additional focus has been placed on technology durability. This is seen in proposed updates, which would require Original Equipment Manufacturers (OEMs) to certify engine families utilizing a full useful life (FUL) aftertreatment system. These kinds of proposed rulings would place a heavy burden on the manufacturer to generate FUL components utilizing traditional engine aging methods. Complications in this process will also increase the product development effort and will likely limit the amount of aftertreatment durability testing. There is also uncertainty regarding the aging approach and the representative impact compared to field aged units. Existing methodologies have evolved to account for several deterioration mechanisms that, when controlled, can be utilized to create a flexible aging protocol. As a result, these methodologies provide the necessary foundation for continued development.

California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.

Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.

Selective Catalytic Reduction (SCR) systems provide excellent NOX control for diesel engines provided the exhaust aftertreatment inlet temperature remains at 200° C or higher. Since diesel engines run lean, extended light load operation typically causes exhaust temperatures to fall below 200° C and SCR conversion efficiency diminishes. Heated urea dosing systems are being developed to allow dosing below 190° C. However, catalyst face plugging remains a concern. Close coupled SCR systems and lower temperature formulation of SCR systems are also being developed, which add additional expense. Current strategies of post fuel injection and retarded injection timing increases fuel consumption. One viable keep-warm strategy examined in this paper is cylinder deactivation (CDA) which can increase exhaust temperature and reduce fuel consumption.

Gasoline direct injection (GDI) has changed the exhaust composition in comparison with the older port fuel injection (PFI) systems. More recently, light-duty vehicle engine manufactures have combined these two technologies to take advantage of the knock benefits and fuel economy of GDI with the low particulate emission of PFI. These dual injection strategy engines have made a change in the combustion emission composition produced by these engines. Understanding the impact of these changes is essential for automotive companies and aftertreatment developers. A novel sampling system was designed to sample the exhaust generated by a dual injection strategy gasoline vehicle using the United States Federal Test Procedure (FTP). This sampling system was capable of measuring the regulated emissions as well as collecting the entire exhaust from the vehicle for measuring unregulated emissions.

Accumulation of lubricant and fuel derived ash in the diesel particulate filter (DPF) during vehicle operation results in a significant increase of pressure drop across the after-treatment system leading to loss of fuel economy and reduced soot storage capacity over time. Under certain operating conditions, the accumulated ash and/or soot cake layer can collapse resulting in ash deposits upstream from the typical ash plug section, henceforth termed mid-channel ash deposits. In addition, ash particles can bond (either physically or chemically) with neighboring particles resulting in formation of bridges across the channels that effectively block access to the remainder of the channel for the incoming exhaust gas stream. This phenomenon creates serious long-term durability issues for the DPF, which often must be replaced. Mid-channel deposits and ash bridges are extremely difficult to remove from the channels as they often sinter to the substrate.

Dual injection fuel systems combine the knock and fuel economy benefits of gasoline direct injection (GDI) technology with the lower particulate emissions of port fuel injection (PFI) systems. For many years, this technology was limited to smaller-volume, high-end, vehicle models, but these technologies are now becoming main stream. The combination of two fuel injection systems has an impact on the combustion emission composition as well as the consistency of control strategy and emissions. Understanding the impact of these changes is essential for fuel and fuel additive companies, automotive companies, and aftertreatment developers. This paper describes the effects of dual injection technology on both regulated and non-regulated combustion emissions from a 2018 Toyota Camry during several cold-start, 4-bag United States Federal Test Procedure (FTP) cycle.

This study is a continuation of previous work assessing the robustness of a Cummins XPI common rail injection system operating with gasoline-like fuel. All the hardware from the original study was retained except for the high pressure pump head and check valves which were replaced due to cavitation damage. An additional 400 hour NATO cycle was run on the refurbished fuel system to achieve a total exposure time of 800 hours and detect any other significant failure modes. As in the initial investigation, fuel system parameters including pressures, temperatures and flow rates were logged on a test bench to monitor performance over time. Fuel and lubricant samples were taken every 50 hours to assess fuel consistency, metallic wear, and interaction between fuel and oil. High fidelity driving torque and flow measurements were made to compare overall system performance when operating with both diesel and light distillate fuel.