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This research focused on the light emission behavior of the OH radical (characteristic spectrum of 306.4 [nm]) that plays a key role in combustion reactions, in order to investigate the influence of the residual gas on autoignition. Authors also analyzed on the heat release and thermodynamic mean temperature due to research activity state of unburned gas. The test engine used was a 2-stroke, air-cooled engine fitted with an exhaust pressure control valve in the exhaust manifold. Raising the exhaust pressure forcibly recirculated more exhaust gas internally. When a certain level of internal EGR is forcibly applied, the temperature of the unburned end gas is raised on account of heat transfer from the hot residual gas and also due to compression by piston motion. As a result, the unburned end gas becomes active and autoignition tends to occur.